化工学报 ›› 2022, Vol. 73 ›› Issue (8): 3381-3393.DOI: 10.11949/0438-1157.20220592
收稿日期:
2022-04-27
修回日期:
2022-08-22
出版日期:
2022-08-05
发布日期:
2022-09-06
通讯作者:
朱为宏
作者简介:
胡宏龙(1995—),男,博士,huhlecust@foxmail.com
基金资助:
Honglong HU1(), Zhigang ZHENG2, Weihong ZHU1()
Received:
2022-04-27
Revised:
2022-08-22
Online:
2022-08-05
Published:
2022-09-06
Contact:
Weihong ZHU
摘要:
光控手性分子开关结合到液晶材料体系中,可以有效利用其光诱导的手性变化,实现远程光刺激液晶材料的自组装螺旋超结构。二芳基乙烯(DAE)是一类新型的、有前景的光致变色分子,作为智能光响应开关,在手性向列相液晶材料体系中表现出优异的性能。本文重点围绕结构设计,总结了一系列具备不同螺旋扭曲力(HTP)的手性DAE分子及其在液晶自组装螺旋结构中所产生的特定性能,如光可逆宽范围调控和光控手性反转。该类光控DAE手性向列相液晶体系在手性调控、光学显示、可调谐激光等领域具有巨大的应用潜力。最后讨论了该领域面临的挑战和机遇,并指出了未来可能的发展方向。
中图分类号:
胡宏龙, 郑致刚, 朱为宏. 基于光控二芳基乙烯的手性向列相液晶体系研究进展[J]. 化工学报, 2022, 73(8): 3381-3393.
Honglong HU, Zhigang ZHENG, Weihong ZHU. Progress of chiral nematic liquid-crystal systems with light-driven diarylethenes[J]. CIESC Journal, 2022, 73(8): 3381-3393.
图3 手性DAE分子1 (a) [65]和分子2(b) [66]的化学结构及其对应的不同光照下的显微织构图
Fig.3 Chemical structures of chiral DAE molecule 1 (a) [65] and molecule 2 (b)[66] and their corresponding textures under different light irradiation
图4 手性DAE分子(R)-D1、(R)-D3、(R)-D5的化学结构及其对应的不同光照下的显微织构图[67]
Fig.4 Chemical structures of chiral DAE molecule (R)-D1, (R)-D3, (R)-D5, and their corresponding textures under different light irradiation[67]
图5 手性DAE 分子3 (a) [68]和分子4 (b) [69]的化学结构及其对应的不同光照下的反射光谱图
Fig.5 Chemical structures of chiral DAE molecule 3 (a)[68] and molecule 4 (b)[69], and their corresponding reflection spectra under different light irradiation
图6 手性DAE分子5(a) [70]、分子6(b) [71]、分子7(c) [72]的化学结构及其对应的不同光照下反射光谱图和手性反转图
Fig.6 Chemical structures of chiral DAE molecule 5 (a)[70], molecule 6 (b) [71] and molecule 7 (c) [72], and their corresponding reflection spectra and chirality inversion under different light irradiation
图7 手性DAE分子 (M)-1o和 (M)-2o的化学结构及其对应的不同光照下的反射光谱图[51]
Fig.7 Chemical structures of chiral DAE molecule (M)-1o and (M)-2o, and their corresponding reflection spectral under different light irradiation[51]
图8 胆甾相液晶螺旋方向调控:(a) 近红外光驱动的手性螺旋反转示意图[73];(b) 光电调控倾斜螺旋超结构体系反射光谱图[48];(c) 光驱动胆甾相螺旋轴三维调控[49]
Fig.8 Modulation of cholesteric liquid-crystal helical direction: (a) schematic illustration of near-infrared light driven chiral helix inversion[73]; (b) reflection spectra of the heliconical superstructures modulated by electric field and light[48]; (c) three-dimensional modulation of light-driven cholesteric helical axis[49]
图9 多色图案显示:(a) RGB三色图案显示图[69]; (b) 液晶微滴反射模式偏振显微镜图像[50]; (c) 可逆、可擦、渐变、角度依赖的多重防伪技术[51]
Fig.9 Multicolor pattern display: (a) RGB three-color pattern display[69]; (b) polarization microscopy image of the liquid crystal droplet in reflection mode[50]; (c) reversible, erasable, gradient, angle-dependent multiple anti-counterfeiting technologies[51]
图10 光调谐激光发射:(a) 光电调控倾斜螺旋超结构体系激光光谱图[48];(b) 光调谐激光发射及其对应的反射光谱图[51];(c) 四维可调谐激光示意图[74]
Fig.10 Light modulated laser emission: (a) laser spectra of the heliconical superstructures modulated by electric field and light[48]; (b) light manipulated laser emission and its corresponding reflection spectra[51]; (c) schematic diagram of the quadri-dimensional manipulable laser[74]
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