CIESC Journal ›› 2012, Vol. 63 ›› Issue (12): 4019-4027.DOI: 10.3969/j.issn.0438-1157.2012.12.040

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Synthesis and characterization of composite flocculant PAFS-CPAM by response surface methodology

ZHU Junren1, ZHENG Huaili1, ZHANG Zhi1, JIANG Zhenzhen1, GUAN Qingqing1, TAN Mingzhuo2, DAI Li1, CHEN Wei1   

  1. 1. Key Laboratory of the Three Gorges Reservoir Region’s Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, China;
    2. Jiangmen Wealth Water Purifying Agent Co., Jiangmen 529000, Guangdong, China
  • Received:2012-04-28 Revised:2012-07-23 Online:2012-09-04 Published:2012-12-05
  • Supported by:

    supported by the National Natural Science Foundation of China (51078366,21177164),the National Science and Technology Major Water Special Project in Water Pollution Control and Governance (2009ZX07315-002) and the Industrial Development Foundation of Chongqing(10-cxy-09).

响应面法优化制备PAFS-CPAM复合混凝剂及其表征

朱俊任1, 郑怀礼1, 张智1, 蒋贞贞1, 关庆庆1, 谭铭卓2, 戴力1, 陈伟1   

  1. 1. 重庆大学教育部三峡库区生态环境重点实验室, 重庆 400045;
    2. 江门慧信环保股份有限公司, 广东 江门 529000
  • 通讯作者: 郑怀礼
  • 作者简介:朱俊任(1984-),男,博士研究生。
  • 基金资助:

    国家自然科学基金项目(51078366,21177164);国家重大科技专项水体污染控制与治理(2009ZX07315-002);重庆市工业发展资金(产研专项)项目(10-cxy-09)。

Abstract: The composite flocculant was prepared by polymerizing CPAM(a cationic flocculant P:acrylamide-methacryloxyethyltrimethyl ammonium chloride-acryloxyethyltrimethyl ammonium chloride)and PFAS(polymeric aluminum ferric sulfate).The morphological distribution of Fe and Al was studied by using Ferron analysis,and the morphology of the copolymer was observed using scan electron microscopy.The Box-Behnken mathematical relational model between CODCr removal rate and affecting factors was established,and the technique composing PAFS-CPAM was optimized.The optimum synthesis conditions were: react temperature 61℃,react time 74 min,and Fe/CPAM mass ratio 28,respectively.At these optimized conditions and using 50 mg·L-1 PAFS-CPAM flocculant prepared,CODCr removal and turbidity removal rates were 80.86% and 97.50%,respectively.

Key words: response surface methodology, synthesis, composite flocculant, polymeric aluminum ferric sulfate, cationic polyacrylamide

摘要: 以聚合硫酸铝铁(PAFS)与阳离子聚丙烯酰胺(CPAM)为原料,制备PAFS-CPAM复合混凝剂。通过Ferron法对产物的铁铝形态分布进行定量分析,用扫描电镜对产物的结构进行表征。采用响应面分析法通过建立CODCr去除率与各因素之间的Box-Behnken数学模型,对复合PAFS-CPAM的工艺进行优化。PFAS/CPAM最优制备工艺条件为:反应温度、反应时间和Fe/CPAM质量比分别为61℃、74 min、28。在最佳投加量50 mg·L-1条件下,优化制备的PAFS-CPAM对生活污水CODCr去除率、浊度去除率分别达80.86%、97.50%。

关键词: 响应面法, 制备, 复合混凝剂, 聚合硫酸铝铁, 阳离子聚丙烯酰胺

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