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Research on modification of inorganic materials by ionic liquid and preparation of rubber additives enhancing thermal conductivity

ZHAO Mingming1,WANG Shaojun1,LU Yang1,SONG Yunbao2,Fu Quan2   

  1. 1School of Light Industry and Chemical Engineering,Dalian Polytechnic University,Dalian 116034,Liaoning,China;2Dalian Tianbao Chemical Industry Co.,Ltd.,Dalian 116300,Liaoning,China
  • Online:2014-08-25 Published:2014-08-05

离子液体改性无机材料制备橡胶导热助剂

赵明明1,王少君1,卢阳1,宋云保2,付泉2   

  1. 1大连工业大学轻工与化学工程学院,辽宁 大连 116034;2大连天宝化学工业有限公司,辽宁 大连 116300

Abstract: The modification of white carbon black,bentonite,kaolin,diatomaceous earth and perlite (deep and shallow) six different inorganic materials loaded with [C4mim]Br,[C7mim]Br,[C8mim]Br and [BPy]Br four ionic liquids was studied. FT-IR,TG and nitrogen adsorption-desorption of the specific surface area of these inorganic materials before and after modification were conducted. These modified inorganic fillers were then kneaded into rubber separately,and the thermal conductivity coefficients of rubber were measured. The thermal conductivity coefficients of these six kinds of inorganic materials modified by ionic liquids were all greater than those before modification. Wherein,the thermal conductivity coefficients of all these inorganic materials modified by [C4mim]Br increased the most. The thermal conductivity coefficient of Kaolin modified by [C4mim]Br was the highest,up to 0.389 W/(m?K),89.76% greater than the unmodified.

Key words: ionic liquids, inorganic materials, thermal conductivity, preparation

摘要: 通过研究[C4mim]Br、[C7mim]Br、[C8mim]Br、[BPy]Br共4种离子液体对白炭黑、膨润土、高岭土、硅藻土、珍珠岩(深、浅色)共6种不同无机材料进行改性,并对改性前后的无机材料进行了FT-IR、TG和氮气吸附-脱附比表面积分析。应用改性后的无机材料与橡胶混炼制胶,测定其导热系数。结果表明,无机材料经离子液体改性后均比未改性的导热系数有所提高,其中,[C4mim]Br改性无机材料的导热系数提高幅度最大,[C4mim]Br改性的高岭土的导热系数高达0.389W/(m?K),与改性前的导热系数相比提高了89.76%。

关键词: 离子液体, 无机材料, 热传导, 制备