CIESC Journal ›› 2023, Vol. 74 ›› Issue (7): 2717-2734.DOI: 10.11949/0438-1157.20230193

• Reviews and monographs • Previous Articles     Next Articles

Advances in the design, synthesis and application of calcium-based catalysts

Yuming TU(), Gaoyan SHAO, Jianjie CHEN, Feng LIU, Shichao TIAN, Zhiyong ZHOU, Zhongqi REN()   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2023-03-06 Revised:2023-07-05 Online:2023-08-31 Published:2023-07-05
  • Contact: Zhongqi REN

钙基催化剂的设计合成及应用研究进展

涂玉明(), 邵高燕, 陈健杰, 刘凤, 田世超, 周智勇, 任钟旗()   

  1. 北京化工大学化工资源有效利用国家重点实验室,北京 100029
  • 通讯作者: 任钟旗
  • 作者简介:涂玉明(1995—),男,博士研究生,tuyumingbuct@yeah.net
  • 基金资助:
    国家自然科学基金项目(22125802)

Abstract:

Calcium-based catalyst are solid base catalyst with calcium oxides as metal active sites. It has the advantages of being green and efficient, cheap and easy to obtain, and has good catalytic performance. It can be widely used in the fields of biodiesel preparation, wastewater treatment, and tar cracking and reforming. They have received more and more attention from researchers all over the world. This article introduces the types of calcium-based catalysts, their application research status and mechanism of action, outlines their research progress in various applications, and analyzes and summarizes the history and trends of calcium-based catalyst design and synthesis ideas. From natural calcium-based catalysts such as CaO and Ca(OH)2 to actively designed and synthesized loaded Ca-containing catalyst, it is pointed out that the synthesis of stable and efficient calcium-based catalysts is the key to realize their further development. Finally, the research progress of calcium-based catalysts is summarized and its future development and application prospects are prospected.

Key words: calcium, catalyst, catalytic oxidation, catalytic cracking, biodiesel synthesis

摘要:

钙基催化剂是以钙氧化物为金属活性位点的固体碱催化剂,具有绿色高效、廉价易得等优点,有较好的催化性能,可广泛应用于生物柴油制备、废水处理和焦油裂解重整等领域,已受到国内外研究者们越来越广泛的关注。主要介绍了钙基催化剂类型、应用研究现状及作用机理,概述了其在各个领域的研究进展,分析归纳了钙基催化剂设计合成思路的历程和趋势:从CaO、Ca(OH)2等天然钙基催化剂到主动设计合成的负载型含Ca催化剂,指出了稳定高效钙基催化剂的设计合成是其实现进一步发展的关键。最后对钙基催化剂研究进展进行归纳总结,并对其未来发展及应用前景进行了展望。

关键词: 钙, 催化剂, 催化氧化, 催化裂解, 生物柴油合成

CLC Number: