CIESC Journal ›› 2023, Vol. 74 ›› Issue (4): 1578-1586.DOI: 10.11949/0438-1157.20221587
• Catalysis, kinetics and reactors • Previous Articles Next Articles
Simin YI1(), Yali MA1,2,3,4, Weiqiang LIU1, Jinshuai ZHANG1, Yan YUE1, Qiang ZHENG1,2,3,4, Songyan JIA1,2,3,4, Xue LI1,2,3,4(
)
Received:
2022-12-09
Revised:
2023-02-26
Online:
2023-06-02
Published:
2023-04-05
Contact:
Xue LI
衣思敏1(), 马亚丽1,2,3,4, 刘伟强1, 张金帅1, 岳岩1, 郑强1,2,3,4, 贾松岩1,2,3,4, 李雪1,2,3,4(
)
通讯作者:
李雪
作者简介:
衣思敏(1998—),女,硕士研究生,y06100319@163.com
基金资助:
CLC Number:
Simin YI, Yali MA, Weiqiang LIU, Jinshuai ZHANG, Yan YUE, Qiang ZHENG, Songyan JIA, Xue LI. Study on ammonia evaporation and hydration kinetics of microcrystalline magnesite[J]. CIESC Journal, 2023, 74(4): 1578-1586.
衣思敏, 马亚丽, 刘伟强, 张金帅, 岳岩, 郑强, 贾松岩, 李雪. 微晶菱镁矿蒸氨及水化动力学研究[J]. 化工学报, 2023, 74(4): 1578-1586.
成分 | 微晶MgO主要成分含量/% | 轻烧MgO主要成分含量/% |
---|---|---|
MgO | 96.15 | 75.83 |
CaO | 1.55 | 7.21 |
SiO2 | 0.24 | 10.25 |
Fe2O3 | 0.05 | 2.04 |
Table 1 Main components of different MgO
成分 | 微晶MgO主要成分含量/% | 轻烧MgO主要成分含量/% |
---|---|---|
MgO | 96.15 | 75.83 |
CaO | 1.55 | 7.21 |
SiO2 | 0.24 | 10.25 |
Fe2O3 | 0.05 | 2.04 |
样品编号 | 以微晶MgO为原料 活性MgO含量/% | 以轻烧MgO为原料 活性MgO含量/% |
---|---|---|
1 | 75.15 | 56.14 |
2 | 76.52 | 56.35 |
3 | 76.47 | 54.77 |
平均值 | 76.05 | 55.75 |
Table 2 Active MgO content in hydrated MgO obtained from different raw materials
样品编号 | 以微晶MgO为原料 活性MgO含量/% | 以轻烧MgO为原料 活性MgO含量/% |
---|---|---|
1 | 75.15 | 56.14 |
2 | 76.52 | 56.35 |
3 | 76.47 | 54.77 |
平均值 | 76.05 | 55.75 |
1 | 李志勋, 冯润棠, 田晓利,等. 水化方式对微晶菱镁矿制备高纯氢氧化镁的影响[J]. 耐火材料, 2018, 52(3):213-216. |
Li Z X, Feng R T, Tian X L, et al. Effect of hydration process on preparation of high purity magnesium hydroxide from microcrystalline magnesite[J]. Refractories, 2018, 52(3):213-216. | |
2 | 田晓利, 李志勋, 冯润棠,等. 煅烧制度对微晶菱镁矿制备高致密度烧结镁砂性能的影响[J]. 耐火材料, 2022, 56(5):400-406. |
Tian X L, Li Z X, Feng R T, et al. Effect of calcination schedule on properties of high density sintered magnesia prepared from microcrystalline magnesite[J]. Refractories, 2022, 56(5):400-406. | |
3 | 王刚, 夏志豪, 李希艳,等. 不同气氛下流化床菱镁矿轻烧产物特性研究[J]. 化工学报, 2022, 73(8):3699-3707. |
Wang G, Xia Z H, Li X Y, et al. Effect of atmosphere on active performance of light-burned magnesium oxides from calcined magnesite in fluidized bed[J]. CIESC Journal, 2022, 73(8):3699-3707. | |
4 | 杨翠杰, 赵华, 徐恺,等. (NH4)2SO4浸取轻烧粉的控制过程[J]. 矿产综合利用, 2016(5):66-68, 42. |
Yang C J, Zhao H, Xu K, et al. Study on controlling process of (NH4)2SO4 leaching of light-calcined powder[J]. Multipurpose Utilization of Mineral Resources, 2016(5):66-68, 42. | |
5 | 巴浩静, 白丽梅, 赵文青,等. 轻烧镁制备及深加工研究进展[J]. 矿产保护与利用, 2017(1):84-89. |
Ba H J, Bai L M, Zhao W Q, et al. Review on preparation and processing of caustic calcined magnesit[J]. Conservation and Utilization of Mineral Resources, 2017(1):84-89. | |
6 | 范天博, 姜宇, 陈思,等. TRIZ理论在轻烧粉氨气法制备氢氧化镁过程中的应用研究[J]. 无机盐工业, 2019, 51(5):23-27, 44. |
Fan T B, Jiang Y, Chen S, et al. Application of TRIZ theory in preparation of magnesium hydroxide by light burning ammonia[J]. Inorganic Chemicals Industry, 2019, 51(5): 23-27, 44. | |
7 | 吴易梅, 孙玉柱, 路贵民,等. 结晶-水热法制备六角片状氢氧化镁[J]. 高校化学工程学报, 2019, 33(2):425-434. |
Wu Y M, Sun Y Z, Lu G M, et al. Preparation of hexagonal sheet magnesium hydroxide flake by a crystallization-hydrothermal method[J]. Journal of Chemical Engineering of Chinese Universities, 2019, 33(2):425-434. | |
8 | 赵丽, 王立艳, 肖姗姗,等.氢氧化镁阻燃剂制备研究进展[J]. 无机盐工业, 2018, 50(3):16-19. |
Zhao L, Wang L Y, Xiao S S, et al. Research progress in preparation of magnesium hydroxide flame retardant[J]. Inorganic Chemicals Industry, 2018, 50(3):16-19. | |
9 | 李雪, 程沛, 侯睿,等. 轻烧粉氨气法制备氢氧化镁阻燃剂的研究[J]. 无机盐工业, 2016, 48(11):21-24. |
Li X, Cheng P, Hou R, et al. Preparation of Mg(OH)2 with caustic calcined magnesia through ammonium circulation[J]. Inorganic Chemicals Industry, 2016, 48(11):21-24. | |
10 | 姚建平, 范天博, 王健,等. 氨状态对氨法制备氢氧化镁颗粒性质的影响[J]. 化工学报, 2012, 63(1):314-319. |
Yao J P, Fan T B, Wang J, et al. Influence of ammonia state on particle characterization of magnesium hydroxide prepared via ammonia method[J]. CIESC Journal, 2012, 63(1):314-319. | |
11 | 孙晓君, 丁珂, 仇龙,等. 以轻烧粉制备六方片状氢氧化镁[J]. 硅酸盐学报, 2019, 47(4):538-544. |
Sun X J, Ding K, Qiu L, et al. Preparation of hexagonal-sheet magnesium hydroxide by surfactant free method[J]. Journal of the Chinese Ceramic Society, 2019, 47(4):538-544. | |
12 | 吴丹, 张琦, 王玉琪,等. 轻烧粉在氯化铵体系中的萃取实验研究[J]. 应用化工, 2021, 50(2):415-418. |
Wu D, Zhang Q, Wang Y Q, et al. Experimental study on extraction of light burning powder in ammonium chloride system[J]. Applied Chemical Industry, 2021, 50(2):415-418. | |
13 | 丁珂, 孙晓君, 李会杰,等. 氧化镁蒸氨反应的动力学和机理研究[J]. 无机盐工业, 2019, 51(11):31-35. |
Ding K, Sun X J, Li H J, et al. Study on kinetics and mechanism of ammonia evaporation reaction of magnesium oxide[J]. Inorganic Chemicals Industry, 2019, 51(11):31-35. | |
14 | 朱云, 王善忠, 胡建锋. 水热法制备阻燃剂氢氧化镁[J]. 有色金属, 2007(3): 30-32, 36. |
Zhu Y, Wang S Z, Hu J F. Hydrothermal preparation of flame retardant Mg(OH)2 [J]. Nonferrous Metals, 2007(3): 30-32, 36. | |
15 | 梁晓正, 马玉新, 李鸣铎,等. 外力环境对氧化镁水化产物性能的影响[J]. 有色金属工程, 2020, 10(6):1-8. |
Liang X Z, Ma Y X, Li M D, et al. Effect of external force on properties of products prepared from hydration of MgO[J]. Nonferrous Metals Engineering, 2020, 10(6): 1-8. | |
16 | 白丽梅, 邢智博, 张俊,等. 氧化镁常压水合法制备氢氧化镁的过程分析[J]. 非金属矿, 2017, 40(4):1-3. |
Bai L M, Xing Z B, Zhang J, et al. The process analysis of hydrating magnesium oxide to prepare magnesium hydroxide under the ordinary pressure[J]. Non-Metallic Mines, 2017, 40(4):1-3. | |
17 | 黄娜娜, 李会杰, 仇龙,等. 菱镁矿氨法制备氢氧化镁及活性氧化镁水化动力学研究[J]. 盐科学与化工, 2020, 49(2):29-32. |
Huang N N, Li H J, Qiu L, et al. Study on hydration kinetics of magnesium hydroxide and active magnesium oxide prepared by magnesite ammonia process[J]. Journal of Salt Science and Chemical Industry, 2020, 49(2):29-32. | |
18 | 刘欣伟, 冯雅丽, 李浩然,等. 菱镁矿制备轻烧氧化镁及其水化动力学研究[J]. 中南大学学报(自然科学版), 2011, 42(12):3912-3917. |
Liu X W, Feng Y L, Li H R, et al. Preparation of light-burned magnesia from magnesite and its hydration kinetics[J]. Journal of Central South University (Science and Technology), 2011, 42(12):3912-3917. | |
19 | 王利莎. 氧化镁水合法制备阻燃级氢氧化镁研究[D]. 天津: 天津科技大学, 2012. |
Wang L S. Research on hydration preparation of fire-retardant level magnesium hydrate from magnesium oxide[D]. Tianjin: Tianjin University of Science & Technology, 2012. | |
20 | 白炳华. 微晶菱镁矿制备高纯轻质氧化镁研究[D]. 西安: 西安建筑科技大学, 2021. |
Bai B H. Research of preparation of high purity light magnesium oxide from microcrystalline magnesite[D]. Xi'an: Xi'an University of Architecture and Technology, 2021. | |
21 | 张诗英. 菱镁粉MgO活性测定方法研究: Cl-测定法[J]. 武汉工业大学学报, 1994, 16(3): 114-117. |
Zhang S Y. The study of determination method in magnisia activity[J]. Journal of Wuhan University of Technology, 1994, 16(3): 114-117. | |
22 | 王素平. 高活性氧化镁的制备与吸附性能的研究[D]. 天津: 天津大学, 2015. |
Wang S P. Study on the synthesis and adsorption properties of high active MgO[D]. Tianjin: Tianjin University, 2015. | |
23 | 孙世清, 谢维章. 用热分析方法研究MgO的活性[J]. 硅酸盐学报, 1986, 14(2): 226-232. |
Sun S Q, Xie W Z. Study on the activity of MgO by thermal analysis[J]. Journal of the Chinese Ceramic Society, 1986, 14(2): 226-232. | |
24 | 李广垠, 李志坚, 徐娜,等. 轻烧氧化镁活性对烧结镁砂性能的影响[J]. 硅酸盐通报, 2018, 37(5):1699-1703. |
Li G Y, Li Z J, Xu N, et al. Effect of light burned magnesia activity on properties of sintered magnesia[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(5):1699-1703. | |
25 | 董金美, 余红发, 张立明. 水合法测定活性MgO含量的试验条件研究[J]. 盐湖研究, 2010, 18(1):38-41. |
Dong J M, Yu H F, Zhang L M. Study on experimental conditions of hydration methods of determining active magnesium oxide content[J]. Journal of Salt Lake Research, 2010, 18(1):38-41. | |
26 | He G X, Zhao Z W, Wang X B, et al. Leaching kinetics of scheelite in hydrochloric acid solution containing hydrogen peroxide as complexing agent[J]. Hydrometallurgy, 2014, 144/145: 140-147. |
27 | 肖永丰, 陈爱国, 张雨薇,等. 粉煤灰提铝硅渣碱溶脱硅反应及其动力学[J]. 硅酸盐通报, 2021, 40(2):542-547. |
Xiao Y F, Chen A G, Zhang Y W, et al. Desilication reaction and kinetics of aluminum-extracting silicon slag in NaOH solution[J]. Bulletin of the Chinese Ceramic Society, 2021,40(2):542-547. | |
28 | Zheng Y J, Chen K K. Leaching kinetics of selenium from selenium-tellurium-rich materials in sodium sulfite solutions[J]. Transactions of Nonferrous Metals Society of China, 2014, 24(2):536-543. |
29 | Amaral L F, Oliveira I R, Salomão R, et al. Temperature and common-ion effect on magnesium oxide (MgO) hydration[J]. Ceramics International, 2010, 36(3):1047-1054. |
30 | Kato Y, Yamashita N, Kobayashi K, et al. Kinetic study of the hydration of magnesium oxide for a chemical heat pump [J]. Applied Thermal Engineering, 1996, 16(11):853-862. |
31 | Birchal V S, Rocha S D F, Mansur M B, et al. A simplified mechanistic analysis of the hydration of magnesia [J]. The Canadian Journal of Chemical Engineering, 2001, 79(4):507-511. |
32 | 郭杰, 刘百宽, 田晓利,等. 微晶菱镁矿制备高纯氢氧化镁水化工艺研究[J]. 非金属矿, 2019, 42(5):45-48. |
Guo J, Liu B K, Tian X L, et al. Study on hydration process of preparing high purity magnesium hydroxide from microcrystalline magnesite[J]. Non-Metallic Mines, 2019, 42(5):45-48. | |
33 | 孔会民, 邹来禧, 刘远,等. 以轻烧氧化镁制备六角片状氢氧化镁的研究[J]. 无机盐工业, 2022, 54(1):39-44. |
Kong H M, Zou L X, Liu Y, et al. Study on preparation of hexagonal plates of magnesium hydroxide by light-burned magnesium oxide[J]. Inorganic Chemicals Industry, 2022, 54(1):39-44. | |
34 | 翟学良, 杨永社. 活性氧化镁水化动力学研究[J]. 无机盐工业, 2000, 32(4): 16-18. |
Zhai X L, Yang Y S. Study of hydrolization kinetics of activated MgO[J]. Inorganic Chemicals Industry, 2000, 32(4): 16-18. |
[1] | Cheng CHENG, Zhongdi DUAN, Haoran SUN, Haitao HU, Hongxiang XUE. Lattice Boltzmann simulation of surface microstructure effect on crystallization fouling [J]. CIESC Journal, 2023, 74(S1): 74-86. |
[2] | Lei WU, Jiao LIU, Changcong LI, Jun ZHOU, Gan YE, Tiantian LIU, Ruiyu ZHU, Qiuli ZHANG, Yonghui SONG. Catalytic microwave pyrolysis of low-rank pulverized coal for preparation of high value-added modified bluecoke powders containing carbon nanotubes [J]. CIESC Journal, 2023, 74(9): 3956-3967. |
[3] | Linzheng WANG, Yubing LU, Ruizhi ZHANG, Yonghao LUO. Analysis on thermal oxidation characteristics of VOCs based on molecular dynamics simulation [J]. CIESC Journal, 2023, 74(8): 3242-3255. |
[4] | Mengmeng ZHANG, Dong YAN, Yongfeng SHEN, Wencui LI. Effect of electrolyte types on the storage behaviors of anions and cations for dual-ion batteries [J]. CIESC Journal, 2023, 74(7): 3116-3126. |
[5] | Zhenghao YANG, Zhen HE, Yulong CHANG, Ziheng JIN, Xia JIANG. Research progress in downer fluidized bed reactor for biomass fast pyrolysis [J]. CIESC Journal, 2023, 74(6): 2249-2263. |
[6] | Guangyu WANG, Kai ZHANG, Kaihua ZHANG, Dongke ZHANG. Heat and mass transfer and energy consumption for microwave drying of coal slime [J]. CIESC Journal, 2023, 74(6): 2382-2390. |
[7] | Jipeng ZHOU, Wenjun HE, Tao LI. Reaction engineering calculation of deactivation kinetics for ethylene catalytic oxidation over irregular-shaped catalysts [J]. CIESC Journal, 2023, 74(6): 2416-2426. |
[8] | Quanbi ZHANG, Yijin YANG, Xujing GUO. Catalytic degradation of dissolved organic matter in rifampicin pharmaceutical wastewater by Fenton oxidation process [J]. CIESC Journal, 2023, 74(5): 2217-2227. |
[9] | Jin YU, Binbin YU, Xinsheng JIANG. Study on quantification methodology and analysis of chemical effects of combustion control based on fictitious species [J]. CIESC Journal, 2023, 74(3): 1303-1312. |
[10] | Qingyun YANG, Qingsong LI, Zeming CHEN, Jing DENG, Yuying LI, Fan YANG, Guoyuan CHEN, Guoxin LI. Degradation of methylparaben by UV/PMS, UV/PDS and UV/SPC process [J]. CIESC Journal, 2023, 74(3): 1322-1331. |
[11] | Ruizhe CHEN, Leilei CHENG, Jing GU, Haoran YUAN, Yong CHEN. Research progress in chemical recovery technology of fiber-reinforced polymer composites [J]. CIESC Journal, 2023, 74(3): 981-994. |
[12] | Lingxin ZU, Rongting HU, Xin LI, Yudao CHEN, Guanglin CHEN. Carbon release products and denitrification bioavailability from chemical components of woody biomass [J]. CIESC Journal, 2023, 74(3): 1332-1342. |
[13] | Han HU, Liang YANG, Chunxiao LI, Daoping LIU. Kinetics of methane storage in the natural tobacco leaching filtrate in the hydrate form [J]. CIESC Journal, 2023, 74(3): 1313-1321. |
[14] | Jieyuan ZHENG, Xianwei ZHANG, Jintao WAN, Hong FAN. Synthesis and curing kinetic analysis of eugenol-based siloxane epoxy resin [J]. CIESC Journal, 2023, 74(2): 924-932. |
[15] | Xianxian RAO, Miao DU, Guorong SHAN, Pengju PAN. Effect of different metal salt demulsifiers on vulcanization behavior of isobutylene isoprene rubber [J]. CIESC Journal, 2023, 74(2): 756-765. |
Viewed | ||||||||||||||||||||||||||||||||||||||||||||||||||
Full text 113
|
|
|||||||||||||||||||||||||||||||||||||||||||||||||
Abstract 210
|
|
|||||||||||||||||||||||||||||||||||||||||||||||||