双微乳液法制备纳米硫酸钡颗粒

doi:10.11949/j.issn.0438-1157.20171265

化工学报 ›› 2018, Vol. 69 ›› Issue (6): 2767-2774.DOI: 10.11949/j.issn.0438-1157.20171265

• 材料化学工程与纳米技术 • 上一篇下一篇

双微乳液法制备纳米硫酸钡颗粒

叶飞飞^1,2, 郭晓燕¹, 侯静¹, 刘旭¹, 汪亮亮¹, 王梓宇¹, 靳海波¹

1. 北京石油化工学院化学工程学院, 燃料清洁化及高效催化减排技术北京市重点实验室, 北京 102617;
2. 北京化工大学化学工程学院, 北京 100029

收稿日期:2017-09-18 修回日期:2017-11-06 出版日期:2018-06-05 发布日期:2018-06-05
通讯作者: 靳海波
基金资助:
国家自然科学基金项目（91634101）；北京市属高校高水平教师队伍建设支持计划高水平创新团队建设计划项目（IDHT20180508）。

Synthesis of BaSO₄ nanoparticles by double microemulsion method

YE Feifei^1,2, GUO Xiaoyan¹, HOU Jing¹, LIU Xu¹, WANG Liangliang¹, WANG Ziyu¹, JIN Haibo¹

1. College of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, Beijing 102617, China;
2. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2017-09-18 Revised:2017-11-06 Online:2018-06-05 Published:2018-06-05
Supported by:
supported by the National Natural Science Foundation of China (91634101) and the Project of Construction of Innovative Teams and Teacher Career Development for Universities and Colleges under Beijing Municipality (IDHT20180508).

摘要/Abstract

摘要：

在水溶液/TritonX-100/正己醇/环己烷组成的反相微乳液中，以氯化钡和硫酸钠为原料，通过沉淀反应，制备出类球形BaSO₄纳米颗粒，并通过XRD、SEM、TEM、FTIR对其进行表征。考察了三种反应方式、水/TritonX-100摩尔比（R）、反应物浓度以及助表面活性剂/表面活性剂摩尔比（P）对纳米BaSO₄颗粒大小和形貌的影响。同时考察了R对微乳液液滴大小和粒径分布的影响，并通过动态光散射技术（DLS）对微乳液液滴进行测定。实验结果表明：室温条件下，采用双微乳液法，R=17.97，P在2.11～4.22之间是纳米BaSO₄颗粒合成的最佳反应条件，反应物浓度对BaSO₄颗粒的大小和形貌几乎没有影响。在该反应条件下，合成出的类球形BaSO₄粒径为18～22 nm，产率可达87.5%。

关键词: 反相微乳液, 纳米粒子, 均一粒径, 类球形, 合成, 粒度分布

Abstract:

Uniform nano BaSO₄ quasispheres were prepared by precipitation reaction with barium chloride and sodium sulfate as raw materials in reverse microemulsion composed of aqueous solution/TritonX-100/n-hexanol/cyclohexane. The product was characterized by XRD (X-ray diffraction), SEM (scanning electron microscope), TEM (transmission electron microscope) and FTIR (Fourier transform infrared spectroscopy). The effects of three reaction modes,[H₂O]/[Triton X-100] molar ratio (R), reactant concentration and[co-surfactants]/[surfactants] molar ratio (P) on the size and morphology of BaSO₄ quasispheres were investigated. At the same time, the effects of the R on the size and size distribution of micro-emulsion droplets were investigated by dynamic light scattering (DLS). The results show that under room temperature, using double microemulsion method, R=17.97, P between 2.11-4.22 is the best reaction condition for the synthesis of BaSO₄ quasispheres, and the reactant concentration had little effect on the size and morphology of BaSO₄ quasispheres. Under the reaction conditions, the size of BaSO₄ nano-quasispheres was 18-22 nm, and the yield was 87.5%.

Key words: reverse microemulsion, nanoparticles, uniform, quasispheres, synthesis, size distribution

中图分类号:

TQ027

叶飞飞, 郭晓燕, 侯静, 刘旭, 汪亮亮, 王梓宇, 靳海波. 双微乳液法制备纳米硫酸钡颗粒[J]. 化工学报, 2018, 69(6): 2767-2774.

YE Feifei, GUO Xiaoyan, HOU Jing, LIU Xu, WANG Liangliang, WANG Ziyu, JIN Haibo. Synthesis of BaSO₄ nanoparticles by double microemulsion method[J]. CIESC Journal, 2018, 69(6): 2767-2774.

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双微乳液法制备纳米硫酸钡颗粒

Synthesis of BaSO₄ nanoparticles by double microemulsion method

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双微乳液法制备纳米硫酸钡颗粒

Synthesis of BaSO4 nanoparticles by double microemulsion method

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Synthesis of BaSO₄ nanoparticles by double microemulsion method