化工学报 ›› 2021, Vol. 72 ›› Issue (5): 2436-2447.DOI: 10.11949/0438-1157.20201409

• 综述与专论 • 上一篇    下一篇

离子液体在纳米ZnO材料制备中的研究进展

陈婷婷(),尹炯婷,许映杰()   

  1. 绍兴文理学院化学化工学院,浙江 绍兴 312000
  • 收稿日期:2020-10-09 修回日期:2020-12-09 出版日期:2021-05-05 发布日期:2021-05-05
  • 通讯作者: 许映杰
  • 作者简介:陈婷婷(1998—),女,硕士研究生,1042566987@qq.com
  • 基金资助:
    国家自然科学基金项目(21978172);浙江省自然科学基金项目(Y18B060014);浙江省大学生科技创新项目(2019R432023)

Research progress of ionic liquids in preparation of ZnO nanomaterials

CHEN Tingting(),YIN Jiongting,XU Yingjie()   

  1. College of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, Zhejiang, China
  • Received:2020-10-09 Revised:2020-12-09 Online:2021-05-05 Published:2021-05-05
  • Contact: XU Yingjie

摘要:

离子液体(ILs)具有蒸气压低、液程宽、热稳定性好、结构和性质可调节等特点, 作为反应溶剂、模板剂或结构导向剂等在纳米材料制备领域得到了广泛的应用。纳米ZnO在传感器、太阳能电池、光催化和发光二极管等领域具有广泛的应用。总结了近年来ILs在纳米ZnO材料制备中的研究进展, 重点归纳和比较了常规非质子型ILs、质子型ILs、碱性ILs和聚ILs在制备纳米ZnO中的应用,及其调控纳米ZnO形貌、尺寸和性能的作用特点, 并为今后ILs应用于金属纳米材料的制备提出了建议。

关键词: 离子液体, 氧化锌, 纳米材料, 制备, 纳米粒子

Abstract:

Ionic liquids (ILs) are a new type of green solvent, which have been widely used in the field of nanomaterial preparation as a solvent, template or structure directing agent due to their unique properties, such as low vapor pressure, wide liquid temperature range, non-flammability, chemical stability and tunable structure and properties. Nano-ZnO materials have a wide range of applications in the field of sensors, solar cells and photocatalysis. The research progress of ILs in the preparation of nano-ZnO materials in recent years is summarized. The applications of traditional aprotic ILs, protic ILs, basic ILs and poly(ionic liquid)s in the synthesis of nano-ZnO materials are compared and analyzed, as well as their roles in regulating the morphology, particle size and properties of nano-ZnO. And put forward suggestions for the future application of ILs in the preparation of metal nanomaterials.

Key words: ionic liquids, zinc oxide, nanomaterials, preparation, nanoparticles

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