小角X射线散射在分子筛研究中的应用

doi:10.11949/j.issn.0438-1157.20160389

化工学报 ›› 2016, Vol. 67 ›› Issue (8): 3146-3159.DOI: 10.11949/j.issn.0438-1157.20160389

小角X射线散射在分子筛研究中的应用

巩雁军¹, 刘汝庚^1,2, 赵晓萌¹, 张恒¹

1 中国石油大学(北京)化学工程学院, CNPC催化重点实验室, 北京 102249;
2 中国科学院高能物理研究所, 北京 100049

收稿日期:2016-03-31 修回日期:2016-05-24 出版日期:2016-08-05 发布日期:2016-08-05
通讯作者: 巩雁军
基金资助:
国家重点基础研究发展计划项目（2012CB215002）；国家自然科学基金项目（21776255，21276278，U1332107，U1532105）；中国矿业大学煤炭资源与安全开采国家重点实验室（SKLCRSM14KFA02）。

Review on application of small angle X-ray scattering to synthesis and characterization of zeolite

GONG Yanjun¹, LIU Rugeng^1,2, ZHAO Xiaomeng¹, ZHANG Heng¹

1 College of Chemical Engineering, the Key Laboratory of Catalysis of CNPC, China University of Petroleum, Beijing 102249, China;
2 Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

Received:2016-03-31 Revised:2016-05-24 Online:2016-08-05 Published:2016-08-05
Supported by:
supported by the National Basic Research Program of China (2012CB215002), the National Natural Science Foundation of China (21776255, 21276278, U1332107, U1532105) and the State Key Laboratory for Coal Resources and Safe Mining, China University of Mining & Technology (SKLCRSM14KFA02).

摘要/Abstract

摘要：

小角X射线散射（SAXS）是在纳米尺度范围内研究物质内部电子密度不均匀区几何结构的物理手段。着重介绍了同步辐射光源小角X射线散射技术（SAXS）优势和特点，系统地总结了SAXS技术在溶胶-凝胶过程、分子筛合成过程及分子筛表征方面的最新进展，尤其是SAXS技术研究溶胶体系中硅物种的存在行为及其对分子筛合成的影响规律，以及在研究分子筛的分形结构、粒径尺寸和介孔的分子筛孔道的大小、形貌和分子筛界面特征方面的最新进展。最后分析了SAXS在分子筛研究中存在问题并对其在该领域未来的研究方向进行了展望。

关键词: SAXS, 沸石, 溶胶-凝胶, 介孔材料, 表征方法

Abstract:

As a physical technique, small angle X-ray scatter (SAXS) can be used to study the geometric structure of inhomogeneous electron density zone inside the matter at nanometer level. This review focuses on advantages and features of synchrotron radiation X-ray source SAXS, and the newly progress of its application to characterizations of sol-gel process, synthesis process and structure of zeolite, in particular, the existence behavior of silicoaluminum species in sol-gel system, the influence on synthesis of zeolite and the fractal structure, particle size, mesoporous size, morphology and interface features of zeolite. Finally, the problems existing in SAXS application to zeolite-related researches are discussed and the future research direction is proposed.

Key words: SAXS, zeolite, sol-gel, mesoporous materials, characterization method

中图分类号:

O643.3

巩雁军, 刘汝庚, 赵晓萌, 张恒. 小角X射线散射在分子筛研究中的应用[J]. 化工学报, 2016, 67(8): 3146-3159.

GONG Yanjun, LIU Rugeng, ZHAO Xiaomeng, ZHANG Heng. Review on application of small angle X-ray scattering to synthesis and characterization of zeolite[J]. CIESC Journal, 2016, 67(8): 3146-3159.

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小角X射线散射在分子筛研究中的应用

Review on application of small angle X-ray scattering to synthesis and characterization of zeolite

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