Interface design and properties of core-shell structure cathode materials

doi:10.11949/0438-1157.20190081

Abstract

Abstract:

The core-shell structure battery material can produce synergistic effect from core and shell and has the advantages of high specific capacity, great redox reversibility, high ion diffusion rate and low cost and strong security. It has wide application in battery materials research.The core-shell structure design of ternary battery materials is mainly divided into non-electroactive materials core-shell, common core-shell, concentration gradient core-shell structure design and full-concentration gradient core-shell structure design. The synthesis method of ternary battery materials for core-shell structure is mainly divided into chemical co-precipitation method, hydrothermal method, sol-gel method, and so on. Electrochemical, thermodynamics and kinetics properties were reviewed, the research status and application of theoretical calculation and numerical simulation of core-shell battery materials were discussed. Finally, the application and prospect of core-shell structural cathode materials were briefly introduced.

Key words: core-shell structure, electrochemical, thermodynamics, kinetics, simulation calculation

摘要：

核壳结构电池材料能从核心和壳体两方面产生协同作用，具有比容量高、氧化还原可逆性好、离子扩散速率高、成本低、安全性强等优点，在电池材料研究中有广泛应用。三元电池材料的核壳结构设计主要分为非电活性材料核壳结构设计、普通核壳结构设计、浓度梯度核壳结构设计、全浓度梯度核壳结构设计等；核壳结构三元电池材料的合成方法主要分为：化学共沉淀法、水热法、溶胶-凝胶法等，综述了核壳结构电池材料热力学、电化学、动力学性能，对核壳结构电池材料理论计算、数值模拟的研究现状和应用进行了阐述，最后简述了核壳结构正极材料的应用和展望。

关键词: 核壳结构, 电化学, 热力学, 动力学, 模拟计算

CLC Number:

O 646

Liubin SONG, Peng JIANG, Zhongliang XIAO, Chengfeng ZHOU, Anxian LI, Zhenzhen CHI. Interface design and properties of core-shell structure cathode materials[J]. CIESC Journal, 2019, 70(7): 2426-2438.

宋刘斌, 蒋鹏, 肖忠良, 周乘风, 黎安娴, 池振振. 核壳结构正极材料界面设计与性能研究[J]. 化工学报, 2019, 70(7): 2426-2438.

Figures/Tables 38

References 82

1	FergusJ W. Recent developments in cathode materials for lithium ion batteries[J].Journal of Power Sources, 2010, 195(4): 939-954.
2	WhittinghamM S. Lithium batteries and cathode materials[J]. Chemical Reviews, 2004, 104(10): 4271-4302.
3	LeeJ, UrbanA, LiX, et al. Unlocking the potential of cation-disordered oxides for rechargeable lithium batteries[J]. Science, 2014, 343(6170): 519-522.
4	GoodenoughJ B, KimY. Challenges for rechargeable Li battery[J]. Chemistry of Materials, 2009, 22(3): 587-603.
5	ParkJ K. Principles and Applications of Lithium Secondary Batteries[M]. New York: John Wiley & Sons, 2012: 12-78．
6	AifantisK E, HackneyS A, KumarR V. High Energy Density Lithium Batteries: Materials, Engineering, Applications[M]. New York: John Wiley & Sons, 2010: 7-145．
7	PistoiaG. Lithium-Ion Batteries: Advances and Applications[M]. New South Wales: Newnes, 2013:34-214．
8	YuanJ, LiuX, ZhangH. Lithium-Ion Batteries: Advanced Materials and Technologies[M].Boca Raton: CRC Press, 2011:11-145．
9	YoonS J, ParkK J, LimB B, et al. Improved performances of LiNi_0.65Co_0.08Mn_0.27O₂ cathode material with full concentration gradient for Li-ion batteries[J]. Journal of the Electrochemical Society, 2015, 162 (2): A3059-A3063.
10	JiangL,YuanX, LiangJ, et al. Nanostructured core-shell electrode materials for electrochemical capacitors[J]. Power Sources, 2016, 9(331): 408-425.
11	LiaoJ Y, OhS M, ManthiramA. Core/double-shell type gradient Ni-rich LiNi_0.76Co_0.10Mn_0.14O₂ with high capacity and long cycle life for lithium-ion batteries[J]. ACS Applied Materials & Interfaces, 2016, 8(37): 24543-24549.
12	LuoW, ZhouF, ZhaoX, et al. Synthesis, characterization, and thermal stability of LiNi_1/3Mn_1/3Co_1/3-_zMg_zO₂,LiNi_1/3-_zMn_1/3Co_1/3Mg_zO₂, and LiNi_1/3Mn_1/3-_zCO_1/3Mg_zO₂[J]. Chemistry of Materials, 2009, 22(3): 1164-1172.
13	LuoW, LiX, DahnJ R. Synthesis, characterization, and thermal stability of Li[Ni_1/3Mn_1/3Co_1/3-_z(MnMg)_z_/2]O₂[J]. Chemistry of Materials, 2010, 22(17): 5065-5073.
14	SongH G, KimJ Y, KimK T, et al. Enhanced electrochemical properties of Li(Ni_0.4Co_0.3Mn_0.3)O₂ cathode by surface modification using Li₃PO₄-based materials[J]. Power Sources, 2011, 196(16): 6847-6855.
15	PuX, YuC. Enhanced overcharge performance of nano-LiCoO₂ by novel Li₃VO₄ surface coatings[J]. Nanoscale, 2012, 4(21): 6743-6747.
16	LiQ, DangR B, ChenM M, et al. Synthesis method for long cycle life lithium-ion cathode material: nickel-rich core-shell LiNi_0.8Co_0.1Mn_0.1O₂[J]. ACS Applied Materials & Interfaces, 2018, 10(21): 17850-17860.
17	MyungS T, NohH J, YoonS J, et al. Progress in high-capacity core-shell cathode materials for rechargeable lithium batteries[J]. The Journal of Physical Chemistry Letters, 2014, 5(4): 671-679.
18	ZhangJ C, YangZ Z,GaoR, et al. Suppressing the structure deterioration of Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ through atom-scale interfacial integration of self-forming hierarchical spinel layer with Ni gradient concentration[J]. ACS Appl. Mater. Interfaces, 2017, 9(35): 29794–29803.
19	LeeY, KimH, YimT, et al. Compositional core-shell design by nickel leaching on the surface of Ni-rich cathode materials for advanced high-energy and safe rechargeable batteries[J]. Journal of Power Sources, 2018, 8(400): 87-95.
20	LiuS, FangH, DaiE, et al. Effect of carbon content on properties of LiMn_0.8Fe_0.19Mg_0.01PO₄/C composite cathode for lithium ion batteries[J]. Electrochim Acta, 2014, 10(116): 97-102.
21	刘兴亮, 杨茂萍, 汪伟伟. 分级过程对LiFePO₄/C电池性能的影响[J]. 电化学, 2017, 23(6): 661-666.
	LiuX L, YangM P, WangW W. Effect of fractionation process on performance of LiFePO₄/C battery[J]. Electrochemistry, 2017, 23(6): 661-666.
22	李宏亮, 毛丽萍, 李世友. 功率LiNi_0.5Mn_1.5O₂正极材料的研究进展[J]. 电源技术, 2018, 42(5): 728-739.
	LiH L, MaoL P, LiS Y. Research progress in power LiNi_0.5Mn_1.5O₂ cathode materials[J]. Power Supply Technology,2018, 42(5): 728-739.
23	常海霞, 周移, 卢静. Co₃O₄-Sn复合材料对锂离子电池性能的影响[J].材料导报, 2018, 32(S2): 17-34.
	ChangH X, ZhouY, LuJ. Effect of Co₃O₄-Sn composite on the performance of lithium ion batteries[J]. Materials Review, 2018, 32(S2): 17-34.
24	YuanW, ZhangH Z, LiuQ, et al. Surface modification of Li(Li_0.17Ni_0.2Co_0.05Mn_0.58)O₂ with CeO₂ as cathode material for Li-ion batteries[J]. Electrochim Acta, 2014, 4(135): 199-207.
25	JingW, WeiQ L, BiheW, et al. CuO modified LiNi_0.5Mn_1.5O₄ cathode materials for lithium ion batteries[J]. Scientia Sinica Chimica, 2014, 8(44):1332-1339.
26	HuangX, QiaoQ, SunY, et al. Preparation and electrochemical characterization of Li(Li_0.17Ni_0.2Co_0.05Mn_0.58)O₂ coated with LiAlO₂[J]. J. Solid State Electrochem, 2014, 19(3): 805-812.
27	LiL, ChenZ, SongL, et al. Characterization and electrochemical performance of lithium-active titanium dioxide inlaid LiNi_0.5Co_0.2Mn_0.3O₂ material prepared by lithium residue-assisted method[J]. J. Alloy Compd., 2015, 25(638):77-82.
28	WangF, ChangZ, WangX, et al. Composites of porous Co₃O₄ grown on Li₂MnO₃ microspheres as cathode materials for lithium ion batteries[J]. J. Mater. Chem. A, 2015, 3 (9):4840-4845.
29	YangF L, ZhangW, ChiZ X, et al. Controlled formation of core-shell structures with uniform AlPO₄ nanoshells[J]. Chem. Commun., 2015, 51(14): 2943-2945.
30	许鑫鸿, 郭东磊, 汤宏伟. 镍锰前驱体表面包覆Co₃(PO₄)₂对LiNi₀.₅Mn₁.₅O₄的电性能影响[C]//河南省化学会. 河南省化学会2014年学术年会论文摘要集. 郑州: 河南省化学会,2014.
	XuX H, GuoD L, TangH W. Effect of Co₃(PO₄)₂ on the electrical properties of nickel manganese precursor on LiNi₀.₅Mn₁.₅O₄[C]// Henan Chemical Society. Summary of the 2014 Annual Meeting of Henan Chemical Society. Zhengzhou: Henan Chemical Society, 2014.
31	WangF, XiaoS, LiM, et al. A nanocomposite of Li₂MnO₃coated by FePO₄ as cathode material for lithium ion batteries[J]. J. Power Sources, 2015, 1(287): 416-421.
32	SunY K. High-energy cathode material for long-life and safe lithium batteries[J]. Nature Mater., 2009, 8(4): 320.
33	LeeK S, MyungS T, SunY K. Synthesis and electrochemical performances of core-shell structured Li[(Ni_1/3Co_1/3Mn_1/3)_0.8(Ni_1/2Mn_1/2)_0.2]O₂ cathode material for lithium ion batteries[J]. J. Power Sources, 2010,18(195): 6043-6048.
34	YooG W, JangB C, SonJ T. Novel design of core shell structure by NCA modification on NCM cathode material to enhance capacity and cycle life for lithium secondary battery[J]. Ceram. Int., 2015, 1(41): 1913-1916.
35	SunY K, KimD H, JungH G, et al. High-voltage performance of concentration-gradient Li[Ni_0.67Co_0.15Mn_0.18]O₂ cathode material for lithium-ion batteries[J]. Electrochimica Acta, 2010, 28(55): 8621-8627.
36	史华. 高镍组分的核壳结构层状锂离子电池正极材料[D]. 天津: 天津理工大学, 2014.
	ShiH. High-nickel component core-shell structure layered lithium ion battery cathode material[D]. Tianjin: Tianjin University of Technology, 2014.
37	WenW, ChenS, FuY, et al. A core-shell structure spinel cathode material with a concentration-gradient shell for high performance lithium-ion batteries[J]. J. Power Sources, 2015, 10(274):219-228.
38	HouP, ZhangH , ZiZ, et al. Core–shell and concentration-gradient cathodes prepared via co-precipitation reaction for advanced lithium-ion batteries[J]. J. Mater. Chem. A, 2017, 5(9): 4254-4279.
39	SunY K, ChenZ H, NohH J, et al. Nanostructured high-energy cathode materials for advanced lithium batteries[J]. Nature Materials, 2012, 11(11): 942-947.
40	黄金龙. 新型镍基复合锂离子电池正极材料的合成研究[D].长沙: 中南大学, 2013.
	HuangJ L. Synthesis of a new nickel-based composite lithium ion battery cathode material[D]. Changsha: Central South University, 2013.
41	LiangL W, HuG R, CaoY B, et al. Synthesis and characterization of full concentration-gradient LiNi_0.7Co_0.1Mn_0.2O₂ cathode material for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2015,25(635): 92-100.
42	NieW B, XiaoQ C, WangJ L, et al. Preparation of Li_1.2Mn_0.54Co_0.13Ni_0.13O₂@V₂O₅ core-shell composite and its electrochemical properties[J]. J. Inorg. Mater., 2014, 3(29): 257-263.
43	WuF,WangZ, SuY F, et al. Synthesis and characterization of hollow spherical cathode Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ assembled with nanostructured particles via homogeneous precipitation-hydrothermal synthesis[J]. J. Power Sources, 2014, 10(267): 337-346.
44	DuK, HuangJ, CaoY, et al. Study of effects on LiNi_0.8Co_0.15Al_0.05O₂ cathode by LiNi_1/3Co_1/3Mn_1/3O₂ coating for lithium ion batteries[J]. J. Alloy Compd., 2013, 574: 377-382.
45	YangX K, WangX Y, WeiQ L, et al. Synthesis and characterization of a Li-rich layered cathode material Li_1.15[(Ni_1/3Co_1/3Mn_1/3)_0.5(Ni_1/4Mn_3/4)_0.5]_0.85O₂ with spherical core shell structure [J]. J. Mater. Chem., 2012, 8(22): 19666-19672.
46	JuJ H, RyuK S. Synthesis and electrochemical performance of Li(Ni_0.8Co_0.15Al_0.05)_0.8(Ni_0.5Mn_0.5)_0.2O₂ with core-shell structure as cathode material for Li-ion batteries[J]. J. Alloy Compd., 2011, 509(30): 7985-7992.
47	周恩娄. 锂离子电池层状正极材料的表面包覆研究[D]. 天津: 天津理工大学, 2013.
	ZhouE L. Surface coating of layered cathode materials for lithium ion batteries[D]. Tianjin: Tianjin University of Technology, 2013.
48	ShiJ L, QiR, ZhangX D, et al. A high thermal and air stability cathode material with concentration-gradient buffer for Li-ion batteries[J]. ACS Appl. Mater. Interfaces, 2017, 9(49): 42829–42835.
49	YangX, WangX, HuL, et al. Layered Li[Ni_0.5Co_0.2Mn_0.3]O₂-Li₂MnO₃ core-shell structured cathode material with excellent stability[J]. J. Power Sources, 2013, 11(242): 589-596.
50	ShiJ Y, YiC W, KimK. Improved electrochemical performance of AlPO₄-coated LiMn_1.5Ni_0.5O₄ electrode for lithium-ion batteries[J]. Journal of Power Sources, 2010, 195(19): 6860-6866.
51	HuG R, QiX Y, HuK H, et al. A facile cathode design with a LiNi_0.6Co_0.2Mn_0.2O₂ core and an AlF₃-activated Li_1.2Ni_0.2Mn_0.6O₂ shell for Li-ion batteries[J]. Electrochim Acta, 2018, 3(265): 391-399.
52	LiuY, ZhangM, XiaY, et al. One-step hydrothermal method synthesis of core-shell LiNi_0.5Mn_1.5O₄ spinel cathodes for Li-ion batteries[J]. J. Power Sources, 2014, 5(256): 66-71.
53	LuZ P, LiuY, LuX J, et al. An active core-shell nanoscale design for high voltage cathode of lithium storage devices[J]. J. Power Sources, 2017, 6(360): 409-418.
54	LiangX, GaoG H, WuG M. Synthesis and characterization of hollow and core-shell structured V₂O₅ microspheres and their electrochemical properties[J]. Journal of Alloys and Compounds 2017, 6(725): 923-934
55	YuJ, HanZ, HuX, et al. Solid-state synthesis of LiCoO₂/LiCo_0.99Ti_0.01O₂ composite as cathode material for lithium ion batteries[J].J. Power Sources, 2013, 9(225): 34-39.
56	HanZ H, YuJ P, ZhanH, et al. Sb₂O₃-modified LiNi_1/3Co_1/3Mn_1/3O₂ material with enhanced thermal safety and electrochemical property[J]. J. Power Sources, 2014, 11(254): 106-111.
57	ZouY H, YangX F, LuC X, et al. Multi-shelled Ni-rich Li(Ni_xCo_yMn_z)O₂ hollow fibers with low cation mixing as high-performance cathode materials for Li-ion batteries [J]. Advanced Science, 2017, 4(10):1600262.
58	ChongS K, WuY F, ChenY Z, et al. A strategy of constructing spherical core-shell structure of Li_1.2Ni_0.2Mn_0.6O₂@Li_1.2Ni_0.4Mn_0.4O₂ cathode material for high performance lithium-ion batteries[J]. Journal of Power Sources, 2017, 4(356):153-162.
59	LeeY, KimH, YimT, et al. Compositional core-shell design by nickel leaching on the surface of Ni-rich cathode materials for advanced high-energy and safe rechargeable batteries[J]. Journal of Power Sources, 2018, 8(400): 87-95.
60	QiuZ P, ZhangY J, HuangX S, et al. Beneficial effect of incorporating Ni-rich oxide and layered over-lithiated oxide into high-energy-density cathode materials for lithium-ion batteries[J]. J. Power Sources, 2014, 8(400):341-349.
61	GaoS L,YangT H,ZhangH Z, et al. Improved electrochemical performance and thermal stability of Li-rich material Li_1.2(Ni_0.25Co_0.25Mn_0.5)_0.8O₂ through a novel core-shelled structure design[J]. Journal of Alloys and Compounds, 2017, 9(729): 695-702.
62	ShiH, WangX Q, HouP Y, et al. Core–shell structured Li(Ni_0.8Mn_0.1Co_0.1)_0.7(Ni_0.45Co_0.1Mn_0.45)_0.3O₂ cathode material for high-energy lithium ion batteries [J]. Journal of Alloys and Compounds, 2014,10(587): 710-716.
63	周新文,代忠旭,张克立.锂离子电池正极材料的热稳定性[J]. 武汉大学学报(理学版), 2010, 56(3): 258-262.
	ZhouX W, DaiZ X, ZhangK L. Thermal stability of cathode materials for lithium ion batteries[J]. Journal of Wuhan University(Natural Science Edition), 2010, 56(3): 258-262.
64	阮艳莉,唐致远. LiFePO₄的合成及其热分析动力学[J]. 物理化学学报, 2008, 24(5): 873-879.
	RuanY L, TangZ Y. Synthesis and thermal analysis kinetics of LiFePO₄[J]. Acta Phys. Sinica, 2008, 24(5): 873-879.
65	ZhangN, LiJ, LiH Y, et al. Structural, electrochemical, and thermal properties of nickel-rich LiNi_xMn_yCo_zO₂ materials[J]. Chem. Mater., 2018, 30(24): 8852–8860.
66	ParkK J, ChoiM J, MagliaF, et al. High-capacity concentration gradient LiNi_0.865Co_0.120Al_0.015O₂ cathode for lithium-ion batteries[J].Adv. Energy Mater., 2018, 8(19): 1703612.
67	SunY K, KimD H, YoonC S, et al. A novel cathode material with a concentration-gradient for high-energy and safe lithium-ion batteries[J]. Adv. Funct. Mater., 2010, 1(20): 485–491.
68	EddahechA, BriatO, VinassaJ M. Thermal characterization of a high-power lithium-ion battery: potentiometric and calorimetric measurement of entropy changes[J]. Energy, 2013,9(61): 432-439.
69	KrauseL J, JensenL D, DahnJ R. Measurement of parasitic reactions in Li ion cells by electrochemical calorimetry[J]. Journal of the Electrochemical Society, 2012, 159 (7): 937-943.
70	VallverduG, MinvielleM, AndreuN, et al. First principle study of the surface reactivity of layered lithium oxides LiMO₂(M=Ni, Mn, Co)[J]. Surface Science, 2016, 1(649): 46-55.
71	BalasundaramM, RamarV, YapC, et al. Heat loss distribution: Impedance and thermal loss analyses in LiFePO₄/graphite 18650 electrochemical cell[J]. Journal of Power Sources, 2016, 8(328): 413-421.
72	宋刘斌, 刘姣, 肖忠良, 等. Li₂ZrO₃包覆LiNi_0.8Co_0.1Mn_0.1O₂的复合材料及其电化学性能[J]. 化工学报, 2017, 68(11): 4390-4397.
	SongL B, LiuJ, XiaoZ L, et al. Composite materials of Li₂ZrO₃ coated LiNi_0.8Co_0.1Mn_0.1O₂ and its electrochemical properties[J]. CIESC Journal, 2017, 68(11): 4390-4397.
73	XiaoZ L,ZhouQ Q, SongL B, et al. Assessment of thermo-electrochemical performance on cathode materials for lithium ion cells[J]. International Journal of Electrochemical Science, 2016, 3(11): 2825-2834.
74	BardA J, FaulknerL R. Electrochemical Methods: Fundamentals and Applications[M]. New York: Wiley, 1980.
75	LiJ W, LiY, GuoY N, et al. A facile method to enhance electrochemical performance of high nickel cathode material LiNi_0.8Co_0.1Mn_0.1O₂via Ti doping [J]. Journal of Materials Science: Materials in Electronics, 2018, 29(13): 10702–10708.
76	ZhangZ, ZhouP F, MengH J, et al. Amorphous Zr(OH)₄ coated LiNi_0.915Co_0.075Al_0.01O₂ cathode material with enhanced electrochemical performance for lithium ion batteries[J]. Journal of Energy Chemistry, 2017,5(26): 481–487.
77	XuC L, XiangW, WuZ G, et al. Constructing a protective pillaring layer by incorporating gradient Mn⁴⁺ to stabilize the surface/interfacial structure of LiNi_0.815Co_0.15Al_0.035O₂ cathode[J]. ACS Appl. Mater. Interfaces, 2018, 1(10):27821-27830.
78	KimU H, KimJ H , HwangJ Y, et al. Compositionally and structurally redesigned high-energy Ni-rich layered cathode for next-generation lithium batteries[J].Journal of Materials Today, 2018, 3(12): 26-36.
79	MinK, SeoS W, SongY Y, et al. A first-principles study of the preventive effects of Al and Mg doping on the degradation in LiNi_0.8Co_0.1Mn_0.1O₂ cathode materials[J]. Physical Chemistry Chemical Physics, 2017, 11(19): 1762-1769.
80	YuH, QianY, OtaniM, et al. Study of the lithium/nickel Ions exchange in the layered LiNi_0.42Mn_0.42Co_0.16O₂ cathode material for lithium ion batteries: experimental and first-principles calculations[J].Energy & Environmental Science, 2014, 7(3): 1068-1078.
81	LongoR C, LiangC P, KongF, et al. Core-shell nanocomposites for improving the structural stability of Li-rich layered oxide cathode materials for Li-ion batteries[J]. ACS Appl. Mater. Interfaces, 2018, 10(22): 19226-19234.
82	WuB,LuW. Mechanical modeling of particles with active core-shell structures for lithium-ion battery electrodes[J]. J. Phys. Chem. C, 2017, 121(35): 19022-19030.

[1]	Xin YANG, Wen WANG, Kai XU, Fanhua MA. Simulation analysis of temperature characteristics of the high-pressure hydrogen refueling process [J]. CIESC Journal, 2023, 74(S1): 280-286.
[2]	Minghui CHANG, Lin WANG, Jiajia YUAN, Yifei CAO. Study on the cycle performance of salt solution-storage-based heat pump [J]. CIESC Journal, 2023, 74(S1): 329-337.
[3]	Cheng CHENG, Zhongdi DUAN, Haoran SUN, Haitao HU, Hongxiang XUE. Lattice Boltzmann simulation of surface microstructure effect on crystallization fouling [J]. CIESC Journal, 2023, 74(S1): 74-86.
[4]	Jianbo HU, Hongchao LIU, Qi HU, Meiying HUANG, Xianyu SONG, Shuangliang ZHAO. Molecular dynamics simulation insight into translocation behavior of organic cage across the cellular membrane [J]. CIESC Journal, 2023, 74(9): 3756-3765.
[5]	Manzheng ZHANG, Meng XIAO, Peiwei YAN, Zheng MIAO, Jinliang XU, Xianbing JI. Working fluid screening and thermodynamic optimization of hazardous waste incineration coupled organic Rankine cycle system [J]. CIESC Journal, 2023, 74(8): 3502-3512.
[6]	Linzheng WANG, Yubing LU, Ruizhi ZHANG, Yonghao LUO. Analysis on thermal oxidation characteristics of VOCs based on molecular dynamics simulation [J]. CIESC Journal, 2023, 74(8): 3242-3255.
[7]	Mengmeng ZHANG, Dong YAN, Yongfeng SHEN, Wencui LI. Effect of electrolyte types on the storage behaviors of anions and cations for dual-ion batteries [J]. CIESC Journal, 2023, 74(7): 3116-3126.
[8]	Qiyu ZHANG, Lijun GAO, Yuhang SU, Xiaobo MA, Yicheng WANG, Yating ZHANG, Chao HU. Recent advances in carbon-based catalysts for electrochemical reduction of carbon dioxide [J]. CIESC Journal, 2023, 74(7): 2753-2772.
[9]	Jipeng ZHOU, Wenjun HE, Tao LI. Reaction engineering calculation of deactivation kinetics for ethylene catalytic oxidation over irregular-shaped catalysts [J]. CIESC Journal, 2023, 74(6): 2416-2426.
[10]	Xueyan WEI, Yong QIAN. Experimental study on the low to medium temperature oxidation characteristics and kinetics of micro-size iron powder [J]. CIESC Journal, 2023, 74(6): 2624-2638.
[11]	Guangyu WANG, Kai ZHANG, Kaihua ZHANG, Dongke ZHANG. Heat and mass transfer and energy consumption for microwave drying of coal slime [J]. CIESC Journal, 2023, 74(6): 2382-2390.
[12]	Quanbi ZHANG, Yijin YANG, Xujing GUO. Catalytic degradation of dissolved organic matter in rifampicin pharmaceutical wastewater by Fenton oxidation process [J]. CIESC Journal, 2023, 74(5): 2217-2227.
[13]	Simin YI, Yali MA, Weiqiang LIU, Jinshuai ZHANG, Yan YUE, Qiang ZHENG, Songyan JIA, Xue LI. Study on ammonia evaporation and hydration kinetics of microcrystalline magnesite [J]. CIESC Journal, 2023, 74(4): 1578-1586.
[14]	Jin YU, Binbin YU, Xinsheng JIANG. Study on quantification methodology and analysis of chemical effects of combustion control based on fictitious species [J]. CIESC Journal, 2023, 74(3): 1303-1312.
[15]	Qingyun YANG, Qingsong LI, Zeming CHEN, Jing DENG, Yuying LI, Fan YANG, Guoyuan CHEN, Guoxin LI. Degradation of methylparaben by UV/PMS, UV/PDS and UV/SPC process [J]. CIESC Journal, 2023, 74(3): 1322-1331.