CIESC Journal ›› 2020, Vol. 71 ›› Issue (11): 5200-5207.DOI: 10.11949/0438-1157.20200091
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Huixia MA1(),Feng ZHOU1(),Guang WU2,Jie FU3,Kai QIAO1
Received:
2020-01-21
Revised:
2020-05-28
Online:
2020-11-05
Published:
2020-11-05
Contact:
Feng ZHOU
通讯作者:
周峰
作者简介:
马会霞(1987—),女,硕士,助理研究员,基金资助:
CLC Number:
Huixia MA,Feng ZHOU,Guang WU,Jie FU,Kai QIAO. Catalytic fast pyrolysis of biomass to aromatics over hierarchical HZSM-5[J]. CIESC Journal, 2020, 71(11): 5200-5207.
马会霞,周峰,武光,傅杰,乔凯. 多级孔HZSM-5分子筛催化快速热解生物质制芳烃[J]. 化工学报, 2020, 71(11): 5200-5207.
编号 | Si/Al① | 比表面积/(m2/g) | 孔容/(cm3/g) | ||||
---|---|---|---|---|---|---|---|
BET② | 微孔③ | 外比表面③ | 总孔容④ | 微孔⑤ | 介孔⑤ | ||
HZ | 38.6 | 277.2 | 222.5 | 54.7 | 0.15 | 0.09 | 0.06 |
HZ-H | 41.6 | 302.9 | 236.2 | 66.7 | 0.18 | 0.11 | 0.07 |
HZ-OH | 34.7 | 376.6 | 201.6 | 175.0 | 0.24 | 0.09 | 0.15 |
HZ-H/OH | 39.6 | 408.9 | 253.2 | 155.7 | 0.22 | 0.10 | 0.12 |
HZ-OH/H | 37.8 | 332.7 | 246.3 | 86.4 | 0.20 | 0.10 | 0.10 |
Table 1 Si/Al ratio, specific surface area and pore volume of the hierarchical HZSM-5 molecular sieve
编号 | Si/Al① | 比表面积/(m2/g) | 孔容/(cm3/g) | ||||
---|---|---|---|---|---|---|---|
BET② | 微孔③ | 外比表面③ | 总孔容④ | 微孔⑤ | 介孔⑤ | ||
HZ | 38.6 | 277.2 | 222.5 | 54.7 | 0.15 | 0.09 | 0.06 |
HZ-H | 41.6 | 302.9 | 236.2 | 66.7 | 0.18 | 0.11 | 0.07 |
HZ-OH | 34.7 | 376.6 | 201.6 | 175.0 | 0.24 | 0.09 | 0.15 |
HZ-H/OH | 39.6 | 408.9 | 253.2 | 155.7 | 0.22 | 0.10 | 0.12 |
HZ-OH/H | 37.8 | 332.7 | 246.3 | 86.4 | 0.20 | 0.10 | 0.10 |
编号 | 脱附峰/℃ | 酸量/(mmol/g) | ||||
---|---|---|---|---|---|---|
LT- peak | HT- peak | 总酸量 | 弱酸 | 强酸 | 强酸/总酸 | |
HZ | 198 | 395 | 1.19 | 0.48 | 0.71 | 0.59 |
HZ-H | 189 | 394 | 0.80 | 0.29 | 0.51 | 0.63 |
HZ-OH | 194 | 396 | 1.23 | 0.50 | 0.73 | 0.59 |
HZ-H/OH | 189 | 390 | 0.97 | 0.38 | 0.59 | 0.60 |
HZ-OH/H | 183 | 396 | 1.11 | 0.54 | 0.57 | 0.50 |
Table 2 NH3-TPD data and acid amount for hierarchical HZSM-5 prepared by acid and/or alkali treatment
编号 | 脱附峰/℃ | 酸量/(mmol/g) | ||||
---|---|---|---|---|---|---|
LT- peak | HT- peak | 总酸量 | 弱酸 | 强酸 | 强酸/总酸 | |
HZ | 198 | 395 | 1.19 | 0.48 | 0.71 | 0.59 |
HZ-H | 189 | 394 | 0.80 | 0.29 | 0.51 | 0.63 |
HZ-OH | 194 | 396 | 1.23 | 0.50 | 0.73 | 0.59 |
HZ-H/OH | 189 | 390 | 0.97 | 0.38 | 0.59 | 0.60 |
HZ-OH/H | 183 | 396 | 1.11 | 0.54 | 0.57 | 0.50 |
编号 | CFP产物产率/% | |||
---|---|---|---|---|
芳烃 | CO+CO2 | 烯烃 | 焦炭 | |
HZ | 23.0 | 22.4 | 7.6 | 47.0 |
HZ-OH/H | 30.8 | 27.8 | 7.1 | 34.3 |
Table 3 Yield distribution for rice straw CFP products
编号 | CFP产物产率/% | |||
---|---|---|---|---|
芳烃 | CO+CO2 | 烯烃 | 焦炭 | |
HZ | 23.0 | 22.4 | 7.6 | 47.0 |
HZ-OH/H | 30.8 | 27.8 | 7.1 | 34.3 |
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