Investigation of performance of SrFe0.6Cu0.3Ti0.1O3-δ mixed conducting membrane for partial oxidation of methane to syngas

doi:10.3969/j.issn.0438-1157.2014.05.015

Abstract

Abstract: SrFe_0.6Cu_0.3Ti_0.1O₃_-δ membrane was used to install a membrane reactor for partial oxidation of methane to syngas. The influences of temperature, space velocity and catalyst particle size on the reaction were studied, and the change of the phase structure of the membrane was analyzed. The interaction between the oxygen permeating process and the partial oxidation reaction caused different reaction performance in membrane reactor compared with fixed bed reactor. The crystallinity of both sides of the SrFe_0.6Cu_0.3Ti_0.1O₃_-δ membrane declined significantly after the catalytic reaction. The decomposition of the perovskite structure and the formation of SrCO₃ and other phases were found in the reaction-side surface of the membrane, along with the emergence of loose porous morphology.

Key words: methane, syngas, oxygen permeation, mixed conductor, perovskite, stability

摘要： 采用SrFe_0.6Cu_0.3Ti_0.1O₃_-δ混合导体透氧膜组装成膜催化反应器，进行甲烷部分氧化制合成气反应，考察了反应温度、空速、催化剂粒径等条件的影响，并分析了反应气氛引起的透氧膜结构变化情况。结果表明，在膜反应器内，催化反应与透氧过程存在相互制约和相互促进的关系。在膜反应器内进行甲烷部分氧化反应后，透氧膜的两侧表面均发生蚀刻现象，结晶度显著降低，反应侧蚀刻现象较为严重，膜表面形成了疏松的多孔层，反应气氛使膜表面晶体结构发生了较大改变，Sr容易从钙钛矿结构中析出并与CO₂结合形成SrCO₃，Sr的析出导致组成不平衡，促进了钙钛矿结构分解及其他物相的产生。

关键词: 甲烷, 合成气, 透氧, 混合导体, 钙钛矿, 稳定性

CLC Number:

TQ174

ZHANG Heng, WANG Tingting, NIE Yi, ZHANG Xiangping, LIN Weiming. Investigation of performance of SrFe_0.6Cu_0.3Ti_0.1O₃_-_δ mixed conducting membrane for partial oxidation of methane to syngas[J]. CIESC Journal, DOI: 10.3969/j.issn.0438-1157.2014.05.015.

张恒, 王婷婷, 聂毅, 张香平, 林维明. SrFe_0.6Cu_0.3Ti_0.1O_3-δ透氧膜反应器中甲烷部分氧化反应工艺及膜稳定性考察[J]. 化工学报, DOI: 10.3969/j.issn.0438-1157.2014.05.015.

References 34

[1]	Cheng Xu(程序), Cui Zongjun(崔宗均), Zhu Wanbin(朱万斌). A discussion on the exploitation of biogas: another kind of unconventional natural gas resources[J]. Natural Gas Industry (天然气工业), 2013, 33(1): 137-144
[2]	Liu Chang(刘畅), Lu Xiaohua(陆小华). Carbon reduction pattern in China: comparison of CCS and biomethane route[J]. CIESC Journal (化工学报), 2013, 64(1): 7-10
[3]	Choudhary T V, Choudhary V R. Energy-efficient syngas production through catalytic oxy-methane reforming reactions[J]. Angewandte Chemie, International Edition, 2008, 47(10):1828-1847
[4]	Hickman D A, Schmidt L D. Production of syngas by direct catalytic oxidation of methane[J]. Science, 1993, 259(5093): 343-346
[5]	Bharadwaj S S, Schmidt L D. Catalytic partial oxidation of natural gas to syngas[J]. Fuel Processing Technology, 1995, 42(2/3): 109-127
[6]	Pena M A, Gomez J P, Fierro J L G. New catalytic routes for syngas and hydrogen production[J]. Applied Catalysis A: General, 1996, 144(1/2): 7-57
[7]	Wu Zhentao(吴振涛), Zhang Chun(张春), Chang Xianfeng(常先锋), Jin Wanqin(金万勤), Xu Nanping(徐南平). Properties of novel Al2O3-doped SrCo0.8Fe0.2O3-δ mixed conducting oxides[J]. Journal of Chemical Industry and Engineering(China) (化工学报), 2006, 57(8):1979-1985
[8]	Hashim S M, Mohamed A R, Bhatia S. Current status of ceramic-based membranes for oxygen separation from air[J]. Advances in Colloid and Interface Science, 2010, 160:88-100
[9]	Sunarso J, Baumann S, Serra J M, Meulenberg W A, Liu S, Lin Y S, Diniz da Costa J C. Mixed ionic-electronic conducting (MIEC) ceramic-based membranes for oxygen separation[J]. Journal of Membrane Science, 2008, 320:13-41
[10]	Zhu Xuefeng(朱雪峰), Yang Weishen(杨维慎). Mixed conductor oxygen permeable membrane reactors[J]. Chinese Journal of Catalysis (催化学报), 2009, 30(8): 801-816
[11]	Gallucci F, Fernandez E, Corengia P, Annaland M S. Recent advances on membranes and membrane reactors for hydrogen production[J]. Chemical Engineering Science, 2013, 92(5):40-66
[12]	Geffroy P M, Fouletier J, Richet N, Chartier T. Rational selection of MIEC materials in energy production processes[J]. Chemical Engineering Science, 2013, 87:408-433
[13]	Wei Y, Yang W, Caro J, Wang H. Dense ceramic oxygen permeable membranes and catalytic membrane reactors[J]. Chemical Engineering Journal, 2013, 220:185-203
[14]	Teraoka Y, Zhang H M, Furukawa S, Yamazoe N. Oxygen permeation through perovskite-type oxides[J]. Chemistry Letters, 1985, 9: 1743-1746
[15]	Pei S, Kleefisch M S, Kobylinski T P, Faber J, Udovich C A, Zhang-McCoy V, Dabrowski B, Balachandran U, Mieville R L, Poeppel R B. Failure mechanisms of ceramic membrane reactors in partial oxidation of methane to synthesis gas[J]. Catalysis Letters, 1995, 30(1/2/3/4): 201-212
[16]	Shao Z P, Xiong G X, Tong J H, Dong H, Yang W S. Ba effect in doped Sr(Co0.8Fe0.2)O3-δ on the phase structure and oxygen permeation properties of the dense ceramic membranes[J]. Separation and Purification Technology, 2001, 25: 419-429
[17]	Shao Z P, Yang W S, Cong Y, Dong H, Tong J H, Xiong G X. Investigation of the permeation behavior and stability of a Ba0.5Sr0.5Co0.8Fe0.2O3-δ oxygen membrane[J]. Journal of Membrane Science, 2000, 172(1/2): 177-188
[18]	Dong H, Shao Z P, Xiong G X, Tong J H, Sheng S S, Yang W S. Investigation on POM reaction in a new perovskite membrane reactor[J]. Catalysis Today, 2001, 67: 3-13
[19]	Tong J H, Yang W S, Cai R, Zhu B C, Lin L W. Novel and ideal zirconium-based dense membrane reactors for partial oxidation of methane to syngas[J]. Catalysis Letters, 2002, 78(1/2/3/4): 129-137
[20]	Tong J H, Yang W S, Zhu B C, Cai R. Investigation of ideal zirconium- doped perovskite- type ceramic membrane materials for oxygen separation[J]. Journal of Membrane Science, 2002, 203(1/2): 175-189
[21]	Balachandran U, Dusek J T, Mileville R L, Poeppel R B, Kleefisch M S, Pei S, Kobylinski T P, Udovich C A, Bose A C. Dense ceramic membranes for partial oxidation of methane to syngas[J]. Applied Catalysis A: General, 1995, 133(1): 19-29
[22]	Balachandran U, Dusek J T, Maiya P S, Ma B, Mieville R L, Kleefisch M S, Udovich C A. Ceramic membrane reactor for converting membrane to syngas[J]. Catalysis Today, 1997, 36: 265-272
[23]	Bouwmeester H J M. Dense ceramic membranes for methane conversion[J]. Catalysis Today, 2003, 82(1/2/3/4): 141-150
[24]	Ishihara T, Takaaki S, Honda M, Nishiguchi H, Takita Y. Intermediate temperature solid oxide fule cell using LaGaO3 electrolyte[J]. Journal of the Electrochemical Society, 2000, 147(4): 1332-1337
[25]	Tsuruta Y, Todaka T, Nisiguchi H, Ishiharaz T, Takita Y. Mixed electronic-oxide ionic conductor of Fe-doped La(Sr)GaO3 perovskite oxide for oxygen permeating membrane[J]. Electrochemical and Solid State Letters, 2001, 4(3): 13-15
[26]	Wang H H, Tablet C, Feldhoff A, Caro J. A cobalt- free oxygen- permeable membrane based on the perovskite- type oxide Ba0.5Sr0.5Zn0.2Fe0.8O3-δ [J]. Advanced Materials, 2005, 17(14): 1785-1788
[27]	Zhu X F, Wang H H, Yang W S. Structural stability and oxygen permeability of cerium lightly doped BaFeO3-δ ceramic membranes [J]. Solid State Ionics, 2006, 177(33/34): 2917-2921
[28]	Teraoka Y, Shimokawa H, Kang Ch Y, Kusaba H, Sasaki K. Fe-based perovskite-type oxides as excellent oxygen-permeableband reduction-tolerant materials[J]. Solid State Ionics, 2006, 177(26-32): 2245-2248
[29]	Zhang H, Wang T T, Dong X F, Lin W M. Preparation and oxygen permeation properties of SrFe(Cu)O3-d dense ceramic membranes[J]. Journal of Natural Gas Chemistry, 2009, 18(1):45-49
[30]	Zhang Heng(张恒), Wang Tingting(王婷婷), Lin Weiming(林维明). Stability of SrFe0.6Cu0.3Ti0.1O3-δ mixed conducting membrane material[J]. Chinese Journal of Applied Chemistry (应用化学), 2009, 26(11):1328-1331
[31]	Efimov K, Halfer T, Kuhn A, Heitjans P, Caro J, Feldhoff A. Novel cobalt-free oxygen-permeable perovskite-type membrane[J]. Chemistry of Materials, 2010, 22(4): 1540-1544
[32]	Qi Xinbing(齐心冰), Dong Xinfa(董新法), Lin Weiming(林维明). Steam reforming and partial oxidation of methane to produce syngas[J]. Natural Gas Industry (天然气工业), 2005, 25(6):125-127
[33]	Hu J, Xing T L, Jia Q C, Hao H S, Yang D L, Guo Y Q, Hu X. Methane partial oxidation to syngas in YBa2Cu3O7-x membrane reactor[J]. Applied Catalysis A: General, 2006, 306: 29-33
[34]	Tsai C, Dixon A G, Ma Y H, Moser W R, Pascucci M. Dense perovskite membrane reactors for partial oxidation of methane to syngas[J]. Journal of the American Ceramic Society, 1998, 81: 1437-1444

Investigation of performance of SrFe_0.6Cu_0.3Ti_0.1O₃_-_δ mixed conducting membrane for partial oxidation of methane to syngas

SrFe_0.6Cu_0.3Ti_0.1O_3-δ透氧膜反应器中甲烷部分氧化反应工艺及膜稳定性考察

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 34

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	He JIANG, Junfei YUAN, Lin WANG, Guyu XING. Experimental study on the effect of flow sharing cavity structure on phase change flow characteristics in microchannels [J]. CIESC Journal, 2023, 74(S1): 235-244.
[2]	Xiaoxiong FAN, Lifang HAO, Chuigang FAN, Songgeng LI. Study on the catalytic denitrification performance of low-temperature NH₃-SCR over LaMnO₃/biochar catalyst [J]. CIESC Journal, 2023, 74(9): 3821-3830.
[3]	Lingding MENG, Ruqing CHONG, Feixue SUN, Zihui MENG, Wenfang LIU. Immobilization of carbonic anhydrase on modified polyethylene membrane and silica [J]. CIESC Journal, 2023, 74(8): 3472-3484.
[4]	Yu FU, Xingchong LIU, Hanyu WANG, Haimin LI, Yafei NI, Wenjing ZOU, Yue LEI, Yongshan PENG. Research on F₃EACl modification layer for improving performance of perovskite solar cells [J]. CIESC Journal, 2023, 74(8): 3554-3563.
[5]	Yuyuan ZHENG, Zhiwei GE, Xiangyu HAN, Liang WANG, Haisheng CHEN. Progress and prospect of medium and high temperature thermochemical energy storage of calcium-based materials [J]. CIESC Journal, 2023, 74(8): 3171-3192.
[6]	Xiaoyang LIU, Jianliang YU, Yujie HOU, Xingqing YAN, Zhenhua ZHANG, Xianshu LYU. Effect of spiral microchannel on detonation propagation of hydrogen-doped methane [J]. CIESC Journal, 2023, 74(7): 3139-3148.
[7]	Chao NIU, Shengqiang SHEN, Yan YANG, Bonian PAN, Yiqiao LI. Flow process calculation and performance analysis of methane BOG ejector [J]. CIESC Journal, 2023, 74(7): 2858-2868.
[8]	Xiaowen ZHOU, Jie DU, Zhanguo ZHANG, Guangwen XU. Study on the methane-pulsing reduction characteristics of Fe₂O₃-Al₂O₃ oxygen carrier [J]. CIESC Journal, 2023, 74(6): 2611-2623.
[9]	Bin CAI, Xiaolin ZHANG, Qian LUO, Jiangtao DANG, Liyuan ZUO, Xinmei LIU. Research progress of conductive thin film materials [J]. CIESC Journal, 2023, 74(6): 2308-2321.
[10]	Lei MAO, Guanzhang LIU, Hang YUAN, Guangya ZHANG. Efficient preparation of carbon anhydrase nanoparticles capable of capturing CO₂ and their characteristics [J]. CIESC Journal, 2023, 74(6): 2589-2598.
[11]	Wenchao XU, Zhigao SUN, Cuimin LI, Juan LI, Haifeng HUANG. Effect of surfactant E-1310 on the formation of HCFC-141b hydrate under static conditions [J]. CIESC Journal, 2023, 74(5): 2179-2185.
[12]	Zefeng GE, Yuqing WU, Mingxun ZENG, Zhenting ZHA, Yuna MA, Zenghui HOU, Huiyan ZHANG. Effect of ash chemical components on biomass gasification properties [J]. CIESC Journal, 2023, 74(5): 2136-2146.
[13]	Zijian WANG, Ming KE, Jiahan LI, Shuting LI, Jinru SUN, Yanbing TONG, Zhiping ZHAO, Jiaying LIU, Lu REN. Progress in preparation and application of short b-axis ZSM-5 molecular sieve [J]. CIESC Journal, 2023, 74(4): 1457-1473.
[14]	Runzhu LIU, Tiantian CHU, Xiaoa ZHANG, Chengzhong WANG, Junying ZHANG. Synthesis and properties of phenylene-containing α,ω-hydroxy-terminated fluorosilicone polymers [J]. CIESC Journal, 2023, 74(3): 1360-1369.
[15]	Han HU, Liang YANG, Chunxiao LI, Daoping LIU. Kinetics of methane storage in the natural tobacco leaching filtrate in the hydrate form [J]. CIESC Journal, 2023, 74(3): 1313-1321.