化工学报 ›› 2016, Vol. 67 ›› Issue (4): 1079-1089.DOI: 10.11949/j.issn.0438-1157.20151352
吕翠翠1,2, 丁剑1,2, 付国燕1,2, 刘娅1,2, 鲁永刚1, 钱鹏1, 叶树峰1
收稿日期:
2015-08-31
修回日期:
2015-10-05
出版日期:
2016-04-05
发布日期:
2016-04-05
通讯作者:
叶树峰
基金资助:
国家高技术研究发展计划项目(2011AA06A104);十二五国家科技支撑项目(2011BAC06B01,2012BAB08B04)。
LÜ Cuicui1,2, DING Jian1,2, FU Guoyan1,2, LIU Ya1,2, LU Yonggang1, QIAN Peng1, YE Shufeng1
Received:
2015-08-31
Revised:
2015-10-05
Online:
2016-04-05
Published:
2016-04-05
Supported by:
supported by the National High Technology Research and Development Program of China(2011AA06A104), the Projects in the National Science & Technology Pillar Program during the 12th Five-year Plan Period (2011BAC06B01, 2012BAB08B04).
摘要:
氰化尾渣是我国的大宗危险固体废物。这种固体废物含有可回收的有价元素,如铜、铅、锌、金、银、硫、铁等。对氰化尾渣的综合利用既可以回收这些有价元素,实现矿石资源的最大化利用,又可以减少氰化尾渣中残存的药剂对环境的危害。本文从氰化尾渣的性质出发,总结了氰化尾渣的预处理方法,介绍了回收铜铅锌、硫铁、金银的研究现状,并指出现阶段存在的主要问题。针对研究现状和存在的问题,提出新工艺的开发、新药剂的研制、尾矿的再利用等发展方向。氰化尾渣的顺利解决将为社会带来一定经济效益和环境效益。
中图分类号:
吕翠翠, 丁剑, 付国燕, 刘娅, 鲁永刚, 钱鹏, 叶树峰. 氰化尾渣中有价元素回收现状与展望[J]. 化工学报, 2016, 67(4): 1079-1089.
LÜ Cuicui, DING Jian, FU Guoyan, LIU Ya, LU Yonggang, QIAN Peng, YE Shufeng. Present situation and prospect of recovering valuable elements from cyanidation tailing[J]. CIESC Journal, 2016, 67(4): 1079-1089.
[1] | 杨剧文, 王二军. 黄金选冶技术进展[J]. 矿产保护与利用, 2007, (4): 34-38. YANG J W, WANG E J. Progress of mineral processing and metallurgy for gold ores[J] . Conservation and Utilization of Mineral Resources, 2007, (4): 34-38. |
[2] | ADAMS M D. Advances in Gold Ore Processing: Chapter 20[M]. Elsevier Ltd, 2005. |
[3] | HABASHI F. One hundred years of cyanidation[J] . Mining and Metallergical Bulletin, 1987, 80(905): 108-114. |
[4] | 郭振杰. 提金新工艺——氰化法[J]. 内蒙古科技与经济, 2007, (24): 75-77. GUO Z J. New technology for gold extraction-cyanidation[J] . Inner Mongolia Science Technology & Economy, 2007, (24): 75-77. |
[5] | 李婷, 尹艳芬, 方夕辉, 等. 从金氰化尾渣中回收铜、铅、锌、硫的工艺技术现状[J]. 现代矿业, 2011, (4): 28-29. LI T, YIN Y F, FANG X H, et al. Technological status of recovering copper, lead, zinc, sulfur from gold cyaniding tailings[J] . Modern Mining, 2011, (4): 28-29. |
[6] | 张渊, 李俊锋, 索崇慧. 矿山尾矿综合利用及其环境治理的意义[J]. 农业与技术, 2000, 20(4): 56-57. ZHANG Y, LI J F, SUO C H. The comprehensive utilization of mine tailing and its environmental significance[J] . Agriculture & Technology, 2000, 20(4): 56-57. |
[7] | LAITOS J G. Cyanide, mining, and the environment[J] . Pace Environmental Law Review, 2013, 30(3): 869-1278. |
[8] | DONATO D B, NICHOLS O, POSSINGHAM H, et al. A critical review of the effects of gold cyanide-bearing tailings solutions on wildlife[J] . Environment International, 2007, 33(7): 974-984. |
[9] | MUDDER T, BOTZ M. Cyanide and society: a critical review[J] . European Journal of Mineral Processing and Environmental Protection, 2004, 4(1): 62-74. |
[10] | EARLS D, JONES J, JAMES J. The impact of the chemical reactions of cyanide on the quality of water seeping from a gold mine tailings dam in chemistry in tropical and temperate environments[C]//4th Environmental Chemistry Conference. Darwin: Northern Territory, 1995. |
[11] | 王静康, 龚俊波, 鲍颖. 21世纪中国绿色化学与化工发展的思考[J]. 化工学报, 2004, 55(12): 1944-1949. WANG J K, GONG J B, BAO Y. Some thoughts about development of Chinese green chemistry and chemical engineering in China in 21st century[J] . Journal of Chemical Industry and Engineering(China), 2004, 55(12): 1944-1949. |
[12] | LV C C, DING J, QIAN P, et al. Comprehensive recovery of metals from cyanidation tailing[J] . Minerals Engineering, 2015, 70: 141-147. |
[13] | MUDDER T I, BOTZ M M, SMITH A. Chemistry and Treatment of Cyanidation Wastes[M]. London: Mining Journal Books Ltd., 2001: 332. |
[14] | 冯肇伍. 金精矿氰化尾渣回收铜的研究与实践[J]. 有色金属(选矿部分), 2002, (1): 17-19. FENG Z W. Research and practice of recovering copper from cyanide tailing of gold concentrate[J] . Nonferrous Metals (Mineral Processing Section), 2002, (1): 17-19. |
[15] | 牛桂强, 邱立明, 綦开祥. 焦家金矿尾矿资源综合利用与生产实践[J]. 金属矿山, 2008, (11): 159-160. NIU G Q, QIU L M, QI K X. The comprehensive utilization and practice of Jiao Jia gold tailing[J] . Metal Mine, 2008, (11): 159-160. |
[16] | 吴向阳. 氰化尾渣浮选铅锌预处理工艺的优化[J]. 金属矿山, 2010, (11): 187-189. WU X Y. Optimization of pretreatment technology in the flotation of lead and zinc from cyanidation tailing[J] . Metal Mine, 2010, (11): 187-189. |
[17] | 路明福, 温建波. 氰化尾渣综合回收工艺及实践[J]. 黄金, 2010, 31(10):52-54. LU M F, WEN J B. Comprehensive recovery and production practice of cyanidation tailings[J] . Gold, 2010, 31(10): 52-54. |
[18] | 李学强, 庄宇凯, 冯金敏, 等. 氰化尾渣综合回收试验研究[J]. 黄金, 2010, 31(9): 43-45. LI X Q, ZHUANG Y K, FENG J M, et al. Experimental study on integrative recovery technique of cyanidation tailings[J] . Gold, 2010, 31(9): 43-45. |
[19] | KITIS M, AKCIL A, KARAYA E. Destruction of cyanide by hydrogen peroxide in tailings slurries from low bearing sulphidic gold ores[J] . Minerals Engineering, 2005, 18(3): 353-362. |
[20] | 孙淑慧, 付国燕, 钱鹏, 等. 氰化尾渣高效脱氰富集硫铁的试验研究[J]. 计算机与应用化学, 2013, 30(3): 229-235. SUN S H, FU G Y, QIAN P, et al. The research on the efficient destruction of cyanide and recovery of pyrite from the residue of cyanide[J] . Computers and Applied Chemistry, 2013, 30(3): 229-235. |
[21] | LIU B L, ZHANG Z H, LI L B, et al. Recovery of gold and iron from the cyanide tailings by magnetic roasting[J] . Rare Metal Materials and Engineering, 2013, 42(9): 1805-1809. |
[22] | 李仕雄, 李学强, 张学政. 从氰化尾渣高效回收铜、铅、锌、硫的新工艺研究[J]. 湖南有色金属, 2009, 25(1): 13-16. LI S X, LI X Q, ZHANG X Z. Study on new techniques for effective recovery of Cu, Pb, Zn and S from cyanide residue[J] . Hunan Nonferrous Metals, 2009, 25(1): 13-16. |
[23] | 徐承焱, 孙春宝, 莫晓兰, 等. 某黄金冶炼厂氰化尾渣综合利用研究[J]. 金属矿山, 2008, (12): 148-151. XU C Y, SUN C B, MO X L, et al. Research on the comprehensive utilization of cyanidation slags of a gold smelter[J] . Metal Mine, 2008, (12): 148-151. |
[24] | 张耀军, 崔中云, 崔学奇. 混合浮选法回收氰渣中铅锌银的生产实践[J]. 矿业研究与开发, 2009, 29(1): 22-24. ZHANG Y J, CUI Z Y, CUI X Q. Production practice of recovering lead, zinc and silver from cyanidation residue by bulk flotation process[J] . Mining Research & Development, 2009, 29(1): 22-24. |
[25] | 郭宏, 张景和. 天水金精矿氰化尾渣综合回收铜铅的试验研究[J]. 黄金, 1999, 20(11): 35-38. GUO H, ZHANG J H. Experimental study of synthetic recovery of copper and lead from cyanide tailings of Tianshui gold concentrate[J] . Gold, 1999, 20(11): 35-38. |
[26] | 崔学奇, 吕宪俊, 胡术刚, 等. 某氰化尾矿综合回收铜铅的试验研究[J]. 矿产综合利用, 2006, (4): 38-40. CUI X Q, LÜ X J, HU S G, et al. Experimental research on comprehensive recovery of copper and lead from tailings of a gold cyanide leaching plant[J] . Multipurpose Utilization of Mineral Resource, 2006, (4): 38-40. |
[27] | 李正要, 汪莉, 于艳红, 等. 金精矿氰化尾渣铅和铜的回收[J]. 北京科技大学学报, 2009, 31(10): 1231-1234. LI Z Y, WANG L, YU H Y, et al. Recovery of lead and copper from cyanide tailings[J] . Journal of University of Science and Technology Beijing, 2009, 31(10): 1231-1234. |
[28] | 代淑娟, 孟宇群, 胡志刚, 等. 某银精矿氰化尾渣中铅和锌的浮选回收试验[J]. 金属矿山, 2009, (10): 176-179. DAI S J, MENG Y Q, HU Z G, et al. Study on flotation experiment of lead and zinc from cyanide gangue residues in a silver concentrate[J] . Metal Mine, 2009, (10): 176-179. |
[29] | 杨玮, 覃文庆, 刘瑞强, 等. 氰化尾渣中铅锌分离试验研究[J]. 矿冶工程, 2010, 30(6): 30-33. YANG W, QIN W Q, LIU R Q, et al. Study on the separation of lead and zinc in cyaniding tailings[J] . Mining and Metallurgical Engineering, 2010, 30(6): 30-33. |
[30] | 王宏军. 超细粒氰化尾渣多金属浮选试验研究与实践[J]. 金属矿山, 2003, (7): 50-52. WANG H J. Research and practice of multiple-metal flotation from superfine cyanidation residue[J] . Metal Mine, 2003, (7): 50-52. |
[31] | 于振福, 郝建贞. 从氰化尾矿中浮选回收铅、锌的生产实践[J]. 黄金, 2002, 23(7): 28-30. YU Z F, HAO J Z. The operation of separating lead, zinc from cyanide tail[J] . Gold, 2002, 23(7): 28-30. |
[32] | 贺政. 氰化尾渣铅锌浮选试验研究[J]. 有色金属(选矿部分), 2002, (6): 9-12. HE Z. The experimental research of floating lead and zinc from cyanide tailing[J] . Nonferrous Metals(Mineral Processing Section), 2002, (6): 9-12. |
[33] | 林俊领, 李增华, 卢冀伟, 等. 新疆某金矿氰化尾渣回收铜的试验研究[J]. 矿产综合利用, 2013, (2): 28-32. LIN J L, LI Z H, LU Y W, et al. Research on recoverying copper from cyanide tailing of a gold ore in Xinjiang[J] . Multipurpose Utilization of Mineral Resources, 2013, (2): 28-32. |
[34] | 梁冠杰. 河南某氰化尾渣中有价金属的综合回收[J]. 矿产综合利用, 2001, (3): 35-37. LIANG G J. Comprehensive recovery of valuable metals from cyanide leach residue[J] . Multipurpose Utilization of Mineral Resources, 2001, (3): 35-37. |
[35] | 许阳芳, 曲保忠. 新疆某氰化提金厂尾矿综合回收试验研究[J]. 新疆有色金属, 2002, (4): 15-l7. XU Y F, QU B Z. Comprehensive recovery research of cyanide tailing in Xinjiang[J] . Xinjiang Nonferrous Metal, 2002, (4): 15-l7. |
[36] | 毕凤琳, 冯玉华, 冯金敏, 等. 氰化尾渣铜锌混合精矿分离浮选试验研究[J]. 黄金, 2009, 30(12): 40-44. BI F L, FENG Y H, FENG J M, et al. Experimental tests on separation floatation for copper zinc mixed floatation concentrate of a certain cyanidation tailings[J] . Gold, 2009, 30(12): 40-44. |
[37] | 罗仙平, 程吉林, 葛清海, 等. 黄狮涝金矿尾矿整体资源化回收与利用研究[J]. 中国矿业, 2006, 15(1): 30-34. LUO X P, CHENG J L, GE Q H, et al. An experimental study of reclaim and reutilization from tailings of huangshilao gold mine[J] . China Mining Magazine, 2006, 15(1): 30-34. |
[38] | 肖坤明, 谢文清, 郑新烟, 等. 福建某氰化尾渣综合利用试验研究[J]. 矿产综合利用, 2013, (5): 72-75. XIAO K M, XIE W Q, ZHENG X Y, et al. Study on comprehensive utilization of cyanidation tailing in Fujian[J] . Multipurpose Utilization of Mineral Resources, 2013, (5): 72-75. |
[39] | 袁艳霞, 曲贤绪. 从直接氰化尾渣中回收有价元素的生产实践[J]. 科技传播, 2014, 18: 108. YUAN Y X, QU X X. The practice of recovering valuable elements from cyanide tailing[J] . Science and Technology Communication, 2014, 18: 108. |
[40] | 何廷树, 张丰, 谢建宏. 从氰渣中回收金的浮选试验研究[J]. 黄金, 2010, 31(7): 39-42. HE T S, ZHANG F, XIE J H. Floatation experiments on recovering gold from cyanide residue[J] . Gold, 2010, 31(7): 39-42. |
[41] | 周东琴. 某氰化尾渣中金的浮选回收试验研究[J]. 有色矿冶, 2009, (1): 15-17. ZHOU D Q. The experiment study on recovering gold by flotation from a cyanide tailing[J] . Non-Ferrous Mining and Metallurgy, 2009, (1): 15-17. |
[42] | 罗传胜. 从某氰化浸金尾渣中浮选回收金的研究[J]. 材料研究与应用, 2012, 6(3): 181-184. LUO C S. Test study of recovery gold from cyaniding slag by flotation[J] . Materials Research and Application, 2012, 6(3): 181-184. |
[43] | 薛光, 于永江. 加压氧化—氰化浸出法从氰化尾渣中回收金[J]. 矿产综合利用, 2004, 12(6): 47-49. XUE G, YU Y J. Using pressurized oxidation-cyanidation to recover gold from cyanidation tailing[J] . Multipurpose Utilization of Mineral Resources, 2004, 12(6): 47-49. |
[44] | 张福元, 张玉华, 俎小凤. 从氰渣中浸取金、银试验研究[J]. 黄金, 2007, 28(9): 37-39. ZHANG F Y, ZHANG Y H, ZU X F. Experimental research on extracting gold and silver from cyanide residue[J] . Gold, 2007, 28(9): 37-39. |
[45] | 于先进, 李怀梅, 张亚莉. 氰化尾渣硫脲浸金试验[J]. 有色金属(冶炼部分), 2012, (5): 30-32. YU X J, LI H M, ZHANG Y L. Experimental study on gold-leaching from cyaniding tailing with thiourea[J] . Nonferrous Metals (Extractive Metallurgy), 2012, (5): 30-32. |
[46] | 史娟华, 于先进, 张亚莉. 氯化钠—次氯酸钠法从氰化渣中回收金[J]. 有色金属(冶炼部分), 2013, (3): 35-37. SHI J H, YU X J, ZHANG Y L. Sodium chloride-sodium hypochlorite method for gold recovery from cyanide residue[J] . Nonferrous Metals(Extractive Metallurgy), 2013, (3): 35-37. |
[47] | 中南矿冶学院冶金研究室. 氯化冶金[M]. 北京: 冶金工业出版社, 1978: 67-70. Institute of Mining and Metallurgy Laboratory of Central South University. Chloridizing Metallurgy[M]. Beijing: Metallurgical Industry Press, 1978: 67-70. |
[48] | LANDSBERG A, HOATSON C L. The kinetics and equilibria of the gold-chlorine system[J] . Journal of the Less Common Metals, 1970, 22(3): 327-339. |
[49] | 黄海辉, 王云, 袁朝新, 等. 从提金渣中回收金银[J]. 有色金属(冶炼部分), 2011, (10): 37-39. HUANG H H, WANG Y, YUAN C X, et al. Extraction of gold and silver from gold-extraction residue[J] . Nonferrous Metals(Extractive Metallurgy), 2011, (10): 37-39. |
[50] | 高远, 王继民, 吴昊, 等. 氰化尾渣综合利用研究[J]. 材料研究与应用, 2010, 4(2): 156-160. GAO Y, WANG J M, WU H, et al. Study on comprehensive utilization of cyanidation slags[J] . Materials Research and Application, 2010, 4(2): 156-160. |
[51] | 马红周, 兰新哲, 王耀宁, 等. 焙烧氰化尾渣的利用研究[J]. 稀有金属, 2010, 34(2): 281-284. MA H Z, LAN X Z, WANG Y N, et al. Utilization of tailings of roasting-cyaniding process[J] . Chinese Journal of Rare Metals, 2010, 34(2): 281-284. |
[52] | 丁剑, 叶树峰. 焙烧氰化渣氯化挥发提金的研究[J]. 黄金科学技术, 2014, 22(4): 114-117. DING J, YE S F. Research on gold recovery from residue of roasting-cyaniding process by chloridizing roast[J] . Gold Science and Technology, 2014, 22(4): 114-117. |
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