CIESC Journal ›› 2022, Vol. 73 ›› Issue (11): 4850-4858.DOI: 10.11949/0438-1157.20220811
• Thermodynamics • Previous Articles Next Articles
Changwei PENG1(), Shihua SANG1(), Ruizhi CUI2,3, Hongbao REN1
Received:
2022-06-10
Revised:
2022-09-29
Online:
2022-12-06
Published:
2022-11-05
Contact:
Shihua SANG
通讯作者:
桑世华
作者简介:
彭昌炜(1998—),男,硕士研究生, 2832975774@qq.com
基金资助:
CLC Number:
Changwei PENG, Shihua SANG, Ruizhi CUI, Hongbao REN. Studies on three-dimensional phase diagram of the quinary system NaBr-KBr-MgBr2-CaBr2-H2O at 298.15 K[J]. CIESC Journal, 2022, 73(11): 4850-4858.
彭昌炜, 桑世华, 崔瑞芝, 任红保. 五元体系NaBr-KBr-MgBr2-CaBr2-H2O在298.15 K下的空间立体相图研究[J]. 化工学报, 2022, 73(11): 4850-4858.
No. | Systems | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibria solids | Ref. | |||||
---|---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | CaBr2 | MgBr2 | KBr | ||||
1 | MCB | 0.00 | 0.00 | 4.96 | 55.71 | 91.82 | 8.18 | 0.00 | MB6 + CB6 | [ |
2 | 0.00 | 0.00 | 5.92 | 54.37 | — | — | — | [ | ||
3 | KCB | 0.00 | 1.33 | 0.00 | 58.24 | 97.77 | 0.00 | 2.23 | KB + CB6 | [ |
4 | 0.00 | 0.81 | 0.00 | 59.14 | — | — | — | [ | ||
5 | KMB | 0.00 | 0.25 | 50.18 | 0.00 | 0.00 | 99.50 | 0.50 | MB6 + KMB6 | [ |
6 | 0.00 | 3.30 | 42.85 | 0.00 | 0.00 | 92.85 | 7.15 | KMB6 + KB | ||
7 | NKB | 43.94 | 7.42 | 0.00 | 0.00 | 0.00 | 0.00 | 14.45 | KB+ NB2 | [ |
8 | 43.06 | 7.23 | 0.00 | 0.00 | — | — | — | [ | ||
9 | NCB | 0.84 | 0.00 | 0.00 | 58.97 | 98.60 | 0.00 | 0.00 | CB6+ NB | [ |
10 | 10.32 | 0.00 | 0.00 | 42.28 | 80.38 | 0.00 | 0.00 | NB + NB2 | ||
11 | 0.76 | 0.00 | 0.00 | 59.34 | — | — | — | CB6+ NB | [ | |
12 | 8.61 | 0.00 | 0.00 | 44.6 | — | — | — | NB + NB2 | ||
13 | NMB | 3.50 | 0.00 | 47.96 | 0.00 | 0.00 | 96.81 | 0.00 | MB6 + NB | [ |
14 | 7.20 | 0.00 | 42.74 | 0.00 | 0.00 | 93.44 | 0.00 | NB + NB2 | ||
15 | 3.52 | 0.00 | 47.95 | 0.00 | — | — | — | MB6 + NB | [ | |
16 | 7.16 | 0.00 | 42.76 | 0.00 | — | — | — | NB + NB2 | ||
F1 | KMCB | 0.00 | 0.14 | 4.73 | 55.21 | 91.89 | 7.87 | 0.23 | MB6 + KMB6 + CB6 | [ |
F2 | 0.00 | 0.61 | 4.66 | 56.05 | 91.41 | 7.60 | 0.99 | KB + KMB6 + CB6 | ||
F3 | NKCB | 0.74 | 1.50 | 0.00 | 57.76 | 96.27 | 0.00 | 2.50 | CB6 + NB + KB | [ |
F4 | 10.45 | 3.05 | 0.00 | 40.61 | 75.05 | 0.00 | 5.64 | NB + NB2 + KB | ||
F5 | NKMB | 3.42 | 0.22 | 47.21 | 0.00 | 0.00 | 92.84 | 0.43 | MB6 + NB+ KMB6 | [ |
F6 | 7.06 | 0.43 | 42.36 | 0.00 | 0.00 | 84.97 | 0.86 | NB + KMB6 + NB2 | ||
F7 | 8.06 | 3.81 | 36.13 | 0.00 | 0.00 | 75.27 | 7.94 | KMB6 + KB + NB2 | ||
F8 | NMCB | 0.59 | 0.00 | 5.89 | 54.16 | 89.31 | 9.71 | 0.00 | MB6 + CB6 + NB | [ |
E1 | NKMCB | 0.73 | 1.48 | 4.62 | 55.21 | 88.99 | 7.45 | 2.39 | NB + CB6 + KMB6 + KB | this work |
E2 | 6.66 | 3.31 | 28.10 | 6.97 | 15.48 | 62.39 | 7.35 | NB2 + NB + KMB6 + KB | ||
E3 | 0.54 | 0.21 | 4.84 | 55.15 | 90.80 | 7.96 | 0.35 | MB6 + KMB6 + NB + CB6 |
Table 1 Equilibrium liquid and solid phase composition in the quinary system NaBr-KBr-MgBr2-CaBr2-H2Oand its quaternary and ternary subsystems at 298.15 K
No. | Systems | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibria solids | Ref. | |||||
---|---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | CaBr2 | MgBr2 | KBr | ||||
1 | MCB | 0.00 | 0.00 | 4.96 | 55.71 | 91.82 | 8.18 | 0.00 | MB6 + CB6 | [ |
2 | 0.00 | 0.00 | 5.92 | 54.37 | — | — | — | [ | ||
3 | KCB | 0.00 | 1.33 | 0.00 | 58.24 | 97.77 | 0.00 | 2.23 | KB + CB6 | [ |
4 | 0.00 | 0.81 | 0.00 | 59.14 | — | — | — | [ | ||
5 | KMB | 0.00 | 0.25 | 50.18 | 0.00 | 0.00 | 99.50 | 0.50 | MB6 + KMB6 | [ |
6 | 0.00 | 3.30 | 42.85 | 0.00 | 0.00 | 92.85 | 7.15 | KMB6 + KB | ||
7 | NKB | 43.94 | 7.42 | 0.00 | 0.00 | 0.00 | 0.00 | 14.45 | KB+ NB2 | [ |
8 | 43.06 | 7.23 | 0.00 | 0.00 | — | — | — | [ | ||
9 | NCB | 0.84 | 0.00 | 0.00 | 58.97 | 98.60 | 0.00 | 0.00 | CB6+ NB | [ |
10 | 10.32 | 0.00 | 0.00 | 42.28 | 80.38 | 0.00 | 0.00 | NB + NB2 | ||
11 | 0.76 | 0.00 | 0.00 | 59.34 | — | — | — | CB6+ NB | [ | |
12 | 8.61 | 0.00 | 0.00 | 44.6 | — | — | — | NB + NB2 | ||
13 | NMB | 3.50 | 0.00 | 47.96 | 0.00 | 0.00 | 96.81 | 0.00 | MB6 + NB | [ |
14 | 7.20 | 0.00 | 42.74 | 0.00 | 0.00 | 93.44 | 0.00 | NB + NB2 | ||
15 | 3.52 | 0.00 | 47.95 | 0.00 | — | — | — | MB6 + NB | [ | |
16 | 7.16 | 0.00 | 42.76 | 0.00 | — | — | — | NB + NB2 | ||
F1 | KMCB | 0.00 | 0.14 | 4.73 | 55.21 | 91.89 | 7.87 | 0.23 | MB6 + KMB6 + CB6 | [ |
F2 | 0.00 | 0.61 | 4.66 | 56.05 | 91.41 | 7.60 | 0.99 | KB + KMB6 + CB6 | ||
F3 | NKCB | 0.74 | 1.50 | 0.00 | 57.76 | 96.27 | 0.00 | 2.50 | CB6 + NB + KB | [ |
F4 | 10.45 | 3.05 | 0.00 | 40.61 | 75.05 | 0.00 | 5.64 | NB + NB2 + KB | ||
F5 | NKMB | 3.42 | 0.22 | 47.21 | 0.00 | 0.00 | 92.84 | 0.43 | MB6 + NB+ KMB6 | [ |
F6 | 7.06 | 0.43 | 42.36 | 0.00 | 0.00 | 84.97 | 0.86 | NB + KMB6 + NB2 | ||
F7 | 8.06 | 3.81 | 36.13 | 0.00 | 0.00 | 75.27 | 7.94 | KMB6 + KB + NB2 | ||
F8 | NMCB | 0.59 | 0.00 | 5.89 | 54.16 | 89.31 | 9.71 | 0.00 | MB6 + CB6 + NB | [ |
E1 | NKMCB | 0.73 | 1.48 | 4.62 | 55.21 | 88.99 | 7.45 | 2.39 | NB + CB6 + KMB6 + KB | this work |
E2 | 6.66 | 3.31 | 28.10 | 6.97 | 15.48 | 62.39 | 7.35 | NB2 + NB + KMB6 + KB | ||
E3 | 0.54 | 0.21 | 4.84 | 55.15 | 90.80 | 7.96 | 0.35 | MB6 + KMB6 + NB + CB6 |
No. | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibrium solids | ||||||
---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | NaBr | KBr | H2O | MgBr2 | ||
1, F1 | 0.00 | 0.14 | 4.73 | 55.21 | 0.00 | 0.25 | 72.12 | 8.55 | MB6 + KMB6 + CB6 |
2, E3 | 0.54 | 0.21 | 4.84 | 55.15 | 0.96 | 0.38 | 70.22 | 8.65 | MB6 + KMB6 + NB + CB6 |
3, F8 | 0.59 | 0.00 | 5.89 | 54.16 | 1.08 | 0.00 | 71.89 | 10.76 | CB6 + NB + MB6 |
4 | 0.54 | 0.12 | 5.27 | 54.20 | 0.99 | 0.22 | 72.65 | 9.61 | CB6 + NB + MB6 |
5, F5 | 3.42 | 0.22 | 47.21 | 0.00 | 93.96 | 6.04 | 1350.27 | 1296.98 | NB + KMB6 + MB6 |
6 | 1.84 | 0.23 | 47.02 | 2.04 | 44.79 | 5.53 | 1192.56 | 1147.34 | NB + KMB6 + MB6 |
7 | 1.91 | 0.24 | 45.01 | 5.88 | 23.82 | 3.02 | 584.66 | 560.37 | NB + KMB6 + MB6 |
8 | 1.54 | 0.23 | 41.54 | 9.26 | 13.93 | 2.06 | 430.28 | 376.83 | NB + KMB6 + MB6 |
9 | 1.46 | 0.23 | 38.24 | 15.83 | 8.32 | 1.33 | 252.45 | 218.26 | NB + KMB6 + MB6 |
10 | 1.14 | 0.22 | 30.78 | 24.02 | 4.48 | 0.88 | 172.70 | 121.27 | NB + KMB6 + MB6 |
11 | 1.16 | 0.21 | 26.24 | 28.73 | 3.84 | 0.70 | 145.06 | 87.20 | NB + KMB6 + MB6 |
12 | 0.76 | 0.21 | 18.28 | 38.96 | 1.91 | 0.52 | 104.64 | 45.78 | NB + KMB6 + MB6 |
13 | 0.69 | 0.21 | 10.63 | 50.21 | 1.34 | 0.41 | 74.90 | 20.80 | NB + KMB6 + MB6 |
14 | 0.63 | 0.22 | 6.56 | 53.59 | 1.16 | 0.40 | 71.65 | 12.05 | NB + KMB6 + MB6 |
Table 2 Equilibrium liquid and solid phase composition in the quinary system NaBr-KBr-MgBr2-CaBr2-H2Oat 298.15 K and 0.0774 MPa (saturated with MgBr2·6H2O)
No. | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibrium solids | ||||||
---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | NaBr | KBr | H2O | MgBr2 | ||
1, F1 | 0.00 | 0.14 | 4.73 | 55.21 | 0.00 | 0.25 | 72.12 | 8.55 | MB6 + KMB6 + CB6 |
2, E3 | 0.54 | 0.21 | 4.84 | 55.15 | 0.96 | 0.38 | 70.22 | 8.65 | MB6 + KMB6 + NB + CB6 |
3, F8 | 0.59 | 0.00 | 5.89 | 54.16 | 1.08 | 0.00 | 71.89 | 10.76 | CB6 + NB + MB6 |
4 | 0.54 | 0.12 | 5.27 | 54.20 | 0.99 | 0.22 | 72.65 | 9.61 | CB6 + NB + MB6 |
5, F5 | 3.42 | 0.22 | 47.21 | 0.00 | 93.96 | 6.04 | 1350.27 | 1296.98 | NB + KMB6 + MB6 |
6 | 1.84 | 0.23 | 47.02 | 2.04 | 44.79 | 5.53 | 1192.56 | 1147.34 | NB + KMB6 + MB6 |
7 | 1.91 | 0.24 | 45.01 | 5.88 | 23.82 | 3.02 | 584.66 | 560.37 | NB + KMB6 + MB6 |
8 | 1.54 | 0.23 | 41.54 | 9.26 | 13.93 | 2.06 | 430.28 | 376.83 | NB + KMB6 + MB6 |
9 | 1.46 | 0.23 | 38.24 | 15.83 | 8.32 | 1.33 | 252.45 | 218.26 | NB + KMB6 + MB6 |
10 | 1.14 | 0.22 | 30.78 | 24.02 | 4.48 | 0.88 | 172.70 | 121.27 | NB + KMB6 + MB6 |
11 | 1.16 | 0.21 | 26.24 | 28.73 | 3.84 | 0.70 | 145.06 | 87.20 | NB + KMB6 + MB6 |
12 | 0.76 | 0.21 | 18.28 | 38.96 | 1.91 | 0.52 | 104.64 | 45.78 | NB + KMB6 + MB6 |
13 | 0.69 | 0.21 | 10.63 | 50.21 | 1.34 | 0.41 | 74.90 | 20.80 | NB + KMB6 + MB6 |
14 | 0.63 | 0.22 | 6.56 | 53.59 | 1.16 | 0.40 | 71.65 | 12.05 | NB + KMB6 + MB6 |
No. | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibrium solids | ||||||
---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | NaBr | KBr | H2O | CaBr2 | ||
1, F1 | 0.00 | 0.14 | 4.73 | 55.21 | 0.00 | 2.87 | 819.71 | 1133.68 | MB6 + KMB6 + CB6 |
2, E3 | 0.54 | 0.21 | 4.84 | 55.15 | 9.62 | 3.81 | 702.58 | 986.59 | MB6 + KMB6 + NB + CB6 |
3, F8 | 0.59 | 0.00 | 5.89 | 54.16 | 9.10 | 0.00 | 607.41 | 835.81 | MB6 + NB + CB6 |
4 | 0.54 | 0.12 | 5.27 | 54.20 | 9.16 | 2.00 | 671.35 | 914.00 | MB6 + NB + CB6 |
5, F2 | 0.00 | 0.61 | 4.66 | 56.05 | 0.00 | 11.57 | 733.97 | 1063.57 | KMB6 + KB + CB6 |
6 | 0.43 | 1.04 | 4.64 | 55.69 | 7.04 | 17.02 | 625.20 | 911.46 | KMB6 + KB + CB6 |
7, E1 | 0.73 | 1.48 | 4.62 | 55.21 | 10.69 | 21.67 | 555.78 | 808.35 | KMB6 + KB + NB + CB6 |
8, F3 | 0.74 | 1.50 | 0.00 | 57.76 | 33.04 | 66.96 | 1785.71 | 2578.57 | NB + KB + CB6 |
9 | 0.74 | 1.50 | 1.21 | 56.98 | 21.45 | 43.48 | 1146.96 | 1651.59 | NB + KB + CB6 |
10 | 0.74 | 1.50 | 2.56 | 56.01 | 15.42 | 31.25 | 816.46 | 1166.88 | NB + KB + CB6 |
11 | 0.74 | 1.49 | 3.66 | 55.89 | 12.56 | 25.30 | 648.90 | 648.90 | NB + KB + CB6 |
Table 3 Equilibrium liquid and solid phase composition in the quinary system NaBr-KBr-MgBr2-CaBr2-H2Oat 298.15 K and 0.0774 MPa (saturated with CaBr2·6H2O)
No. | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibrium solids | ||||||
---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | NaBr | KBr | H2O | CaBr2 | ||
1, F1 | 0.00 | 0.14 | 4.73 | 55.21 | 0.00 | 2.87 | 819.71 | 1133.68 | MB6 + KMB6 + CB6 |
2, E3 | 0.54 | 0.21 | 4.84 | 55.15 | 9.62 | 3.81 | 702.58 | 986.59 | MB6 + KMB6 + NB + CB6 |
3, F8 | 0.59 | 0.00 | 5.89 | 54.16 | 9.10 | 0.00 | 607.41 | 835.81 | MB6 + NB + CB6 |
4 | 0.54 | 0.12 | 5.27 | 54.20 | 9.16 | 2.00 | 671.35 | 914.00 | MB6 + NB + CB6 |
5, F2 | 0.00 | 0.61 | 4.66 | 56.05 | 0.00 | 11.57 | 733.97 | 1063.57 | KMB6 + KB + CB6 |
6 | 0.43 | 1.04 | 4.64 | 55.69 | 7.04 | 17.02 | 625.20 | 911.46 | KMB6 + KB + CB6 |
7, E1 | 0.73 | 1.48 | 4.62 | 55.21 | 10.69 | 21.67 | 555.78 | 808.35 | KMB6 + KB + NB + CB6 |
8, F3 | 0.74 | 1.50 | 0.00 | 57.76 | 33.04 | 66.96 | 1785.71 | 2578.57 | NB + KB + CB6 |
9 | 0.74 | 1.50 | 1.21 | 56.98 | 21.45 | 43.48 | 1146.96 | 1651.59 | NB + KB + CB6 |
10 | 0.74 | 1.50 | 2.56 | 56.01 | 15.42 | 31.25 | 816.46 | 1166.88 | NB + KB + CB6 |
11 | 0.74 | 1.49 | 3.66 | 55.89 | 12.56 | 25.30 | 648.90 | 648.90 | NB + KB + CB6 |
No. | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibrium solids | ||||||
---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | MgBr2 | CaBr2 | H2O | NaBr | ||
1, F4 | 10.45 | 3.05 | 0.00 | 40.61 | 0.00 | 93.01 | 105.11 | 23.93 | KB + NB + NB2 |
2 | 10.02 | 3.07 | 1.99 | 37.31 | 4.70 | 88.06 | 112.37 | 23.65 | KB + NB + NB2 |
3 | 9.86 | 3.10 | 4.02 | 34.20 | 9.73 | 82.77 | 118.15 | 23.86 | KB + NB + NB2 |
4 | 9.30 | 3.13 | 6.72 | 29.90 | 16.91 | 75.22 | 128.18 | 23.40 | KB + NB + NB2 |
5 | 8.85 | 3.16 | 8.87 | 26.32 | 23.13 | 68.63 | 137.68 | 23.08 | KB + NB + NB2 |
6 | 8.46 | 3.18 | 12.7 | 21.79 | 33.71 | 57.84 | 143.01 | 22.46 | KB + NB + NB2 |
7 | 7.99 | 3.21 | 15.77 | 18.97 | 41.55 | 49.99 | 142.45 | 21.05 | KB + NB + NB2 |
8 | 7.47 | 3.25 | 19.76 | 14.86 | 52.18 | 39.24 | 144.34 | 19.73 | KB + NB + NB2 |
9 | 7.01 | 3.29 | 24.33 | 10.60 | 63.66 | 27.73 | 143.30 | 18.34 | KB + NB + NB2 |
10, E2 | 6.66 | 3.31 | 28.10 | 6.97 | 73.22 | 18.16 | 143.20 | 17.35 | KB + NB + KMB6 + NB2 |
11, F7 | 8.06 | 3.81 | 36.13 | 0.00 | 90.46 | 0.00 | 130.20 | 20.18 | KB + KMB6 + NB2 |
12 | 7.40 | 3.64 | 32.35 | 2.90 | 83.18 | 7.46 | 138.11 | 19.03 | KB + KMB6 + NB2 |
13 | 6.98 | 3.50 | 30.30 | 4.83 | 78.44 | 12.50 | 140.80 | 18.07 | KB + KMB6 + NB2 |
14, F6 | 7.06 | 0.43 | 42.36 | 0.00 | 99.00 | 0.00 | 117.20 | 16.50 | NB + KMB6 + NB2 |
Table 4 Equilibrium liquid and solid phase composition in the quinary system NaBr-KBr-MgBr2-CaBr2-H2Oat 298.15 K and 0.0774 MPa (saturated with NaBr·2H2O)
No. | Composition of liquid phase w(B)/% | Jänecke index of dry slat J/(g/100 g) | Equilibrium solids | ||||||
---|---|---|---|---|---|---|---|---|---|
NaBr | KBr | MgBr2 | CaBr2 | MgBr2 | CaBr2 | H2O | NaBr | ||
1, F4 | 10.45 | 3.05 | 0.00 | 40.61 | 0.00 | 93.01 | 105.11 | 23.93 | KB + NB + NB2 |
2 | 10.02 | 3.07 | 1.99 | 37.31 | 4.70 | 88.06 | 112.37 | 23.65 | KB + NB + NB2 |
3 | 9.86 | 3.10 | 4.02 | 34.20 | 9.73 | 82.77 | 118.15 | 23.86 | KB + NB + NB2 |
4 | 9.30 | 3.13 | 6.72 | 29.90 | 16.91 | 75.22 | 128.18 | 23.40 | KB + NB + NB2 |
5 | 8.85 | 3.16 | 8.87 | 26.32 | 23.13 | 68.63 | 137.68 | 23.08 | KB + NB + NB2 |
6 | 8.46 | 3.18 | 12.7 | 21.79 | 33.71 | 57.84 | 143.01 | 22.46 | KB + NB + NB2 |
7 | 7.99 | 3.21 | 15.77 | 18.97 | 41.55 | 49.99 | 142.45 | 21.05 | KB + NB + NB2 |
8 | 7.47 | 3.25 | 19.76 | 14.86 | 52.18 | 39.24 | 144.34 | 19.73 | KB + NB + NB2 |
9 | 7.01 | 3.29 | 24.33 | 10.60 | 63.66 | 27.73 | 143.30 | 18.34 | KB + NB + NB2 |
10, E2 | 6.66 | 3.31 | 28.10 | 6.97 | 73.22 | 18.16 | 143.20 | 17.35 | KB + NB + KMB6 + NB2 |
11, F7 | 8.06 | 3.81 | 36.13 | 0.00 | 90.46 | 0.00 | 130.20 | 20.18 | KB + KMB6 + NB2 |
12 | 7.40 | 3.64 | 32.35 | 2.90 | 83.18 | 7.46 | 138.11 | 19.03 | KB + KMB6 + NB2 |
13 | 6.98 | 3.50 | 30.30 | 4.83 | 78.44 | 12.50 | 140.80 | 18.07 | KB + KMB6 + NB2 |
14, F6 | 7.06 | 0.43 | 42.36 | 0.00 | 99.00 | 0.00 | 117.20 | 16.50 | NB + KMB6 + NB2 |
1 | 宋彭生, 李武, 孙柏, 等. 盐湖资源开发利用进展[J]. 无机化学学报, 2011, 27(5): 801-815. |
Song P S, Li W, Sun B, et al. Recent development on comprehensive utilization of salt lake resources[J]. Chinese Journal of Inorganic Chemistry, 2011, 27(5): 801-815. | |
2 | 林耀庭. 我国卤水溴资源及其开发前景展望[J]. 盐湖研究, 2000, 8(2): 59-67. |
Lin Y T. Bromine resource in brines and its exploitation prospect[J]. Journal of Salt Lake Research, 2000, 8(2): 59-67. | |
3 | 张学平, 崔瑞芝, 桑世华. NaBr-CaBr2-H2O和KBr-CaBr2-H2O三元体系 273.15 K相平衡实验及计算[J]. 化工学报, 2021, 72(9): 4479-4486. |
Zhang X P, Cui R Z, Sang S H. Experiment and calculation of phase equilibrium in ternary systems NaBr-CaBr2-H2O and KBr-CaBr2-H2O at 273.15 K[J]. CIESC Journal, 2021, 72(9): 4479-4486. | |
4 | 林耀庭, 陈绍兰. 四川盆地地下卤水勘探开发前景展望[J]. 盐湖研究, 2008, 16(1): 1-7, 21. |
Lin Y T, Chen S L. Exploration and development prospect of underground brine in Sichuan basin[J]. Journal of Salt Lake Research, 2008, 16(1): 1-7, 21. | |
5 | 林耀庭, 姚有成, 康正华, 等. 四川宣达盐盆富钾富矿卤水地球化学特征及资源意义研究[J]. 盐湖研究, 2004, 12(1): 8-18. |
Lin Y T, Yao Y C, Kang Z H, et al. Study on the geochemical characteristics and resource significance of the highly mineralized potassium-rich brine in the Sichuan Xuanda salt basin[J]. Journal of Salt Lake Research, 2004, 12(1): 8-18. | |
6 | 陈向楠, 王海增. 溴素资源与产业发展分析[J]. 盐业与化工, 2013, 42(6): 4-7. |
Chen X N, Wang H Z. Bromine resource and analysis of the industry development[J]. Journal of Salt and Chemical Industry, 2013, 42(6): 4-7. | |
7 | 张婷婷, 桑世华. 低温下水盐体系相平衡研究进展[J]. 浙江化工, 2017, 48(3): 24-26. |
Zhang T T, Sang S H. Progress on phase equilibria of salt-water systems at low temperature[J]. Zhejiang Chemical Industry, 2017, 48(3): 24-26. | |
8 | 邬莉婷, 李晨, 陈鹏, 等. 三元体系NH4Cl-NaCl-H2O 298 K介稳相平衡研究[J]. 云南化工, 2020, 47(5): 39-42. |
Wu L T, Li C, Chen P, et al. Metastable phase equilibrium in the ternary system NH4Cl-NaCl-H2O at 298 K[J]. Yunnan Chemical Technology, 2020, 47(5): 39-42. | |
9 | 曹旭, 邓天龙, 李栋婵, 等. 含锂水盐体系相平衡研究进展[J]. 盐业与化工, 2009, 38(2): 36-40. |
Cao X, Deng T L, Li D C, et al. Progresses on the phase equilibria of lithium-containing salt-water system[J]. Journal of Salt and Chemical Industry, 2009, 38(2): 36-40. | |
10 | 张杰, 史学伟, 赵双良, 等. 水盐体系相平衡研究进展[J]. 化工学报, 2016, 67(2): 379-389. |
Zhang J, Shi X W, Zhao S L, et al. Progress in study on phase equilibria of salt-water systems[J]. CIESC Journal, 2016, 67(2): 379-389. | |
11 | Balarew C, Christov C, Valyashko V, et al. Thermodynamics of formation of carnallite type double salts[J]. Journal of Solution Chemistry, 1993, 22: 173-181. |
12 | Donchev S, Ismailov I, Parushev I, et al. Solubility in the NH4Br-CaBr2-H2O system at T = (298.15 and 323.15) K[J]. Research Journal of Pharmaceutical, Biological and Chemical Sciences, 2019, 10(5): 83-88. |
13 | Kartzmark E M. Solubilities in the system indium tribromide-sodium bromide-water at 25℃[J]. Canadian Journal of Chemistry, 1976, 54(12): 1884-1885. |
14 | Meng L Z, Li D, Guo Y F, et al. Experimental study on solid and liquid equilibria of the system MgCl2-MgBr2-MgSO4-H2O at 323.15 K [J]. Journal of Chemical & Engineering Data, 2013, 58(12): 3499-3503. |
15 | Charykova M V, Charykov N A. Thermodynamic model of natural brines accounting for the presence of trace components (Ⅱ): System Na+, K+, Mg2+ ‖Cl-, Br--H2O[J]. Geochemistry International, 2007, 45(10): 1040-1049. |
16 | 桑世华, 殷辉安, 倪师军, 等. 三元体系K2B4O7-KBr-H2O在298 K的相平衡研究[J]. 成都理工大学学报(自然科学版), 2006, 33(4): 414-416. |
Sang S H, Yin H A, Ni S J, et al. A study on equilibrium solubilities and properties of solutions in the ternary system K2B4O7-KBr-H2O at 298 K[J]. Journal of Chengdu University of Technology (Science & Technology Edition), 2006, 33(4): 414-416. | |
17 | Cui R Z, Li W, Dong Y P, et al. Measured and predicted solubility phase diagrams of quaternary systems LiBr-NaBr-MgBr2-H2O and LiBr-KBr-MgBr2-H2O at 298.15 K[J]. Chemical Research in Chinese Universities, 2020, 36(6): 1234-1240. |
18 | Cui R Z, Li W, Dong Y P, et al. Phase equilibrium and phase diagram for the quaternary system LiBr-NaBr-KBr-H2O at 298.15 K[J]. Journal of Chemical & Engineering Data, 2020, 65(6): 3021-3028. |
19 | Sang S H, Cui R Z, Hu J W, et al. Measurements of the solid-liquid equilibria in the quaternary system NaCl-NaBr-Na2SO4-H2O at 323 K[J]. Journal of Solution Chemistry, 2013, 42(8): 1633-1640. |
20 | Liu Q, Gao Y Y, Sang S H, et al. Solid-liquid equilibria in the quaternary systems NaBr-SrBr2-MgBr2-H2O and KBr-SrBr2-MgBr2-H2O at 323 K[J]. Journal of Chemical & Engineering Data, 2017, 62(4): 1264-1268. |
21 | Sang S H, Zhang H, Zhong S Y, et al. Experimental study of the solubilities of salts in the systems Na2B4O7-NaBr-H2O and Na2B4O7-Na2SO4-NaBr-H2O at 323 K[J]. Fluid Phase Equilibria, 2014, 361: 171-174. |
22 | Hu Y X, Sang S H, Cui R Z, et al. Solid-liquid equilibria in the quaternary system KCl-KBr-K2B4O7-H2O at 323 K[J]. Journal of Chemical & Engineering Data, 2014, 59(6): 1886-1891. |
23 | Nie G L, Sang S H, Cui R Z. Measurements of the solid-liquid phase equilibria in quinary system NaBr-KBr-MgBr2-SrBr2-H2O at 323 K[J]. Journal of Chemical & Engineering Data, 2019, 64(8): 3436-3443. |
24 | Hu J X, Sang S H, Zhou M F, et al. Phase equilibria in the ternary systems KBr-MgBr2-H2O and NaBr-MgBr2-H2O at 348.15 K[J]. Fluid Phase Equilibria, 2015, 392: 127-131. |
25 | Zhang K J, Sang S H, Li T, et al. Liquid-solid equilibria in the quaternary system KCl-KBr-K2SO4-H2O at 348 K[J]. Journal of Chemical & Engineering Data, 2013, 58(1): 115-117. |
26 | Hu J X, Sang S H, Liu Q Z. Measurements and calculations of the solid-liquid equilibria in the quaternary systems NaBr-KBr-MgBr2-H2O and NaBr-KBr-CaBr2-H2O at 348.15 K[J]. Journal of Solution Chemistry, 2015, 44(10): 1963-1975. |
27 | 桑世华, 崔瑞芝, 胡咏霞. 三元体系NaBr-Na2SO4-H2O和NaBr-KBr-H2O 373 K相平衡[J]. 高校化学工程学报, 2014, 28(5): 939-943. |
Sang S H, Cui R Z, Hu Y X. Phase equilibria of two ternary systems NaBr-Na2SO4-H2O and NaBr-KBr-H2O at 373 K[J]. Journal of Chemical Engineering of Chinese Universities, 2014, 28(5): 939-943. | |
28 | Cui R Z, Sang S H, Hu Y X. Solid-liquid equilibria in the quaternary systems KCl-KBr-K2B4O7-H2O and KCl-KBr-K2SO4-H2O at 373 K[J]. Journal of Chemical & Engineering Data, 2013, 58(2): 477-481. |
29 | 聂国亮, 桑世华, 崔瑞芝. 298 K和323 K条件下五元体系NaBr-KBr-MgBr2-CaBr2-H2O相平衡研究[J]. 化工学报, 2019, 70(9): 3267-3274. |
Nie G L, Sang S H, Cui R Z. Phase equilibria in quinary system NaBr-KBr-MgBr2-CaBr2-H2O at 298 K and 323 K[J]. CIESC Journal, 2019, 70(9): 3267-3274. | |
30 | Cui R Z, Wang Z C, Xu J S, et al. Measurements and calculations of solid-liquid equilibria in the quaternary system KBr-CaBr2-MgBr2-H2O at (298 and 323) K[J]. Fluid Phase Equilibria, 2017, 450: 140-148. |
31 | Nie G L, Sang S H, Cui R Z. Solid-liquid equilibrium phase diagram and calculation in the quaternary system (KBr + NaBr + MgBr2 + H2O) at 298 K[J]. Journal of Solution Chemistry, 2019, 48(6): 862-874. |
32 | Cui R Z, Sang S H, Li W, et al. (Solid + liquid) phase equilibria in the quaternary system (NaBr + MgBr2 + CaBr2 + H2O) at 298.15 K[J]. Journal of Chemical & Engineering Data, 2018, 63(9): 3400-3407. |
33 | Cui R Z, Sang S H, Li D W, et al. Measurements and calculations of solid-liquid equilibria in the quaternary system NaBr-KBr-CaBr2-H2O at 298 K[J]. Calphad, 2015, 49: 120-126. |
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