An Improved Method for Fullerol Preparation Based on Dialysis

›› 2010, Vol. 18 ›› Issue (5): 876-879.

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An Improved Method for Fullerol Preparation Based on Dialysis

YAO Lu, KANG Feng, PENG Qiyun, YANG Xinlin

School of Life Science and Technology, Beijing Institute of Technology, Beijing 100081, China

Received:2009-11-05 Revised:2010-07-07 Online:2010-10-28 Published:2010-10-28
Supported by:
Supported by the National Natural Science Foundation of China (20672012);the Natural Science Foundation of Beijing(20822020)

An Improved Method for Fullerol Preparation Based on Dialysis

姚璐, 康峰, 彭琦云, 杨新林

School of Life Science and Technology, Beijing Institute of Technology, Beijing 100081, China

通讯作者: YANG Xinlin,E-mail:xlyang@bit.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (20672012);the Natural Science Foundation of Beijing(20822020)

Abstract

Abstract: A dialysis-based method was developed to remove Na ions in fullerol preparation by a conventional synthetic route. Fullerol was synthesized using a typical two-phase reaction in the presence of tetrabutylammonium hydroxide. Its structure was confirmed by UV spectra, Fourier transform infrared spectroscopy spectra, ¹H nuclear magnetic resonance, and matrix-assisted laser desorption/ionization time of flight mass spectra. The content of Na element was determined by inductive coupled plasma atomic emission spectroscopy. The mass content of Na in the product obtained from the conventional route was about 10%, and it could be almost completely eliminated by dialysis with a membrane of molecular weight cut-off (MWCO) 8-15 kDa. The yield of fullerol by the dialysis method was slightly higher than by the conventional route. These results indicate that dialysis may have a potential application for fullerol preparation.

Key words: fullerol, preparation, sodium contamination, dialysis

摘要： A dialysis-based method was developed to remove Na ions in fullerol preparation by a conventional synthetic route. Fullerol was synthesized using a typical two-phase reaction in the presence of tetrabutylammonium hydroxide. Its structure was confirmed by UV spectra, Fourier transform infrared spectroscopy spectra, ¹H nuclear magnetic resonance, and matrix-assisted laser desorption/ionization time of flight mass spectra. The content of Na element was determined by inductive coupled plasma atomic emission spectroscopy. The mass content of Na in the product obtained from the conventional route was about 10%, and it could be almost completely eliminated by dialysis with a membrane of molecular weight cut-off (MWCO) 8-15 kDa. The yield of fullerol by the dialysis method was slightly higher than by the conventional route. These results indicate that dialysis may have a potential application for fullerol preparation.

关键词: fullerol, preparation, sodium contamination, dialysis

YAO Lu, KANG Feng, PENG Qiyun, YANG Xinlin. An Improved Method for Fullerol Preparation Based on Dialysis[J]. , 2010, 18(5): 876-879.

姚璐, 康峰, 彭琦云, 杨新林. An Improved Method for Fullerol Preparation Based on Dialysis[J]. CIESC Journal, 2010, 18(5): 876-879.

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An Improved Method for Fullerol Preparation Based on Dialysis

An Improved Method for Fullerol Preparation Based on Dialysis

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