仿生雾水收集材料：从基础研究到性能提升策略

doi:10.11949/0438-1157.20200454

摘要/Abstract

摘要：

由于水资源污染、淡水资源日益匮乏，水危机已经严重影响到人们的日常生活。从晨雾中捕获水气则可以缓解干旱地区的缺水问题。受纳米布沙漠甲虫、仙人掌、蜘蛛丝等动植物自发捕集雾水的启发，构建特殊润湿性的仿生雾水收集材料备受关注。详细总结了仿生雾水收集材料的最新研究进展，讨论了仿生集水材料的设计和制备方法，并从雾水收集的四大仿生策略出发，介绍了提升雾水收集效率的设计方案。在此基础上，分析了当前仿生雾水收集过程存在的问题，展望了此类材料未来的发展趋势和方向。

关键词: 水危机, 特殊润湿性, 仿生材料, 雾水收集, 效率

Abstract:

Nowadays, the water crisis has seriously affected people??s daily life due to water pollution and the increasing shortage of fresh water. Capturing water from the morning fog can relieve water shortages in dry areas. Inspired by the spontaneous fog trapping of Namib desert beetles, cacti, spider silk, and other animals or plants, various bionic fog collection materials with special wetting properties have been constructed by researchers. This review summarizes the latest research progress of bio-inspired fog harvesting materials in detail, discusses the design and preparation method of constructing bionic water collection materials from the four major bio-inspired strategies of fog collection, and introduces the design schemes to improve the efficiency of fog harvesting. Furthermore, the problems existing in the current bionic water collection process are analyzed, and the development trend of the materials in the future is forecasted.

Key words: water crisis, special wettability, bioinspired material, fog harvesting, efficiency

中图分类号:

TB 34

周威, 陈立, 杜京城, 谭陆西, 董立春, 周才龙. 仿生雾水收集材料：从基础研究到性能提升策略[J]. 化工学报, 2020, 71(10): 4532-4552.

Wei ZHOU, Li CHEN, Jingcheng DU, Luxi TAN, Lichun DONG, Cailong ZHOU. Bio-inspired fog harvesting materials: from fundamental research to promotional strategy[J]. CIESC Journal, 2020, 71(10): 4532-4552.

参考文献 88

1	Gorjian S, Ghobadian B. Solar desalination: a sustainable solution to water crisis in iran[J]. Renew. Sust. Energ. Rev., 2015, 48: 571-584.
2	El-Ghonemy A M K. Fresh water production from/by atmospheric air for arid regions, using solar energy: review[J]. Renew. Sust. Energ. Rev., 2012, 16: 6384-6422.
3	Grubert E A, Stillwell A S, Webber M E. Where does solar-aided seawater desalination make sense? A method for identifying sustainable sites[J]. Desalination, 2014, 339: 10-17.
4	Raluy R G, Serra L, Uche J. Life cycle assessment of desalination technologies integrated with renewable energies[J]. Desalination, 2005, 183: 81-93.
5	文刚, 郭志光, 刘维民. 仿生超润湿材料的研究进展[J]. 中国科学:化学, 2018, 48: 1531-1547.
	Wen G, Guo Z G, Liu W M. Research progress of biomimetic superwetting materials [J]. Scientia Sinica: Chemistry, 2018, 48: 1531-1547.
6	江雷. 仿生智能纳米材料[M]. 北京: 科学出版社, 2015: 7.
	Jiang L. Biomimetic Intelligent Nanomaterials [M]. Beijing: Science Press, 2015: 7.
7	Wu H, Zhang R, Sun Y, et al. Biomimetic nanofiber patterns with controlled wettability[J]. Soft Matter, 2008, 4: 2429-2433.
8	Avinash M B, Verheggen E, Schmuck C, et al. Self-cleaning functional molecular materials[J]. Angew. Chem., Int. Ed., 2012, 51: 10324-10328.
9	Abualhamayel H I, Gandhidasan P. A method of obtaining fresh water from the humid atmosphere[J]. Desalination, 1997, 113: 51-63.
10	Klemm O, Schemenauer R S, Lummerich A, et al. Fog as a fresh-water resource: overview and perspectives[J]. Ambio, 2012, 41: 221-234.
11	Bartholomew G A, Lighton J R B, Louw G N. Energetics of locomotion and patterns of respiration in tenebrionid beetles from the namib desert[J]. J. Comp. Physiol. B, 1985, 155: 155-162.
12	Ju J, Bai H, Zheng Y, et al. A multi-structural and multi-functional integrated fog collection system in cactus[J]. Nat. Commun., 2012, 3: 1247.
13	Yi S, Wang J, Chen Z, et al. Cactus‐inspired conical spines with oriented microbarbs for efficient fog harvesting[J]. Adv. Mater. Technol., 2019, 4: 1900727.
14	Feng R, Xu C, Song F, et al. A bioinspired slippery surface with stable lubricant impregnation for efficient water harvesting[J]. ACS Appl. Mater. Interfaces, 2020, 12: 12373-12381.
15	陈振, 张增志, 杜红梅, 等. 仿生材料在集水领域应用的研究现状[J]. 材料工程, 2020, 48: 10-18.
	Chen Z, Zhang Z Z, Du H M, et al. Research status of biomimetic materials in the field of water collection [J]. Materials Engineering, 2020, 48:10-18.
16	Yin K, Du H, Dong X, et al. A simple way to achieve bioinspired hybrid wettability surface with micro/nanopatterns for efficient fog collection[J]. Nanoscale, 2017, 9: 14620-14626.
17	Young T. An essay on the cohesion of fluids[J]. Phil. Trans. R. Soc. London, 1805, 95: 65-87.
18	Xia F, Jiang L. Bio‐inspired, smart, multiscale interfacial materials[J]. Adv. Mater., 2008, 20: 2842-2858.
19	Su B, Tian Y, Jiang L. Bioinspired interfaces with superwettability: from materials to chemistry[J]. J. Am. Chem. Soc., 2016, 138: 1727-1748.
20	Berg J M, Eriksson L T, Claesson P M, et al. Three-component langmuir-blodgett films with a controllable degree of polarity[J]. Langmuir, 1994, 10: 1225-1234.
21	Wenzel R N. Resistance of solid surfaces to wetting by water[J]. Ind. Eng. Chem., 1936, 28: 988-994.
22	Cassie A, Baxter S. Wettability of porous surfaces[J]. Trans. Faraday Soc., 1944, 40: 546-551.
23	Furmidge C. Studies at phase interfaces(I): The sliding of liquid drops on solid surfaces and a theory for spray retention[J]. J. Colloid Interface Sci., 1962, 17: 309-324.
24	Li C, Li J, Chen C, et al. Tailoring ordered taper-nanopore arrays by combined nanosphere self-assembling, imprinting, anodizing and etching[J]. Chem. Commun., 2012, 48: 5100-5102.
25	Gao X, Jiang L. Biophysics: water-repellent legs of water striders[J]. Nature, 2004, 432: 36-38.
26	Feng L, Zhang Y, Xi J, et al. Petal effect: a superhydrophobic state with high adhesive force[J]. Langmuir, 2008, 24: 4114-4119.
27	Parker A R, Lawrence C R. Water capture by a desert beetle[J]. Nature, 2001, 414: 33-34.
28	Ju J, Bai H, Zheng Y, et al. A multi-structural and multi-functional integrated fog collection system in cactus[J]. Nat. Commun., 2012, 3: 1-6.
29	Zheng Y, Bai H, Huang Z, et al. Directional water collection on wetted spider silk[J]. Nature, 2010, 463: 640-643.
30	Chen H, Zhang P, Zhang L, et al. Continuous directional water transport on the peristome surface of nepenthes alata[J]. Nature, 2016, 532: 85-89.
31	Daniel S. Fast drop movements resulting from the phase change on a gradient surface[J]. Science, 2001, 291: 633-636.
32	Chaudhury M K, Whitesides G M. Correlation between surface free energy and surface constitution[J]. Science, 1992, 255: 1230-1232.
33	Lorenceau L, Qur D. Drops on a conical wire[J]. J. Fluid Mech., 2004, 510: 29-45.
34	Lee J, Hwang S, Cho D H, et al. Rf plasma based selective modification of hydrophilic regions on super hydrophobic surface[J]. Appl. Surf. Sci., 2017, 394: 543-553.
35	Gao Y, Wang J, Xia W, et al. Reusable hydrophilic-superhydrophobic patterned weft backed woven fabric for high-efficiency water-harvesting application[J]. ACS Sustain. Chem. Eng., 2018, 6: 7216-7220.
36	Wang Y, Zhang L, Wu J, et al. A facile strategy for the fabrication of a bioinspired hydrophilic–superhydrophobic patterned surface for highly efficient fog-harvesting[J]. J. Mater. Chem. A, 2015, 3: 18963-18969.
37	Cao M, Xiao J, Yu C, et al. Hydrophobic/hydrophilic cooperative Janus system for enhancement of fog collection[J]. Small, 2015, 11: 4379-4384.
38	Wang B, Zhang Y, Liang W, et al. A simple route to transform normal hydrophilic cloth into a superhydrophobic–superhydrophilic hybrid surface[J]. J. Mater. Chem. A, 2014, 2: 7845-7852.
39	Xu C, Feng R, Song F, et al. Desert beetle-inspired superhydrophilic/superhydrophobic patterned cellulose film with efficient water collection and antibacterial performance[J]. ACS Sustain. Chem. Eng., 2018, 6: 14679-14684.
40	Ye Q, Zhou F, Liu W. Bioinspired catecholic chemistry for surface modification[J]. Chem. Soc. Rev., 2011, 40: 4244-4258.
41	Takei G, Nonogi M, Hibara A, et al. Tuning microchannel wettability and fabrication of multiple-step Laplace valves[J]. Lab Chip, 2007, 7: 596-602.
42	Bai H, Wang L, Ju J, et al. Efficient water collection on integrative bioinspired surfaces with star-shaped wettability patterns[J]. Adv. Mater., 2014, 26: 5025-5030.
43	Zahner D, Abagat J, Svec F, et al. A facile approach to superhydrophilic-superhydrophobic patterns in porous polymer films[J]. Adv. Mater., 2011, 23: 3030-3034.
44	Seo J, Lee S, Lee J, et al. Guided transport of water droplets on superhydrophobic-hydrophilic patterned Si nanowires[J]. ACS Appl. Mater. Interfaces, 2011, 3: 4722-4729.
45	Zhang L, Wu J, Hedhili M N, et al. Inkjet printing for direct micropatterning of a superhydrophobic surface: toward biomimetic fog harvesting surfaces[J]. J. Mater. Chem. A, 2015, 3: 2844-2852.
46	Nishimoto S, Kubo A, Nohara K, et al. TiO₂-based superhydrophobic-superhydrophilic patterns: fabrication via an ink-jet technique and application in offset printing[J]. Appl. Surf. Sci., 2009, 255: 6221-6225.
47	Yu Z, Yun F F, Wang Y, et al. Desert beetle-inspired superwettable patterned surfaces for water harvesting[J]. Small, 2017, 13: 1701403.
48	Moazzam P, Tavassoli H, Razmjou A, et al. Mist harvesting using bioinspired polydopamine coating and microfabrication technology[J]. Desalination, 2018, 429: 111-118.
49	Tian X, Chen Y, Zheng Y, et al. Controlling water capture of bioinspired fibers with hump structures[J]. Adv. Mater., 2011, 23: 5486-5491.
50	Day R W, Mankin M N, Gao R, et al. Plateau-rayleigh crystal growth of periodic shells on one-dimensional substrates[J]. Nat. Nanotechnol., 2015, 10: 345-352
51	Bai H, Tian X, Zheng Y, et al. Direction controlled driving of tiny water drops on bioinspired artificial spider silks[J]. Adv. Mater., 2010, 22: 5521-5525.
52	Bai H, Ju J, Sun R, et al. Controlled fabrication and water collection ability of bioinspired artificial spider silks[J]. Adv. Mater., 2011, 23: 3708-3711.
53	Chen Y, Wang L, Xue Y, et al. Bioinspired spindle-knotted fibers with a strong water-collecting ability from a humid environment[J]. Soft Matter, 2012, 8: 11450-11454.
54	Bai H, Sun R, Ju J, et al. Large-scale fabrication of bioinspired fibers for directional water collection[J]. Small, 2011, 7: 3429-3433.
55	He X H, Wang W, Liu Y M, et al. Microfluidic fabrication of bio-inspired microfibers with controllable magnetic spindle-knots for 3D assembly and water collection[J]. ACS Appl. Mater. Interfaces, 2015, 7: 17471-17481.
56	Choi C H, Yi H, Hwang S, et al. Microfluidic fabrication of complex-shaped microfibers by liquid template-aided multiphase microflow[J]. Lab Chip, 2011, 11: 1477-1483.
57	Cheng Y, Zheng F, Lu J, et al. Bioinspired multicompartmental microfibers from microfluidics[J]. Adv. Mater., 2014, 26: 5184-5190.
58	Tian X, Bai H, Zheng Y, et al. Bio-inspired heterostructured bead-on-string fibers that respond to environmental wetting[J]. Adv. Funct. Mater., 2011, 21: 1398-1402.
59	Zhao L, Song C, Zhang M, et al. Bioinspired heterostructured bead-on-string fibers via controlling the wet-assembly of nanoparticles[J]. Chem. Commun., 2014, 50: 10651-10654.
60	Dong H, Wang N, Wang L, et al. Bioinspired electrospun knotted microfibers for fog harvesting[J]. ChemPhysChem, 2012, 13: 1153-1156.
61	Ju J, Yao X, Yang S, et al. Cactus stem inspired cone-arrayed surfaces for efficient fog collection[J]. Adv. Funct. Mater., 2014, 24: 6933-6938.
62	Peng Y, He Y, Yang S, et al. Magnetically induced fog harvesting via flexible conical arrays[J]. Adv. Funct. Mater., 2015, 25: 5967-5971.
63	Ju J, Xiao K, Yao X, et al. Bioinspired conical copper wire with gradient wettability for continuous and efficient fog collection[J]. Adv. Mater., 2013, 25: 5937-5942.
64	Heng X, Xiang M, Lu Z, et al. Branched ZnO wire structures for water collection inspired by cacti[J]. ACS Appl. Mater. Interfaces, 2014, 6: 8032-8041.
65	Xing H, Cheng J, Zhou C, et al. Fog collection on a conical copper wire: effect of fog flow velocity and surface morphology[J]. Micro Nano Lett., 2018, 13: 1068-1070.
66	Li X, Yang Y, Liu L, et al. 3D‐printed cactus‐inspired spine structures for highly efficient water collection[J]. Adv. Mater. Interfaces, 2019, 7: 1-10.
67	Wong T S, Kang S H, Tang S K, et al. Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity[J]. Nature, 2011, 477: 443-447.
68	Wang Y, Qian B, Lai C, et al. Flexible slippery surface to manipulate droplet coalescence and sliding, and its practicability in wind-resistant water collection[J]. ACS Appl. Mater. Interfaces, 2017, 9: 24428-24432.
69	Huang Y, Stogin B B, Sun N, et al. A switchable cross-species liquid repellent surface[J]. Adv. Mater., 2017, 29: 1604641.
70	Chen H, Zhang L, Zhang P, et al. A novel bioinspired continuous unidirectional liquid spreading surface structure from the peristome surface of Nepenthes alata[J]. Small, 2017, 13: 1601676.
71	Li C, Li N, Zhang X, et al. Uni-directional transportation on peristome-mimetic surfaces for completely wetting liquids[J]. Angew. Chem., Int. Ed., 2016, 55:14988-14992.
72	Tandon V, Kang W S, Robbins T A, et al. Microfabricated reciprocating micropump for intracochlear drug delivery with integrated drug/fluid storage and electronically controlled dosing[J]. Lab Chip, 2016, 16: 829-846.
73	Moghadam A D, Omrani E, Menezes P L, et al. Mechanical and tribological properties of self-lubricating metal matrix nanocomposites reinforced by carbon nanotubes (CNTs) and graphene—a review[J]. Compos. B. Eng., 2015, 77: 402-420.
74	Zhong L, Zhang R, Li J, et al. Efficient fog harvesting based on 1D copper wire inspired by the plant pitaya[J]. Langmuir, 2018, 34: 15259-15267.
75	Varanasi K K, Ming H, Bhate N, et al. Spatial control in the heterogeneous nucleation of water[J]. Appl. Phys. Lett., 2009, 95: 094101.
76	He M, Zhang Q, Zeng X, et al. Hierarchical porous surface for efficiently controlling microdroplets self-removal[J]. Adv. Mater., 2013, 25: 2291-2295.
77	Hu R, Wang N, Hou L, et al. A bioinspired hybrid membrane with wettability and topology anisotropy for highly efficient fog collection[J]. J. Mater. Chem. A, 2019, 7: 124-132.
78	Ren F, Li G, Zhang Z, et al. A single-layer Janus membrane with dual gradient conical micropore arrays for self-driving fog collection[J]. J. Mater. Chem. A, 2017, 5: 18403-18408.
79	Bai H, Zhang C, Long Z, et al. A hierarchical hydrophilic/hydrophobic cooperative fog collector possessing self-pumped droplet delivering ability[J]. J. Mater. Chem. A, 2018, 6: 20966-20972.
80	Liu W, Fan P, Cai M, et al. An integrative bioinspired venation network with ultra-contrasting wettability for large-scale strongly self-driven and efficient water collection[J]. Nanoscale, 2019, 11: 8940-8949.
81	Wang Y, Wang X, Lai C, et al. Biomimetic water-collecting fabric with light-induced superhydrophilic bumps[J]. ACS Appl. Mater. Interfaces, 2016, 8: 2950-2960.
82	Xing Y, Shang W, Wang Q, et al. Integrative bioinspired surface with wettable patterns and gradient for enhancement of fog collection[J]. ACS Appl. Mater. Interfaces, 2019, 11: 10951-10958.
83	Park K C, Kim P, Grinthal A, et al. Condensation on slippery asymmetric bumps[J]. Nature, 2016, 531(7592): 78-82.
84	Zhang X, Sun L, Wang Y, et al. Multibioinspired slippery surfaces with wettable bump arrays for droplets pumping[J]. Proc. Natl. Acad. Sci. U.S.A., 2019, 116: 20863-20868.
85	Wang Y, Liang X, Ma K, et al. Nature-inspired windmill for water collection in complex windy environments[J]. ACS Appl. Mater. Interfaces, 2019, 11: 17952-17959.
86	Chen H, Ran T, Gan Y, et al. Ultrafast water harvesting and transport in hierarchical microchannels[J]. Nat. Mater., 2018, 17: 935-942.
87	Li J, Zhou Y, Wang W, et al. A bio-inspired superhydrophobic surface for fog collection and directional water transport[J]. J. Alloys Compd., 2020, 819: 152968.
88	Kim S W, Kim J, Park S S, et al. Enhanced water collection of bio-inspired functional surfaces in high-speed flow for high performance demister[J]. Desalination, 2020, 479: 114314.

[1]	邢雷, 苗春雨, 蒋明虎, 赵立新, 李新亚. 井下微型气液旋流分离器优化设计与性能分析[J]. 化工学报, 2023, 74(8): 3394-3406.
[2]	高金明, 郭玉娇, 鄂承林, 卢春喜. 一种封闭罩内顺流多旋臂气液分离器的分离特性研究[J]. 化工学报, 2023, 74(7): 2957-2966.
[3]	周继鹏, 何文军, 李涛. 异形催化剂上乙烯催化氧化失活动力学反应工程计算[J]. 化工学报, 2023, 74(6): 2416-2426.
[4]	葛泽峰, 吴雨青, 曾名迅, 查振婷, 马宇娜, 侯增辉, 张会岩. 灰化学成分对生物质气化特性的影响规律[J]. 化工学报, 2023, 74(5): 2136-2146.
[5]	查坦捷, 杨涵, 秦荷杰, 关小红. 仿生材料的构建及其在水环境化学领域中的研究进展[J]. 化工学报, 2023, 74(2): 585-598.
[6]	刘星伟, 贾胜坤, 罗祎青, 袁希钢. 基于信赖域算法的精馏塔优化[J]. 化工学报, 2022, 73(5): 2031-2038.
[7]	卢沛, 罗向龙, 陈健勇, 杨智, 梁颖宗, 陈颖. 板式换热器及其热力系统的运行特性和高级分析[J]. 化工学报, 2021, 72(S1): 512-519.
[8]	侯勇俊, 祝敬涛, 李华川, 吴先进, 蒋锐. 均衡运动旋转振动筛DEM数值模拟[J]. 化工学报, 2021, 72(5): 2706-2717.
[9]	朱明军, 胡大鹏. 三相卧螺离心机设计分析及结构参数对分离效果的影响[J]. 化工学报, 2021, 72(4): 2113-2122.
[10]	于程远, 吴金奎, 周利, 吉旭, 戴一阳, 党亚固. 基于深度学习预测有机光伏电池能量转换效率[J]. 化工学报, 2021, 72(3): 1487-1495.
[11]	郭达, 祁贵生, 刘有智, 焦纬洲, 闫文超, 高雨松. 错流旋转填料床的质、热同传性能及传热机理研究[J]. 化工学报, 2021, 72(11): 5543-5551.
[12]	许晓佳, 吴永真, 朱为宏. CsPbX₃钙钛矿材料与光伏器件稳定性强化研究进展[J]. 化工学报, 2020, 71(9): 3933-3949.
[13]	黄健, 赵众. 延迟焦化加热炉热效率的机理建模与实时估计应用[J]. 化工学报, 2020, 71(7): 3140-3150.
[14]	姚春, 黄龙龙, 常江伟, 丁一旺, 于畅, 邱介山. 碳分子筛的优化设计及其I₃^-还原性能研究[J]. 化工学报, 2020, 71(6): 2696-2704.
[15]	叶小琴, 闻沚玥, 沈王强, 卢兴. 富勒烯材料在钙钛矿太阳能电池中的应用[J]. 化工学报, 2020, 71(6): 2510-2529.