ZnO修饰的不锈钢网支撑体上ZIF-8膜的制备

doi:10.11949/j.issn.0438-1157.20180194

化工学报 ›› 2018, Vol. 69 ›› Issue (8): 3724-3731.DOI: 10.11949/j.issn.0438-1157.20180194

• 材料化学工程与纳米技术 • 上一篇下一篇

ZnO修饰的不锈钢网支撑体上ZIF-8膜的制备

李甲, 谷景华, 殷文杰, 李泽耀

北京航空航天大学材料科学与工程学院, 北京 100191

收稿日期:2018-02-11 修回日期:2018-04-03 出版日期:2018-08-05 发布日期:2018-08-05
通讯作者: 谷景华
基金资助:
国家自然科学基金项目（51178017）。

Preparation of ZIF-8 membranes on ZnO modified stainless steel nets

LI Jia, GU Jinghua, YIN Wenjie, LI Zeyao

School of Materials Science and Engineering, Beihang University, Beijing 100191, China

Received:2018-02-11 Revised:2018-04-03 Online:2018-08-05 Published:2018-08-05
Supported by:
supported by the National Natural Science Foundation of China(51178017).

摘要/Abstract

摘要：

ZIF-8因具有0.34 nm的孔道直径而被认为是最具应用前景的气体分离膜材料之一。不锈钢网（SSN）作为分离膜的支撑体具有价格低廉、易于裁剪、厚度薄等优点。采用水热法在SSN表面生长ZnO缓冲层，以ZnO修饰的SSN（ZnO/SSN）为支撑体制备ZIF-8膜。采用X射线衍射（XRD）和扫描电子显微镜（SEM）对合成的ZIF-8膜进行表征，并进行了气体渗透性能测试，结果表明，在ZnO颗粒修饰后的SSN支撑体上无需活化可制备出单一物相、无缺陷的ZIF-8膜；在室温（298 K）下，ZIF-8膜的H₂/CO₂、H₂/N₂、H₂/CH₄的理想分离系数分别为7.3、9.2、12.4；在150℃，ZIF-8膜的渗透性能稳定。

关键词: ZIF-8膜, 不锈钢网支撑体, ZnO缓冲层, 气体分离, 氢渗透选择性

Abstract:

ZIF-8 is one of the most perspective membrane materials for gas separation due to its regular pore size of 0.34 nm. Stainless steel nets (SSN) have the advantages of low price, easy cutting, and thin thickness as membrane substrates. In this work, ZnO buffering layer was synthesized on SSN substrate by hydrothermal method. ZIF-8 membranes were prepared on the ZnO modified SSN (ZnO/SSN) supports. ZnO/SSN supported ZIF-8 membranes were characterized by X ray diffraction (XRD) and scanning electron microscopy (SEM). The gas separation property of prepared ZIF-8 membranes was carried out. It is indicated that phase-pure and defect-free ZIF-8 membrane can be obtained on the ZnO/SSN substrate without additional activation step of ZnO layer. The ideal separation factors of H₂/CO₂, H₂/N₂ and H₂/CH₄ were 7.3, 9.2 and 12.4 at room temperature. The membrane demonstrates a good stability of permeability at 150℃.

Key words: ZIF-8 membrane, stainless steel net substrate, ZnO buffering layer, gas separation, hydrogen permselectivity

中图分类号:

O614

李甲, 谷景华, 殷文杰, 李泽耀. ZnO修饰的不锈钢网支撑体上ZIF-8膜的制备[J]. 化工学报, 2018, 69(8): 3724-3731.

LI Jia, GU Jinghua, YIN Wenjie, LI Zeyao. Preparation of ZIF-8 membranes on ZnO modified stainless steel nets[J]. CIESC Journal, 2018, 69(8): 3724-3731.

参考文献 30

[1]	LI H, EDDAOUDI M, O'KEEFFE M, et al. Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J]. Nature, 1999, 402(6759):276-279.
[2]	SEO J S, WHANG D, LEE H, et al. A homochiral metal-organic porous material for enantioselective separation and catalysis[J]. Nature, 2000, 404(6781):982-986.
[3]	MURRAY L J, DINCA M, LONG J R. Hydrogen storage in metal-organic frameworks[J]. Chemical Society Reviews, 2009, 38(5):1294-1314.
[4]	YAGHI O M, O'KEEFFE M, OCKWIG N W, et al. Reticular synthesis and the design of new materials[J]. Nature, 2003, 423(6941):705-714.
[5]	LI J R, KUPPLER R J, ZHOU H C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chemical Society Reviews, 2009, 38(5):1477-1504.
[6]	PARK K S, NI Z, COTE A P, et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J]. Proceedings of the National Academy of Sciences, 2006, 103(27):10186-10191.
[7]	PHAN A, DOONAN C J, URIBE-ROMO F J, et al. Synthesis, structure, and carbon dioxide capture properties of zeolitic imidazolate frameworks[J]. Acc. Chem. Res., 2010, 43(1):58-67.
[8]	YAO J, WANG H. Zeolitic imidazolate framework composite membranes and thin films:synthesis and applications[J]. Chemical Society Reviews, 2014, 43(13):4470-4493.
[9]	HARA N, YOSHIMUNE M, NEGISHI H, et al. Diffusive separation of propylene/propane with ZIF-8 membranes[J]. Journal of Membrane Science, 2014, 450(15):215-223.
[10]	HUANG K, DONG Z, LI Q, et al. Growth of a ZIF-8 membrane on the inner-surface of a ceramic hollow fiber via cycling precursors[J]. Chemical Communications, 2013, 49(87):10326-10328.
[11]	KWON H T, JEONG H K. Improving propylene/propane separation performance of zeolitic-imidazolate framework ZIF-8 Membranes[J]. Chemical Engineering Science, 2015, 124(3):20-26.
[12]	KWON H T, JEONG H K. Highly propylene-selective supported zeolite-imidazolate framework (ZIF-8) membranes synthesized by rapid microwave-assisted seeding and secondary growth[J]. Chemical Communications, 2013, 49(37):3854-3856.
[13]	KWON H T, JEONG H K. In situ synthesis of thin zeolitic-imidazolate framework ZIF-8 membranes exhibiting exceptionally high propylene/propane separation[J]. Journal of the American Chemical Society, 2013, 135(29):10763-10768.
[14]	LI L, YAO J, CHEN R, et al. Infiltration of precursors into a porous alumina support for ZIF-8 membrane synthesis[J]. Microporous and Mesoporous Materials, 2013, 168(1):15-18.
[15]	PAN Y, LAI Z. Sharp separation of C2/C3 hydrocarbon mixtures by zeolitic imidazolate framework-8(ZIF-8) membranes synthesized in aqueous solutions[J]. Chemical Communications, 2011, 47(37):10275-10277.
[16]	PAN Y, LI T, LESTARI G, et al. Effective separation of propylene/propane binary mixtures by ZIF-8 membranes[J]. Journal of membrane science, 2012, 390(15):93-98.
[17]	XU G, YAO J, WANG K, et al. Preparation of ZIF-8 membranes supported on ceramic hollow fibers from a concentrated synthesis gel[J]. Journal of Membrane Science, 2011, 385(1):187-193.
[18]	ZHU Y, LIU Q, CARO J, et al. Highly hydrogen-permselective zeolitic imidazolate framework ZIF-8 membranes prepared on coarse and macroporous tubes through repeated synthesis[J]. Separation and Purification Technology, 2015, 146(26):68-74.
[19]	VENNA S R, CARREON M A. Highly permeable zeolite imidazolate framework-8 membranes for CO2/CH4 separation[J]. Journal of the American Chemical Society, 2009, 132(1):76-78.
[20]	JANG E, KIM E, KIM H, et al. Formation of ZIF-8 membranes inside porous supports for improving both their H2/CO2 separation performance and thermal/mechanical stability[J]. Journal of Membrane Science, 2017, 540(15):430-439.
[21]	ZHANG H, JAMES J, ZHAO M, et al. Improving hydrostability of ZIF-8 membranes via surface ligand exchange[J]. Journal of Membrane Science, 2017, 532(15):1-8.
[22]	KONG L, ZHANG X, LIU H, et al. Synthesis of a highly stable ZIF-8 membrane on a macroporous ceramic tube by manual-rubbing ZnO deposition as a multifunctional layer[J]. Journal of Membrane Science, 2015, 490(15):354-363.
[23]	ZHANG X, LIU Y, LI S, et al. New membrane architecture with high performance:ZIF-8 membrane supported on vertically aligned ZnO nanorods for gas permeation and separation[J]. Chemistry of Materials, 2014, 26(5):1975-1981.
[24]	HUANG A, LIU Q, WANG N, et al. Highly hydrogen permselective ZIF-8 membranes supported on polydopamine functionalized macroporous stainless-steel-nets[J]. Journal of Materials Chemistry A, 2014, 2(22):8246-8251.
[25]	RUAN X, ZHANG X, LIAO X, et al. Enhancing mechanical stability and uniformity of 2-D continuous ZIF-8 membranes by Zn (Ⅱ)-doped polydopamine modification[J]. Journal of Membrane Science, 2017, 541(1):101-107.
[26]	LI W, MENG Q, LI X, et al. Non-activation ZnO array as a buffering layer to fabricate strongly adhesive metal-organic framework/PVDF hollow fiber membranes[J]. Chemical Communications, 2014, 50(68):9711-9713.
[27]	LIU Q, WANG N, CARO J, et al. Bio-inspired polydopamine:a versatile and powerful platform for covalent synthesis of molecular sieve membranes[J]. Journal of the American Chemical Society, 2013, 135(47):17679-17682.
[28]	ZHANG X, LIU Y, KONG L, et al. A simple and scalable method for preparing low-defect ZIF-8 tubular membranes[J]. Journal of Materials Chemistry A, 2013, 1(36):10635-10638.
[29]	ZHAN W, KUANG Q, ZHOU J, et al. Semiconductor@metal-organic framework core-shell heterostructures:a case of ZnO@ZIF-8 nanorods with selective photoelectrochemical response[J]. Journal of the American Chemical Society, 2013, 135(5):1926-1933.
[30]	FAIREN-JIMENEZ D, MOGGACH S A, WHARMBY M T, et al. Opening the gate:framework flexibility in ZIF-8 explored by experiments and simulations[J]. Journal of the American Chemical Society, 2011, 133(23):8900-8902.

ZnO修饰的不锈钢网支撑体上ZIF-8膜的制备

Preparation of ZIF-8 membranes on ZnO modified stainless steel nets

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献 30

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张瑞航, 曹潘, 杨锋, 李昆, 肖朋, 邓春, 刘蓓, 孙长宇, 陈光进. ZIF-8纳米流体天然气乙烷回收工艺的产品纯度关键影响因素分析[J]. 化工学报, 2023, 74(8): 3386-3393.
[2]	王绍宇, 马翰泽, 吴洪, 梁旭, 王洪建, 朱姿亭, 姜忠义. 有机框架膜在气体分离中的研究进展[J]. 化工学报, 2021, 72(7): 3488-3510.
[3]	张娅, 王锐, 文思斯, 周燚洒, 薛健, 王海辉. 石墨相氮化碳纳米片膜研究进展[J]. 化工学报, 2021, 72(12): 6188-6202.
[4]	王琛璐, 王艳磊, 赵秋, 吕玉苗, 霍锋, 何宏艳. 低维纳米受限离子液体的研究进展[J]. 化工学报, 2021, 72(1): 366-383.
[5]	张生义, 李琳, 王春雷, 郑天赋, 孙亚明, 王同华. 自支撑石墨烯炭膜的制备及气体分离性能[J]. 化工学报, 2016, 67(10): 4225-4230.
[6]	白璐, 张香平, 邓靓, 李梦蝶. 离子液体膜材料分离二氧化碳的研究进展[J]. 化工学报, 2016, 67(1): 248-257.
[7]	曹领帝, 曾少娟, 张香平, 张锁江. 离子液体吸收分离硫化氢进展[J]. 化工学报, 2015, 66(S1): 1-9.
[8]	聂飞, 贺高红, 赵薇, 鞠佳, 李皓. 疏水SiO₂/PTFPMS杂化复合膜的制备及其气体分离性能[J]. 化工学报, 2014, 65(8): 3019-3025.
[9]	赵祯霞, 许锋, 李忠. 二次生长法制备ZIF-8膜及其对CO₂/N₂的分离性能[J]. 化工学报, 2014, 65(5): 1673-1679.
[10]	张春芳，赖傲楠，白云翔，顾瑾，孙余凭. EVA38/Tween20凝胶气体分离膜的制备及其性能[J]. 化工进展, 2013, 32(05): 996-1000.
[11]	青格乐图，刘平，郭伟男，王保国. 离子液体在膜分离过程中的应用研究进展 [J]. CIESC Journal, 2010, 29(11): 2019-.
[12]	赵选英, 王同华, 李琳, 刘颖, 曹义鸣. Fe/C杂化炭膜的制备及其气体分离性能 [J]. 化工学报, 2009, 60(9): 2232-2236.
[13]	姚伟静，辜敏，鲜学福，林文胜. 变压吸附气体分离用煤基炭分子筛的制备研究进展 [J]. CIESC Journal, 2009, 28(4): 549-.
[14]	顾飞龙，张力钧，陈栋. 变压吸附制氮技术及其应用 [J]. CIESC Journal, 2007, 26(9): 1356-.
[15]	滕一万，武法文，王辉，李磊，张志炳. CO₂/CH₄高分子气体分离膜材料研究进展 [J]. CIESC Journal, 2007, 26(8): 1075-.