基于3D打印的多孔陶瓷膜研究进展

doi:10.11949/0438-1157.20220994

摘要/Abstract

摘要：

高性能膜材料是膜分离技术的“芯片”，发展新型高效制备方法是膜分离领域的重要研究方向。以数字模型为基础的3D打印技术，在复杂结构器件精密构筑方面展现出了优异的灵活性。近年来，3D打印技术在高性能膜材料开发方面的应用被广泛关注。本文从制备方法、性能强化等方面介绍了3D打印多孔陶瓷膜的研究进展，探讨了多孔陶瓷膜3D打印技术面临的挑战，并对3D打印技术在陶瓷膜领域的潜在发展方向进行了展望。

关键词: 陶瓷膜, 3D打印, 增材制造, 多孔陶瓷

Abstract:

High-performance membranes are the “chip” of membrane separation technology, and the development of new and efficient preparation methods is an important research direction in the field of membrane separation. 3D printing technology based on digital model has shown excellent flexibility in the precise construction of complex structures. In recent years, the application of 3D printing technologies in the development of high-performance membranes has received extensive and continues attention. In this paper, the research progress of 3D printing technology for porous ceramic membranes is reviewed from the aspects of preparation methods and performance enhancement. The challenges of 3D printing technology faced by porous ceramic membranes are discussed, and their potential development directions are also prospected.

Key words: ceramic membrane, 3D printing, additive manufacturing, porous ceramic

中图分类号:

TQ 028.8

陈献富, 王冬雨, 范益群, 邢卫红, 乔旭. 基于3D打印的多孔陶瓷膜研究进展[J]. 化工学报, 2023, 74(1): 105-115.

Xianfu CHEN, Dongyu WANG, Yiqun FAN, Weihong XING, Xu QIAO. Research progress of porous ceramic membranes based on 3D printing technologies[J]. CIESC Journal, 2023, 74(1): 105-115.

图/表 2

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成型方法	支撑体	膜层	孔径/μm	水通量/(m³·m^-2·h^-1·MPa^-1)	文献
3D打印(DLP)	氧化铝	无	0.86	27.0	[50-51] (本课题组工作)
		无	0.47	8.0
		氧化铝	0.11	10.5
3D打印(IJP)	黏土	无	2~8	14.0^②	[43]
3D打印(IJP)	黏土	无	7.8^①	5.0^③	[44]
3D打印(SLA)	氧化铝	无	约0.01	—	[45]
3D打印(DLP)	氧化铝	氧化铝	0.18	1.5	[49]
3D打印(DIW)	—	氧化铝	0.07~0.09	42.0	[60]
间接3D打印(SLA)	碳化硅	无	1.3	—	[59]
挤出	氧化铝	无	1.0	18.0	[55]
挤出	粉煤灰	无	1.25	31.6	[61]
挤出	粉煤灰	无	0.3	4.6	[61]
干压	粉煤灰	无	1.3	21	[62]
冷冻铸造	波特兰水泥	无	2	18	[63]
挤出	氧化铝	氧化铝	0.5	14.7	[64](商品化)
挤出	碳化硅	碳化硅	0.5	49.8	[64](商品化)
挤出	氧化铝	氧化锆	0.5	10.5	[65](商品化)
			0.2	6.3
			0.05	3.6
挤出	氧化铝	氧化铝	0.2	10.2	[57](商品化)

成型方法	支撑体	膜层	孔径/μm	水通量/(m³·m^-2·h^-1·MPa^-1)	文献
3D打印(DLP)	氧化铝	无	0.86	27.0	[50-51] (本课题组工作)
		无	0.47	8.0
		氧化铝	0.11	10.5
3D打印(IJP)	黏土	无	2~8	14.0^②	[43]
3D打印(IJP)	黏土	无	7.8^①	5.0^③	[44]
3D打印(SLA)	氧化铝	无	约0.01	—	[45]
3D打印(DLP)	氧化铝	氧化铝	0.18	1.5	[49]
3D打印(DIW)	—	氧化铝	0.07~0.09	42.0	[60]
间接3D打印(SLA)	碳化硅	无	1.3	—	[59]
挤出	氧化铝	无	1.0	18.0	[55]
挤出	粉煤灰	无	1.25	31.6	[61]
挤出	粉煤灰	无	0.3	4.6	[61]
干压	粉煤灰	无	1.3	21	[62]
冷冻铸造	波特兰水泥	无	2	18	[63]
挤出	氧化铝	氧化铝	0.5	14.7	[64](商品化)
挤出	碳化硅	碳化硅	0.5	49.8	[64](商品化)
挤出	氧化铝	氧化锆	0.5	10.5	[65](商品化)
			0.2	6.3
			0.05	3.6
挤出	氧化铝	氧化铝	0.2	10.2	[57](商品化)

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