CIESC Journal ›› 2019, Vol. 70 ›› Issue (S2): 62-69.DOI: 10.11949/0438-1157.20190592
• Thermodynamics • Previous Articles Next Articles
Fuxin YANG1(),Xiaopo WANG1,Qiang CHEN2,Houzhang TAN1
Received:
2019-05-29
Revised:
2019-06-09
Online:
2019-09-06
Published:
2019-09-06
Contact:
Fuxin YANG
通讯作者:
杨富鑫
作者简介:
杨富鑫(1985—),男,副教授,基金资助:
CLC Number:
Fuxin YANG,Xiaopo WANG,Qiang CHEN,Houzhang TAN. Molecular thermodynamics for solubility of gas in binary liquid[J]. CIESC Journal, 2019, 70(S2): 62-69.
杨富鑫,王晓坡,陈强,谭厚章. 气体在混合溶液中溶解度的分子热力学计算[J]. 化工学报, 2019, 70(S2): 62-69.
计算模型 | K11 | K12 | K22 | α31/(J·cm-3) | α32/(J·cm-3) | α12/(J·cm-3) | x3的标准偏差/% |
---|---|---|---|---|---|---|---|
缔合作用 | 0.083 | 1.80 | 0.054 | 102.8 | 108.4 | 9.0 | 6.08 |
缔合作用 | 0.083 | 1.80 | 0.16 | 102.8 | 104.4 | 6.5 | 5.45 |
缔合作用 | 0.16 | 1.80 | 0.16 | 100.1 | 104.4 | 5.3 | 4.74 |
无缔合作用 | 0 | 1.30 | 0 | 106.8 | 111.1 | 5.0 | 8.29 |
Table 1 Parameters of model for calculating solubility of nitrogen (3) in mixtures of acetone (1) and chloroform (2)
计算模型 | K11 | K12 | K22 | α31/(J·cm-3) | α32/(J·cm-3) | α12/(J·cm-3) | x3的标准偏差/% |
---|---|---|---|---|---|---|---|
缔合作用 | 0.083 | 1.80 | 0.054 | 102.8 | 108.4 | 9.0 | 6.08 |
缔合作用 | 0.083 | 1.80 | 0.16 | 102.8 | 104.4 | 6.5 | 5.45 |
缔合作用 | 0.16 | 1.80 | 0.16 | 100.1 | 104.4 | 5.3 | 4.74 |
无缔合作用 | 0 | 1.30 | 0 | 106.8 | 111.1 | 5.0 | 8.29 |
1 | PrausnitzJ M, LichtenthalerR N, de AzevedoE G. Molecular Thermodynamics of Fluid-phase Equilibria[M]. New Jersey: Prentice Hall, 1999: 352-378. |
2 | HarrisH G, PrausnitzJ M. Thermodynamics of solutions with physical and chemical interactions. Solubility of acetylene in organic solvents[J]. Ind. Eng. Chem. Fundam., 1969, 8(2): 180-188. |
3 | KretschmerC B, WiebeR. Thermodynamics of alcohol - hydrocarbon mixtures[J]. J. Chem. Phys., 1954, 22(10): 1697-1701. |
4 | 陈小鹏, 王琳琳, 邓双, 等. 氢气在松节油中高压平衡溶解度和体积传质系数[J]. 化工学报, 2003, 54(5): 682-686. |
ChenX P, WangL L, DengS, et al. Equilibrium solubility and volumetric mass transfer coefficient of H2 in turpentine at high pressure[J]. Journal of Chemical Industry and Engineering (China), 2003, 54(5): 682-686. | |
5 | 何潮洪, 侯虞钧, 吴兆立. 纯气体在非挥发性溶剂中溶解度的关联[J]. 化工学报, 1992, 43(2): 178-183. |
HeC H, HouY J, WuZ L. Correlation of solubility of pure gases in non-volatile solvents[J]. Journal of Chemical Industry and Engineering (China), 1992, 43(2): 178-183. | |
6 | 何茂刚, 白里航, 刘思琦, 等. CO2在正戊醇中的溶解度和体积传质系数[J]. 化工学报, 2017, 68(5): 1780-1785. |
HeM G, BaiL H, LiuS Q, et al.Solubility and volumetric mass transfer coefficient of CO2 in 1-pentanol[J]. CIESC Journal, 2017, 68(5): 1780-1785. | |
7 | 胡冬冬, 包磊, 刘涛, 等. 超临界二氧化碳-共溶剂体系与聚醋酸乙烯酯相互作用[J]. 化工学报, 2018, 69(2): 555-562. |
HuD D, BaoL, LiuT, et al. Interaction between supercritial carbon dioxide-cosolvent and poly(vinyl acetate)[J]. CIESC Journal, 2018, 69(2): 555-562. | |
8 | 胡英, 徐英年, PrausnitzJ M. 气体溶解度的分子热力学(Ⅰ): 气体在非极性溶剂中的Henry常数[J]. 化工学报, 1987, 38(1): 22-38. |
HuY, XuY N, PrausnitzJ M. Molecular thermodynamics of gas solubility (Ⅰ): Henry constant of gas in non-polar solvent[J]. Journal of Chemical Industry and Engineering (China), 1987, 38(1): 22-38. | |
9 | 沈家城, 李竞庆, 鲍祁, 等. 加压下二氧化碳在二甲基甲酰胺中的溶解度研究[J]. 化工学报, 1988, 39(6): 716-722. |
ShenJ C, LiJ Q, BaoQ, et al. Solubility of carbon dioxide in dimethylamine under pressure [J]. Journal of Chemical Industry and Engineering (China), 1988, 39(6): 716-722. | |
10 | 孙婧元, 蒋浩, 蒋斌波, 等. 乙烯和丙烯在低聚物-正己烷溶液中的溶解度及体积传质系数测定[J]. 化工学报, 2009, 60(9): 2153-2160. |
SunJ Y, JiangH , JiangB B, et al. Solubility and volumetric mass transfer coefficient of ethylene and propylene in n-hexane solution of low molecular weight polyethylene [J]. CIESC Journal, 2009, 60(9): 2153-2160. | |
11 | 王邵雷, 彭昌军, 李鲲, 等. 石英晶体微平衡法测定CO2在聚合物中的溶解度[J]. 化工学报, 2003, 54(2): 141-146. |
WangS L, PengC J, LiK, et al. Measurement of solubilities of CO2 in polymers by quartz crystal microbalance [J]. Journal of Chemical Industry and Engineering (China), 2003, 54(2): 141-146. | |
12 | 王伟, 高强, 桂霞, 等. 二氧化碳在稠油中溶解度的测定与模型预测[J]. 化工学报, 2016, 67(2): 442-447. |
WangW, GaoQ, GuiX, et al. Determination and model prediction of solubilities of CO2 in heavy oil under high pressure [J]. CIESC Journal, 2016, 67(2): 442-447. | |
13 | 伍艳辉, 于世昆, 段永超, 等. 基团贡献法预测含极性基团离子液体对气体的溶解选择性[J]. 化工学报, 2011, 62(10): 2684-2690. |
WuY H, YuS K, DuanY C, et al. Determination of gas selectivity of solution in RTILs with polar group by group contribution method [J]. CIESC Journal , 2011, 62(10): 2684-2690. | |
14 | 邢潇, 赵志军, 汤志刚, 等. 离子液体[Bmim][NTf2]对CO2在碳酸二乙酯中溶解性能的强化[J]. 化工学报, 2017, 68(2): 542-551. |
XingX, ZhaoZ J, TangZ G, et al. Solubility enhancement of CO2 in diethyl carbonate by ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide [J]. CIESC Journal , 2017, 68(2): 542-551. | |
15 | 徐英年, 胡英. 气体溶解度的分子热力学(Ⅲ): 气体在1—1价电解质溶液中的Henry常数[J]. 化工学报, 1987, 38(2): 146-155. |
XuY N, HuY. Molecular thermodynamics of gas solubility (Ⅲ): Henry constant of gas in 1-1 valence electrolyte solution [J]. Journal of Chemical Industry and Engineering (China), 1987, 38(2): 146-155. | |
16 | 徐英年, 胡英, 刘国杰. 气体溶解度的分子热力学(Ⅱ): 气体在极性溶剂中的Henry常数[J]. 化工学报, 1987, 38(2): 137-145. |
XuY N, HuY, LiuG J. Molecular thermodynamics of gas solubility (Ⅱ): Henry constant of gas in polar solvent [J]. Journal of Chemical Industry and Engineering (China), 1987, 38(2): 137-145. | |
17 | 姚善泾, 朱自强. 气体在含盐非水溶液中的溶解度——CO2-CuAlCl4(C6H5CH3)n体系的气-液平衡[J]. 化工学报, 1988, 39(3): 327-334. |
YaoS J, ZhuZ Q. Solubility of gases in salt-containing non-aqueous solutions - gas-liquid equilibrium of the system CO2-CuAlCl4(C6H5CH3)n [J]. Journal of Chemical Industry and Engineering (China), 1988, 39(3): 327-334. | |
18 | 张光旭, 吴元欣, 马沛生, 等. CO等气体在苯酚中的溶解度的测定及关联[J]. 化工学报, 2005, 56(11): 7-13. |
ZhangG X, WuY X, MaP S, et al. Measurement and correlation of solubility of carbon monoxide and other gases solubility in phenol [J]. Journal of Chemical Industry and Engineering (China), 2005, 56(11): 7-13. | |
19 | 郑碏, 董立户, 陈健, 等. CO2捕集的吸收溶解度计算和过程模拟[J]. 化工学报, 2010, 61(7): 1740-1746. |
ZhengQ, DongL H, ChenJ, et al. Absorption solubility calculation and process simulation for CO2 capture [J]. CIESC Journal, 2010, 61(7): 1740-1746. | |
20 | 左有祥, 郭天民. 单个气体在单盐水溶液中的溶解度[J]. 化工学报, 1991, 42(3): 318-327. |
ZuoY X, GuoT M. Solubility of a gas in a single salt aqueous solution [J]. Journal of Chemical Industry and Engineering (China), 1991, 42(3): 318-327. | |
21 | DolezalekF. On the theory of binary mixture and concentrated solutions[J]. Z. Phys. Chem., Stoechiom Verwandtschaftsl, 1908, 64(6): 727-747. |
22 | PrausnitzJ M. Regular solution theory for gas-liquid solutions[J]. AIChE Journal, 1958, 4(3): 269-272. |
23 | HildebrandJ H, ScottR L. The Solubility of Nonelectrolytes[M]. New York: Dover Publications, 1964: 156. |
24 | JumperC F, EmersonM T, HowardB B. Self-association constant of chloroform from NMR chemical shifts[J]. The Journal of Chemical Physics, 1961, 35(5): 1911-1912. |
25 | LemmonE W, SpanR. Short fundamental equations of state for 20 industrial fluids[J]. Journal of Chemical & Engineering Data, 2006, 51(3): 785-850. |
26 | ClechetP. Application to the binary mixtures: the system dimethyl sulphoxide-chloroform at 20, 25, 35, 45, and 55°C[J]. Bulletin de la Societe Chimique de France, 1971: 2866-2871. |
27 | BlanksR F, PrausnitzJ M. Volumetric properties of gas mixtures containing one or more polar components[J]. AIChE Journal, 1962, 8(1): 86-92. |
28 | NittaT, NakamuraY, AriyasuH, et al. Solubilities of nitrogen in binary-solutions of acetone with cyclohexane, benzene, chloroform and 2-propanol[J]. Journal of Chemical Engineering of Japan, 1980, 13(2): 97-103. |
29 | KearnsE R. Thermodynamic studies of the system: acetone-chloroform (Ⅱ): The relation of excess mixing functions to association complexes[J]. The Journal of Physical Chemistry, 1961, 65(2): 314-316. |
30 | ApelblatA, TamirA, WagnerM. Thermodynamics of acetone-chloroform mixtures[J]. Fluid Phase, 1980, 4(3/4): 229-255. |
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