石蜡乳液中直接沉淀制备单分散性的纳米氧化镁

doi:10.11949/j.issn.0438-1157.20141022

化工学报 ›› 2015, Vol. 66 ›› Issue (2): 843-847.DOI: 10.11949/j.issn.0438-1157.20141022

• 材料化学工程与纳米技术 • 上一篇下一篇

石蜡乳液中直接沉淀制备单分散性的纳米氧化镁

贺兴, 谭世语, 郑小刚, 董立春, 李少波, 陈红梅, 罗自萍

重庆大学化学化工学院, 重庆 400044

收稿日期:2014-07-08 修回日期:2014-10-13 出版日期:2015-02-05 发布日期:2015-02-05
通讯作者: 罗自萍
基金资助:
国家自然科学基金项目(21176270)。

Preparation of mono-dispersed MgO nanoparticles by using direct deposition in paraffin emulsion system

HE Xing, TAN Shiyu, ZHENG Xiaogang, DONG Lichun, LI Shaobo, CHEN Hongmei, LUO Ziping

School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China

Received:2014-07-08 Revised:2014-10-13 Online:2015-02-05 Published:2015-02-05
Supported by:
supported by the National Natural Science Foundation of China (21176270).

摘要/Abstract

摘要：

MgCl₂·6H₂O和Na₂CO₃在石蜡乳液中直接沉淀出碱式碳酸镁/石蜡前驱体,该前驱体在600℃条件下焙烧后获得MgO纳米粉体。采用TG-DTA、FTIR、XRD、BET和FESEM等手段对MgO粉体进行表征分析,并研究焙烧温度和物料比对纳米MgO的粒径及形貌的影响。结果表明,在最佳工艺条件下,石蜡乳液体系中能够得到分散性好、晶粒呈六边形、颗粒均匀、平均粒径约60 nm和比表面积132.54 m²·g^-1的纳米MgO。其最佳工艺条件为:MgCl₂·6H₂O溶液浓度0.6 mol·L^-1、Na₂CO₃溶液浓度0.6 mol·L^-1、反应时间0.5 h、焙烧温度600℃和焙烧时间3 h。

关键词: MgO, 乳液体系, 纳米粒子, 沉淀法, 石蜡

Abstract:

MgO nanoparticles were prepared by using a direct deposition method, in which, the precursor, alkaline magnesium carbonate/paraffin, was firstly obtained by direct precipitation of the mixture of MgCl₂·6H₂O and Na₂CO₃ in paraffin emulsion, and then calcined at 600℃. The nanoparticles were characterized by using TG-DTA, FTIR, XRD, BET and FESEM. Under the optimum conditions, the as-prepared MgO nanoparticles were hexagonal crystals with a uniform size of around 60 nm and a specific surface area of 132.54 m²·g^-1. The optimum preparation conditions were: MgCl₂·6H₂O concentration, 0.6 mol·L^-1; Na₂CO₃ concentration, 0.6 mol·L^-1; reaction time, 0.5 h; calcination temperature, 600℃, and calcination time, 3 h.

Key words: MgO, emulsion system, nanoparticles, precipitation, paraffin

中图分类号:

TQ132.2

贺兴, 谭世语, 郑小刚, 董立春, 李少波, 陈红梅, 罗自萍. 石蜡乳液中直接沉淀制备单分散性的纳米氧化镁[J]. 化工学报, 2015, 66(2): 843-847.

HE Xing, TAN Shiyu, ZHENG Xiaogang, DONG Lichun, LI Shaobo, CHEN Hongmei, LUO Ziping. Preparation of mono-dispersed MgO nanoparticles by using direct deposition in paraffin emulsion system[J]. CIESC Journal, 2015, 66(2): 843-847.

参考文献 19

[1]	Yang Hongping(杨红萍), Kong Jie(孔洁), Wu Bo(吴博). Progress on nanometer magnesia synthetic method [J]. Liaoning Chemical Industry(辽宁化工), 2008, 37(10): 692-694
[2]	Mishakow I V, Bedilo A F, Richards R M. Nanocrystalline MgO as adehydrohalogenation catalyst [J]. J. Catal.,2002, 206: 40-48.
[3]	Zhang Wei(张伟), Wang Baohe(王宝和). Progress on preparation of nano-structured magnesia powder [J]. China Powder Science and Technology(中国粉体技术), 2004, 2: 40-44
[4]	Yin Lisong(尹荔松), Chen Mintao(陈敏涛), Li Ting(李婷), Zhou Kesheng(周克省), Gao Songhua(高松华). Preparation of rhombic MgO nanoflakes from dolomites [J]. Acta. Phys.-Chim. Sin.(物理化学学报), 2007, 23(3): 433-437
[5]	Zheng Xiaogang(郑小刚), Li Changhong(李长红), Li Haimin(李海民). Modified magnesium hydroxide in a new-type solvent system [J]. Journal of Saltlake Reserch(盐湖研究), 2010, 18(2): 41-46
[6]	Hu Zhangwen(胡章文), Zheng Longjin(郑龙金). On preparation and surface modification of nanometer MgO [J]. Journal of Anhui University of Technology and Science(安徽工程科技学院学报), 2006, 21(4): 4-7
[7]	Lucas E M, Klabunde K J. Nanocrystals as destructive adsorbents for mimics of chemical warfare agents [J]. Nanostructured Materials, 1999, 12: 179-182
[8]	He Xiaohong(何晓红), Liao Zhengfu(廖正福), Zhang Xiaowei(张小伟), Zhang Shuofeng(张烁锋). Preparation and properties of scratch-resistant PC/ABS/nano-MgO blends [J]. Materials Research and Application(材料研究与应用), 2008, 2(4): 273-276
[9]	Zheng Xiaogang(郑小刚), Li Changhong(李长红), Li Haimin(李海民). Modification magnesium hydroxide prepared by water-bath method [J]. Journal of Saltlake Research(盐湖研究), 2010, 18(3): 68-72
[10]	Liao Liling(廖莉玲), Liu Jiping(刘吉平). Preparation of nanometer MgO by solid state reaction [J]. Fine Chemicals(精细化工), 2001, 18(12): 696-698
[11]	Chhor K, Bocquet J F, Pommier C. Syntheses of submieron magnesium oxide powders [J]. Mater. Chem. Phys., 1995, 40: 63-68
[12]	Zhang Gai(张改), Tian Min(田敏), Feng Xun(冯勋). Preparation and characterization of ultra-fine MgO powder [J]. Guangzhou Chemical Industry(广州化工), 2012, 40(10): 59-61
[13]	Gao Zhijin(高志谨), Qin Bingjie(秦兵杰), Feng Guolin(冯国琳). Study on preparation of nanometer MgO by homogeneous precipitation method [J]. Paper Science and Technology(造纸科学与技术), 2013, 32(4): 53-57
[14]	Zhang Zhigang(张志刚), Yuan Yuan(袁媛), Liu Changsheng(刘昌胜). Synthesis of nanometer magnesia by SOL-GEL method [J]. Journal of the Chinese Ceramic Society(硅酸盐学报), 2005, 33(8): 968-974
[15]	Wang Duzheng(王笃政), Sun Yongjie(孙永杰), Liu Xiaoyu(刘晓逾), Xiang Yang(向阳), Wang Peng(王鹏). The process research on preparation technology of nano-magnesia [J]. Powder Metallurgy Industry (粉末冶金工业), 2012, 22(6): 49-53
[16]	Xu Ke(许珂), Zhang Baolin(张保林), Hou Cuihong(侯翠红), Chen Keke(陈可可). Review on nano-magnesia preparation technology [J]. Inorganic Chemicals Industry(无机盐工业), 2007, 39(6): 7-9
[17]	Maria A A, Jose A B, Victoriano B. Characterization of various magnesium oxides by XRD and 1H MAS NMR spectroscopy [J]. J. Solid State Chem., 1999, 144: 25-29
[18]	Hong Ruixiang(洪瑞祥), Ju Yilian(剧鹢莲), Chen Suqin(陈素琴), Xia Shuping(夏树屏). The study for some physical and chemical properties of trihydrated magnesium carbonate and its hydrolytic product-basic magnesium carbonate [J]. Journal of Chemical Industry and Engineering(China)(化工学报), 1983,34(2):156-160
[19]	Liu Guoliang(刘国良), Zhu Yimin(朱一民), Fang Xin(房鑫), Zhang Weijia(张维佳). Preparation of MgO with different nanoparticle sizes and their infrared wave absorptivities [J]. Journal of Northeastern University(东北大学学报), 2010, 31(8): 1192-1195

石蜡乳液中直接沉淀制备单分散性的纳米氧化镁

Preparation of mono-dispersed MgO nanoparticles by using direct deposition in paraffin emulsion system

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 19

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张双星, 刘舫辰, 张义飞, 杜文静. R-134a脉动热管相变蓄放热实验研究[J]. 化工学报, 2023, 74(S1): 165-171.
[2]	仪显亨, 周骛, 蔡小舒, 蔡天意. 光纤后向动态光散射测量纳米颗粒的浓度适用范围研究[J]. 化工学报, 2023, 74(8): 3320-3328.
[3]	李勇, 高佳琦, 杜超, 赵亚丽, 李伯琼, 申倩倩, 贾虎生, 薛晋波. Ni@C@TiO₂核壳双重异质结的构筑及光热催化分解水产氢[J]. 化工学报, 2023, 74(6): 2458-2467.
[4]	黄心童, 耿宇昊, 刘恒源, 陈卓, 徐建鸿. 微流控制备新型功能纳米粒子研究进展[J]. 化工学报, 2023, 74(1): 355-364.
[5]	曲国娟, 江涛, 刘涛, 马骧. 超分子策略调控金纳米团簇的发光行为[J]. 化工学报, 2023, 74(1): 397-407.
[6]	张炜, 李昊阳, 徐纯刚, 李小森. 气体水合物生成微观机理及分析方法研究进展[J]. 化工学报, 2022, 73(9): 3815-3827.
[7]	张鑫, 许蕊, 路馨语, 牛永安. SiO₂@BiOCl-Bi₂₄O₃₁Cl₁₀核壳微球的合成及光催化[J]. 化工学报, 2022, 73(8): 3636-3646.
[8]	张苗, 杨洪海, 尹勇, 徐悦, 沈俊杰, 卢心诚, 施伟刚, 王军. 氧化石墨烯/水脉动热管的启动及传热特性[J]. 化工学报, 2022, 73(3): 1136-1146.
[9]	李文祥, 王钧禾, 郝怡静, 周乐平. 淬火初温影响疏水表面沸腾传热特性的实验研究[J]. 化工学报, 2022, 73(12): 5394-5404.
[10]	林肯, 许肖永, 李强, 胡定华. 石蜡-膨胀石墨复合相变材料热导率研究[J]. 化工学报, 2021, 72(8): 4425-4432.
[11]	董晓锐, 王凯, 骆广生. 金纳米颗粒的微反应连续合成[J]. 化工学报, 2021, 72(7): 3823-3831.
[12]	朱丹丹, 许雄文, 刘金平, 卢炯. 混合润湿性图案化铜基表面冷凝换热性能研究[J]. 化工学报, 2021, 72(5): 2528-2546.
[13]	陈婷婷, 尹炯婷, 许映杰. 离子液体在纳米ZnO材料制备中的研究进展[J]. 化工学报, 2021, 72(5): 2436-2447.
[14]	茹绍青, 武亚飞, 车黎明. 低过冷度石蜡Pickering乳液的制备和表征[J]. 化工学报, 2021, 72(4): 2309-2316.
[15]	齐聪, 李可傲, 李春阳. 微肋结构对纳米流体绕流圆柱热性能的影响[J]. 化工学报, 2021, 72(4): 2006-2017.