Synthesis of cinnamic acid-based ionic liquids and application in CO2 absorption

doi:10.11949/j.issn.0438-1157.20151217

CIESC Journal ›› 2016, Vol. 67 ›› Issue (2): 623-626.DOI: 10.11949/j.issn.0438-1157.20151217

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Synthesis of cinnamic acid-based ionic liquids and application in CO₂ absorption

CHEN Kaihong¹, MEI Ke¹, LI Haoran^1,2, WANG Congmin^1,3

1 Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, China;
2 State Key Laboratory of Chemical Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China;
3 Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University, Hangzhou 310027, Zhejiang, China

Received:2015-07-29 Revised:2015-11-04 Online:2016-02-05 Published:2016-02-05
Supported by:
supported by the National Basic Research Program of China (2015CB251401) and the National Natural Science Foundation of China (21322602, 21176205).

肉桂酸型离子液体的合成及其二氧化碳吸收

陈凯宏¹, 梅柯¹, 李浩然^1,2, 王从敏^1,3

1 浙江大学化学系, 浙江杭州 310027;
2 化学工程联合国家重点实验室(浙江大学), 浙江杭州 310027;
3 生物质化工教育部重点实验室(浙江大学), 浙江杭州 310027

通讯作者: 王从敏
基金资助:
国家重点基础研究发展计划项目(2015CB251401);国家自然科学基金项目(21322602,21176205)。

Abstract

Abstract:

A series of cinnamic acid-based ionic liquids [P66614][CIN] were prepared and applied in the CO₂ absorption. The results showed that the cinnamic acid-based ionic liquids exhibited good CO₂ absorption performance. The CO₂ absorption ability was influenced by the substituent in the cinnamic acid. The CO₂ absorption capacity would decrease with increasing temperature or decreasing pressure. Furthermore, these ionic liquids exhibited excellent reversibility since higher CO₂ absorption capacity can be maintained after 5 times of absorption/desorption circulation. The results of a combination of FT-IR spectrum and CO₂ absorption under 10% CO₂ indicated that CO₂ was absorbed by chemisorption.

Key words: ionic liquids, carbon dioxide, cinnamic acid, absorption, functionalized

摘要：

合成了一系列肉桂酸型功能化离子液体,研究了其CO₂ 吸收性能。结果表明,肉桂酸型功能化离子液体吸收二氧化碳性能良好,其阴离子苯环上的取代基会影响CO₂ 吸收性能。随着温度的升高和压力的降低,其CO₂吸收性能都会降低。同时,该离子液体具有很好的循环稳定性,经过5 次吸收脱附循环,该离子液体仍能保持较高的CO₂ 吸收量。结合红外光谱和其低浓度下CO₂ 的吸收研究发现肉桂酸型离子液体吸收CO₂ 存在着化学作用。

关键词: 离子液体, 二氧化碳, 肉桂酸, 吸收, 功能化

CLC Number:

TQ028.8

CHEN Kaihong, MEI Ke, LI Haoran, WANG Congmin. Synthesis of cinnamic acid-based ionic liquids and application in CO₂ absorption[J]. CIESC Journal, 2016, 67(2): 623-626.

陈凯宏, 梅柯, 李浩然, 王从敏. 肉桂酸型离子液体的合成及其二氧化碳吸收[J]. 化工学报, 2016, 67(2): 623-626.

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Synthesis of cinnamic acid-based ionic liquids and application in CO₂ absorption

肉桂酸型离子液体的合成及其二氧化碳吸收

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