Phase equilibria for ternary system CsCl-PEG8000-H2O at 288.2, 298.2 and 308.2 K

doi:10.11949/0438-1157.20201720

Abstract

Abstract:

The phase equilibrium relationship of the ternary system CsCl-PEG8000-H₂O at 288.2, 298.2 and 308.2 K was studied by isothermal dissolution method and turbidimetric method. Meanwhile, the empirical equations were used to fit the data of binodal curve and tie line. Based on the experimental data, the completed phase diagrams at 288.2, 298.2 and 308.2 K were plotted. According to the experimental results, both solid-liquid equilibrium and liquid-liquid equilibrium coexisted in the ternary systems CsCl-PEG8000-H₂O at T = 288.2, 298.2 and 308.2 K. The corresponding phase diagrams at three temperature all composed of 6 regions: unsaturated liquid phase (L), two regions of one liquid and one solid phase CsCl (L+S), region of two-liquids phase (2L), two liquids with one solid CsCl (2L+S), and region of one liquid with two solids of CsCl and PEG8000 (L+2S). Comparing the phase diagrams CsCl-PEG8000-H₂O at T = 288.2, 298.2 and 308.2 K, it can be concluded that with the temperature increase, the areas of (L), (2L), (L+S) and (2L+S) increased, while the area of (2S+L) decreased. Comparing the phase diagrams CsCl-PEG1000/4000/6000/8000-H₂O at T = 288.2, 298.2 and 308.2 K, it can be found that there is only solid-liquid equilibrium in the ternary system CsCl-PEG1000-H₂O at 288.2 and 298.2 K, while the solid-liquid and liquid-liquid equilibria were found in the systems CsCl-PEG4000/6000/8000-H₂O at 288.2 and 298.2 K. Both solid-liquid and liquid-liquid equilibria were found in ternary systems CsCl-PEG1000/4000/6000/8000-H₂O at 308.2 K. And the region of two-liquids phase increase with the increase of molecular weight of PEG.

Key words: phase equilibria, solubility, thermodynamic properties, polymers, mixed solvents

摘要：

采用等温溶解法和浊点法研究了288.2、298.2、308.2 K下三元体系CsCl-PEG8000-H₂O的相平衡关系，采用经验方程分别对双液线和结线数据进行了拟合，绘制了完整相图。研究发现CsCl-PEG8000-H₂O体系在288.2、298.2、308.2 K下同时存在固液平衡与液液平衡关系，其完整相图均由不饱和液相区（L）、两个一液一固区（L+S）、双液相区（2L）、两液一固区（2L+S）和两固一液区（2S+L）构成；随着温度升高，不饱和液相区（L）、双液相区（2L）、一液一固区（L+S）、两液一固区（2L+S）均增大，两固一液区（2S+L）减小。对比288.2、298.2、308.2 K下三元体系CsCl-PEG1000/4000/6000/8000-H₂O完整相图，结果表明：288.2、298.2 K时，仅CsCl-PEG1000-H₂O体系存在固液平衡关系，CsCl-PEG4000/6000/8000-H₂O体系同时存在固液和液液平衡关系；308.2 K时，CsCl-PEG1000/4000/6000/8000-H₂O体系同时存在固液和液液平衡关系；双液相区（2L）随聚乙二醇分子量增大而增大。

关键词: 相平衡, 溶解性, 热力学性质, 聚合物, 混合溶剂

CLC Number:

O 642.4

LUO Jun, WANG Lin, HUANG Qin, REN Siying, YU Xudong, ZENG Ying. Phase equilibria for ternary system CsCl-PEG8000-H₂O at 288.2, 298.2 and 308.2 K[J]. CIESC Journal, 2021, 72(6): 3140-3148.

罗军, 王林, 黄琴, 任思颖, 于旭东, 曾英. CsCl-PEG8000-H₂O三元体系288.2、298.2、308.2 K相平衡测定[J]. 化工学报, 2021, 72(6): 3140-3148.

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Phase equilibria for ternary system CsCl-PEG8000-H₂O at 288.2, 298.2 and 308.2 K

CsCl-PEG8000-H₂O三元体系288.2、298.2、308.2 K相平衡测定

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