基于超亲水超疏油原理的网膜及其在油水分离中的应用

doi:10.3969/j.issn.0438-1157.2014.06.001

化工学报 ›› 2014, Vol. 65 ›› Issue (6): 1943-1951.DOI: 10.3969/j.issn.0438-1157.2014.06.001

基于超亲水超疏油原理的网膜及其在油水分离中的应用

袁腾¹, 陈卓², 周显宏³, 涂伟萍¹, 胡剑青¹, 王锋¹

1. 华南理工大学化学与化工学院, 广东省绿色化学产品技术重点实验室, 广东广州 510640;
2. 华南理工大学轻工与食品学院, 广东广州 510640;
3. 东莞理工学院化学与环境工程学院, 广东东莞 523808

收稿日期:2014-01-06 修回日期:2014-03-04 出版日期:2014-06-05 发布日期:2014-06-05
通讯作者: 王锋
作者简介:袁腾（1987- ），男，博士研究生。
基金资助:
国家自然科学基金项目（50903031）；中央高校基本科研业务费专项资金（2013ZM0072）；广东省重大科技专项计划项目（2010A080406002）；广东省省部产学研项目（2010A080405006，2010A080404008）；广州市国际科技交流与合作专项（2012J5100043）；广东省绿色化学产品技术重点实验室开放基金（GC201201）；深圳市新型锂离子电池与介孔正极材料重点实验室开放课题（20120213）；广东高校轻化工清洁生产工程技术研究中心开放课题。

Coated mesh film based on superhydrophilic and superoleophobic principle and its application in oil-water separation

YUAN Teng¹, CHEN Zhuo², ZHOU Xianhong³, TU Weiping¹, HU Jianqing¹, WANG Feng¹

1. Guangdong Provincial Key Laboratory for Green Chemical Product Technology, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China;
2. School of Light Industry and Food Sciences, South China University of Technology, Guangzhou 510640, Guangdong, China;
3. College of Chemistry and Environmental Engineering, Dongguan University of Technology, Dongguan 523808, Guangdong, China

Received:2014-01-06 Revised:2014-03-04 Online:2014-06-05 Published:2014-06-05
Supported by:
supported by the National Natural Science Foundation of China (50903031), the Fundamental Research Funds for the Central Universities (2013ZM0072), the Key Scientific and Technological Special Research Fund of Guangdong Province (2010A080406002)，the Project Funds of Combination Research of the Guangdong Province and Ministry of Education (2010A080405006, 2010A080404008) and the Research Fund of the Guangdong Provincial Laboratory of Green Chemical Product Technology (GC201201).

摘要/Abstract

摘要： 综述了基于超亲水超疏油原理的网膜的研究进展及其在油水分离中的应用。首先介绍了研究的理论基础，包括构筑超亲水超疏油网膜的理论基础及膜分离原理，膜的基本性能及影响因素，液桥原理在超亲水超疏油膜中的应用以及该类膜的结构、制备的原材料和制备的基本方法。然后全面综述了刺激响应超亲水超疏油膜，超亲水及水下超疏油膜，无机结晶纳米线超亲水超疏油膜，分子刷结构超亲水超疏油膜及可用于含油乳液分离的网膜等的研究进展。最后指出了目前在该领域的研究中存在的一些问题，主要包括膜分离的基本理论，制备膜的原材料、膜通量、膜寿命及应用范围等，并对未来的发展进行了展望。

关键词: 特殊润湿性, 微纳二元粗糙结构, 刺激响应, 重组装, 薄膜, 油水分离

Abstract: This paper reviews the research progress of membranes based on the principle of superhydrophilicity and superoleophobicity and its application in the oil-water separation. First, the fundamentals of the research are introduced, including those for preparing superhydrophilic and superoleophobic membranes and separation process, basic properties of membranes and influencing factors. The applications of liquid bridge principle in the superhydrophilic and superoleophobic membranes, membranes structures, general raw materials and prepared methods are also introduced. Then a comprehensive overview is given on the research progress of current common types of membranes, mainly including the stimuli-responsive superhydrophilic and superoleophobic membranes, superhydrophilic and underwater superoleophobic membranes, inorganic crystalline nanowires superhydrophilic and superoleophobic membranes, molecular brush structure superhydrophilic and superoleophobic membranes, and membranes for effective separation of oil-in-water emulsions. Finally, some problems in the current research area are advanced, including the basic theory of membrane separation, raw materials of membrane, membrane flux, membrane life, range of application, etc., and the development trends are prospected.

Key words: special wettability, micro-nanoscale binary rough structure, stimuli-responsive, reconfiguration, membranes, oil-water separation

中图分类号:

袁腾, 陈卓, 周显宏, 涂伟萍, 胡剑青, 王锋. 基于超亲水超疏油原理的网膜及其在油水分离中的应用[J]. 化工学报, 2014, 65(6): 1943-1951.

YUAN Teng, CHEN Zhuo, ZHOU Xianhong, TU Weiping, HU Jianqing, WANG Feng. Coated mesh film based on superhydrophilic and superoleophobic principle and its application in oil-water separation[J]. CIESC Journal, 2014, 65(6): 1943-1951.

参考文献 34

[1]	Ma Zijun (马自俊). Emulsions and Oily Wastewater Treatment Technology (乳状液与含油废水处理技术) [M]. Beijing: China Petrochemical Press, 2006: 176-186
[2]	Feng Lin, Zhang Zhongyi, Mai Zhenhong, et al. A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water [J]. Angewandte Chemie-International Edition, 2004, 43: 2012-2014
[3]	Jiang Lei (江雷), Feng Lin (冯琳). Bionic Intelligent Nano Interface Material (仿生智能纳米界面材料) [M]. Beijing: Chemical Industry Press, 2007: 100-180
[4]	Adam Steele, Ilker Bayer, Eric Loth. Inherently superoleophobic nanocomposite coatings by spray atomization [J]. Nano Letters, 2009, 9 (1): 501-505
[5]	Arun K Kota, Li Yongxin, Joseph M Mabry, et al. Hierarchically structured superoleophobic surfaces with ultralow contact angle hysteresis [J]. Advanced Material, 2012, 24: 5838-5843
[6]	Xue Zhongxin (薛众鑫), Jiang Lei (江雷). Bioinspired underwater superoleophobic surfaces [J]. Acta Polymerica Sinica (高分子学报), 2012, 10: 1091-1101
[7]	Xue Zhongxin, Liu Mingjie, Jiang Lei. Recent developments in polymeric superoleophobic surfaces [J]. Journal of Polymer Science, 2012, 50: 1209-1224
[8]	Wenzel R N. Resistance of solid surfaces to wetting by water [J]. Industrial and Engineering Chemistry, 1936, 28: 988-994
[9]	Cassie A B D, Baxter S. Wettability of porous surfaces [J]. Transactions of the Faraday Society, 1944, 40: 546-551
[10]	Jin Meihua, Li Shasha, Wang Jing, et al. Underwater superoleophilicity to superoleophobicity: role of trapped air [J]. Chemical Communications, 2012, 48: 11745-11747
[11]	Kwon Gibum, Arun K Kota, Li Yongxin, et al. On-demand separation of oil-water mixtures [J]. Advanced Materials, 2012, 24: 3666-3671
[12]	Meng Haifeng, Wang Shutao, Xi Jinming, et al. Facile means of preparing superamphiphobic surfaces on common engineering metals [J]. The Journal of Physical Chemistry C, 2008, 112: 11454-11458
[13]	Marc H. Break-up of oil-in-water emulsions induced by permeation through a microfiltration membrane [J]. Journal of Membrane Science, 1995, 102: 1-7
[14]	Kota Arun K, Tuteja Anish, Choi Wonjae, et al. Hygro-responsive membranes for effective oil-water separation [J]. Nature Communications, 2012, DOI:10.1038/ncomms2027
[15]	Yang Jin, Zhang Zhaozhu, Xu Xianghui, et al. Superhydrophilic-superoleophobic coatings [J]. Journal of Materials Chemistry, 2012, 22: 2834-2837
[16]	Kobayashi Motoyasu, Terayama Yuki, Yamaguchi Hiroki, et al. Wettability and antifouling behavior on the surfaces of superhydrophilic polymer brushes [J]. Langmuir, 2012, 28: 7212-7222
[17]	Gao Shiqiao (高世桥), Liu Haipeng (刘海鹏). Capillary Mechanics (毛细力学) [M]. Beijing: Science Press, 2010: 128-140
[18]	Tu Weiping (涂伟萍), Yuan Teng (袁腾), Wang Feng (王锋). UV curing superhydrophilic and underwater superhydrophobic oily water separation membrane and preparation method and application [P]: CN, 103357276A. 2013.10.23
[19]	Tuteja Anish, Choi Wonjae, Ma Minglin, et al. Designing superoleophobic surfaces [J]. Science, 2007, 318: 1618-1622
[20]	Tu Weiping (涂伟萍), Yuan Teng (袁腾), Wang Feng (王锋). Oleophobic and hydrophilic polymer and its preparation method and the application in hygro-responsive membranes for oil-water separation [P]: CN, 103601826A. 2014.02.26
[21]	Feng Lin (冯琳), Cao Yingze (曹莹泽), Tao Lei (陶磊). A kind of underwater superoleophobic retinal response membrane of oil-water separation and its preparation method [P]: CN, 201310027762.6. 2013.01.24
[22]	Xue Zhongxin, Wang Shutao, Lin Ling, et al. A novel superhydrophilic and underwater superoleophobic hydrogel-coated mesh for oil/water separation [J]. Advanced Material, 2011, 23: 4270-4273
[23]	Yu Jihong (于吉红), Wen Qiang (温强), Di Jiancheng (邸建成), et al. A kind of inorganic separating membrane and its application in oil/water separation [P]: CN, 201210086896.0. 2012.07.25
[24]	Yang H, Pi P H, Cai Z Q, et al. Facile preparation of super-hydrophobic and super-oleophilic silica film on stainless steel mesh via sol-gel process [J]. Applied Surface Science, 2010, 13 (256): 4095-4102
[25]	Xu Guilong, Deng Lili, Wen Xiufang, et al. Synthesis and characterization of fluorine-containing poly-styrene-acrylate latex with core-shell structure using a reactive surfactant [J]. Journal of Coating Technology and Research, 2011, 8 (3): 401-407
[26]	Tu Weiping (涂伟萍), Yuan Teng (袁腾), Wang Feng (王锋). Superhydrophilic and underwater superoleophobic oil and water separation membrane and its preparation method and application [P]: CN, 103316507A. 2013.09.25
[27]	Lee C H, Baik S. Vertically-aligned carbon nano-tube membrane filters with superhydrophobicity and superoleophilicity [J]. Carbon, 2010, 48 (8): 2192-2197
[28]	Lee C H, Johnson N, Drelich J, et al. The performance of superhydrophobic and superoleophilic carbon nanotube meshes in water-oil filtration [J]. Carbon, 2011, 49: 669 -676
[29]	Tian Dongliang, Zhang Xiaofang, Wang Xiao, et al. Micro/nanoscale hierarchical structured ZnO mesh film for separation of water and oil [J]. Physical Chemistry Chemical Physics, 2011, 13: 14606-14610
[30]	Feng Lin (冯琳), Liu Na (刘娜), Wei Yan (危岩). A superhydrophilic and underwater superoleophobic oil-water separation membrane and its preparation method [P]: CN, 201210435983.2. 2012.11.05
[31]	Liu Xiangmei, He Junhui. Hierarchically structured superhydrophilic coatings fabricated by self-assembling raspberry-like silica nanospheres [J]. Journal of Colloid and Interface Science, 2007, 314: 341-345
[32]	Liu Xiangmei, He Junhui. Hierarchically structured porous films of silica hollow spheres via layer-by-layer assembly and their superhydrophilic and antifogging properties [J]. Chem. Phys. Chem., 2008, 9: 305-309
[33]	Liu Xiangmei, He Junhui. Superhydrophilic and antireflective properties of silica nanoparticle coatings fabricated via layer-by-layer assembly and post-calcination [J]. The Journal of Physical Chemistry C, 2009, 113: 148-152
[34]	Zhang Wenbin, Zhu Yuzhang, Liu Xia, et al. Salt-induced fabrication of superhydrophilic and underwater superoleophobic PAA-g-PVDF membranes for effective separation of oil-in-water emulsions [J]. Angewandte Chemie-International Edition, 2014, 53: 856-860

基于超亲水超疏油原理的网膜及其在油水分离中的应用

Coated mesh film based on superhydrophilic and superoleophobic principle and its application in oil-water separation

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