化工学报 ›› 2017, Vol. 68 ›› Issue (11): 4383-4389.DOI: 10.11949/j.issn.0438-1157.20170304

• 材料化学工程与纳米技术 • 上一篇    下一篇

基于醇胺固定-释放二氧化碳原理的聚氨酯泡沫绿色制备

陈旭亮1, 任强1, 宋艳2, 吴盾2, 李坚2   

  1. 1 江苏省环境友好高分子材料重点实验室, 江苏 常州 213164;
    2 常州大学材料科学与工程学院, 江苏 常州 213164
  • 收稿日期:2017-03-27 修回日期:2017-05-25 出版日期:2017-11-05 发布日期:2017-11-05
  • 通讯作者: 任强
  • 基金资助:

    国家自然科学基金项目(51203014)。

Ammonium carbamate from diethanolamine for green foaming of polyurethanes with carbon dioxide

CHEN Xuliang1, REN Qiang1, SONG Yan2, WU Dun2, LI Jian2   

  1. 1 Jiangsu Key Laboratory of Environment-friendly Polymer Materials, Changzhou 213164, Jiangsu, China;
    2 School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
  • Received:2017-03-27 Revised:2017-05-25 Online:2017-11-05 Published:2017-11-05
  • Supported by:

    supported by the National Natural Science Foundation of China (51203014).

摘要:

通过二乙醇胺(DEA)和二氧化碳反应制得一种氨基甲酸铵化合物(DEAC)。DEAC初始分解温度约为54℃,二氧化碳含量14.6%。将不同份数的DEAC作为反应型发泡剂添加到硬质聚氨酯发泡体系中制备泡沫材料,得到密度为90~150 kg·m-3,压缩强度为0.02~1.65 MPa性能良好的泡沫材料。DEA在火力发电厂作为二氧化碳吸收剂以减少二氧化碳排放。因此,DEAC可以来源于火力发电厂的副产物,成本低廉。本研究为硬质聚氨酯泡沫的制备提供了一种新型的绿色、环保、经济的方法。

关键词: 聚氨酯, 泡沫, 二氧化碳, 二乙醇胺, 氨基甲酸铵

Abstract:

Diethanol ammonium carbamate (DEAC) was prepared by reaction of diethanolamine (DEA) with carbon dioxide. DEAC has onset decomposition temperature round 54℃. Addition of DEAC as reactive blowing agent into common rigid polyurethane foaming formulation gave foams with densities in the range of 90 to 150 kg·m-3 and compressive strengths in the range of 0.02 to 1.65 MPa. DEA can be used as CO2 absorbents in coal-burn power generation plant to reduce greenhouse gas emission. DEAC can be obtained as byproduct from coal-burn power station with low cost. This novel approach is environmentally friendly, cost effective and promising to open up a new platform for green foaming of polyurethanes.

Key words: polyurethane, foam, carbon dioxide, diethanolamine, ammonium carbamate

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