Research progress in photocatalytic reduction of CO2 with iron-based catalysts

doi:10.11949/0438-1157.20210617

Abstract

Abstract:

Using renewable clean energy-solar energy to convert CO₂ into carbon monoxide, methane, methanol, etc., has attracted more and more attention because of its potential to provide sustainable fuels and solve global warming problems. Iron-based materials have broad application potential in the field of photocatalytic reduction of CO₂ due to their metal/semiconductor properties and unique electronic structure. According to this, various iron-based catalysts with high catalytic activity have been designed to enhance the efficiency of photocatalytic reduction of CO₂. This article reviews recent advances in the field of photocatalytic reduction of carbon dioxide based on iron-based catalysts. The structural characteristics and catalytic activity of iron-based catalysts are described and compared. Finally, the problems to be solved and the future development direction of iron-based catalysts in the field of photocatalytic reduction of CO₂ are summarized and prospected.

Key words: carbon dioxide, reduction, photocatalysis, iron-based catalyst

摘要：

利用可再生清洁能源——太阳能，将CO₂转化为一氧化碳、甲烷、甲醇等，因同时具有提供可持续燃料和解决全球变暖问题的潜力而受到越来越多的关注。铁基材料因具有金属/半导体的特性和独特的电子结构，在光催化还原CO₂领域具有广阔的应用潜力。基于此，各种具有高催化活性的铁基催化剂已经被设计来提高光催化还原CO₂的效率。概述了近年来铁基催化剂在光催化还原二氧化碳中的研究进展，对它们的结构特征和催化活性进行了阐述和比较，最后总结了铁基催化剂在光催化还原CO₂领域中待解决的问题，并展望了未来发展的方向。

关键词: 二氧化碳, 还原, 光催化, 铁基催化剂

CLC Number:

TQ 138.1

Yongqiang DANG,Boni LI,Keke LI,Jianlan ZHANG,Xiangyu FENG,Yating ZHANG. Research progress in photocatalytic reduction of CO₂ with iron-based catalysts[J]. CIESC Journal, 2021, 72(10): 5016-5027.

党永强,李博妮,李可可,张建兰,冯香钰,张亚婷. 铁基催化剂光催化还原CO₂研究进展[J]. 化工学报, 2021, 72(10): 5016-5027.

Figures/Tables 12

Fig.1 Schematic illustration of probable mechanism of photocatalytic CO2 conversion over a semiconducting photocatalyst[19]

Fig.2 Transfer paths of photogenerated carriers on different heterojunctions

Fig.3 Schematic description of reductive quenching pathway of metal complexes in photocatalytic conversion of CO2

Table 1 Standard potentials of CO2 reduction to various products in aqueous solutions at 25 ℃， 101.325 kPa and pH 7

Reaction	E^o (vs NHE)/V
CO₂ + 2H⁺ + 2e^- HCOOH	-0.61
CO₂+ 2H⁺ + 2e^- CO + H₂O	-0.53
CO₂ + 4H⁺ + 4e^- ΗCHO + H₂O	-0.48
CO₂ + 6H⁺ + 6e^- CH₃OH + H₂O	-0.38
CO₂ + 8H⁺ + 8e^- CH₄ + 2H₂O	-0.24
2CO₂ + 12H⁺ + 12e^- C₂H₄ + 4H₂O	-0.34
2CO₂ + 12H⁺ + 12e^- C₂H₅OH + 3H₂O	-0.33
2CO₂ + 14H⁺ + 14e^- C₂H₆ + 4H₂O	-0.27

Fig.4 Conversion of CO2 to methanol over time using blank reaction, rGO, InVO4/Fe2O3, InVO4 and rGO/InVO4/Fe2O3 [37]

Fig.5 The structure of Fe-p-TMA, FeTPP-p-TMA and FeTPP-o-OH

Fig.6 Structures of the tris(2-phenylpyridine)iridium, 9-anthrracenecarbonitrile and purpurin

Table 2 Application of iron complex catalyst in photocatalytic reduction of CO2 in recent years

光催化剂	光敏剂	还原剂	溶剂^①	产物	TON	选择性	文献
FeTPP	FeTPP	TEA	DMF	CO	70	—	[50]
Fe-p-TMA	Ir(ppy)₃	TEA	ACN∶H₂O(3∶8)	CH₄	81	81%	[51]
FeTMA	CuInS₂/ZnS QD	—	H₂O	CO	450	99%	[61]
FeTPP-p-TMA	无	BIH	CAN	CO	63	—	[52]
FeTPP-p-TMA	无	TEA	CAN	CO	33	100%	[52]
FeTPP-p-TMA	Ir(ppy)₃	TEA	CAN	CH₄	89	82%	[53]
FeTPP-o-OH	Ir(ppy)₃	TEA	CAN	CO	140	93%	[54]
Fe₃(CO)₁₂	[Ru(bpy)₃]Cl₂	TEOA	NMP∶TEOA(5∶1)	CO	36	—	[55]
Fe(CO)₃bpy	[Ru(bpy)₃]Cl₂	TEOA	NMP∶TEOA(5∶1)	CO	42	—	[55]
（环戊二烯酮）铁-三羰基配合物	Ir PS	TEOA	NMP	CO	596	—	[56]
环戊二烯酮铁配合物	Cu PS	BNAH	NMP∶TEOA(5∶1)	CO	487	99%	[57]
四联吡啶铁配合物	$R u (b p y) 3 2 +$	BIH	MeCN∶TEOA(4∶1)	CO	384	85%	[58]
四联吡啶铁配合物	Purpurin	BIH	DMF	CO	1365	92%	[58]
四联吡啶铁配合物	mpg-C₃N₄	TEOA	ACN∶TEOA (4∶1)	CO	155	97%	[59]

Table 2 Application of iron complex catalyst in photocatalytic reduction of CO2 in recent years

光催化剂	光敏剂	还原剂	溶剂^①	产物	TON	选择性	文献
FeTPP	FeTPP	TEA	DMF	CO	70	—	[50]
Fe-p-TMA	Ir(ppy)₃	TEA	ACN∶H₂O(3∶8)	CH₄	81	81%	[51]
FeTMA	CuInS₂/ZnS QD	—	H₂O	CO	450	99%	[61]
FeTPP-p-TMA	无	BIH	CAN	CO	63	—	[52]
FeTPP-p-TMA	无	TEA	CAN	CO	33	100%	[52]
FeTPP-p-TMA	Ir(ppy)₃	TEA	CAN	CH₄	89	82%	[53]
FeTPP-o-OH	Ir(ppy)₃	TEA	CAN	CO	140	93%	[54]
Fe₃(CO)₁₂	[Ru(bpy)₃]Cl₂	TEOA	NMP∶TEOA(5∶1)	CO	36	—	[55]
Fe(CO)₃bpy	[Ru(bpy)₃]Cl₂	TEOA	NMP∶TEOA(5∶1)	CO	42	—	[55]
（环戊二烯酮）铁-三羰基配合物	Ir PS	TEOA	NMP	CO	596	—	[56]
环戊二烯酮铁配合物	Cu PS	BNAH	NMP∶TEOA(5∶1)	CO	487	99%	[57]
四联吡啶铁配合物	$R u (b p y) 3 2 +$	BIH	MeCN∶TEOA(4∶1)	CO	384	85%	[58]
四联吡啶铁配合物	Purpurin	BIH	DMF	CO	1365	92%	[58]
四联吡啶铁配合物	mpg-C₃N₄	TEOA	ACN∶TEOA (4∶1)	CO	155	97%	[59]

Fig.7 Dual excitation pathways over amino-functionalized Fe-based MOFs[67]

Fig.8 Influence of the electron configurations of the metal centers on the metal-carbon interactions in [FeⅡ(Por2-)(COOH-)]- and[CoⅡ(Por2-)(COOH-)]-[72]

Fig.9 Product amounts of LaFeO3 and its composites during the photocatalytic CO2 conversion[81]

Table 3 Application of iron-based catalysts in photocatalytic reduction of CO2 in recent years

光催化剂	合成方法	产物	产率	文献
g-C₃N₄/α-Fe₂O₃	超声波辅助法	CO/CH₄	15.8/3.1 μmol/(g·h)	[35]
CN-Al-F	湿化学法	CO	24 μmol/(g·h)	[35]
g-C₃N₄/α-Fe₂O₃	水热法	CH₃OH	5.63 μmol/(g·h)	[36]
rGO/InVO₄/Fe₂O₃	沉积-沉淀法	CH₃OH	16.9 mmol/g(24 h）	[37]
FeO_x/ZSM-5	功能离子预吸附法	CO/CH₃CHO	10.01/3.8 μmol/(g·h)	[38]
ZnFe₂O₄	溶剂热法	CH₃CHO/CH₃CH₂OH	57.8/13.7 μmol/(g·h)	[42]
ZnFe₂O₄/Ag/TiO₂	水热法	CO/CH₄/CH₃OH	606.25/132/31 μmol/(g·h)	[43]
Au/CuFe₂O₄	溶剂热法	CO	537.6 μl/(g·h)	[39]
NH₂-MIL-101（Fe）	水热法	HCOO^-	178 μmol(4 h)	[67]
NH₂-MIL-101（Fe）	水热法	CO	17.52 μmol/(g·h)	[68]
MAPbI₃@PCN-221(Fe_x)	顺序沉积法	CO/CH₄	6.625/12.85 μmol/(g·h)	[70]
NH₂-MIL-101(Fe)/g-C₃N₄	水热法	CO	132.8 μmol/g(6 h)	[71]
In-Fe_nTCPP-MOF	超声波辅助法	CO	3469 μmol/g(24 h)	[72]
BiFeO₃/SWCNTs	溶胶-凝胶法	CH₃OH	1000 μmol/g(4~6 h)	[76]
BiFeO₃-ZnO	水热法	—	CO₂转化率：21%	[77]
Ag₂CrO₄/Ag/BiFeO₃@RGO	—	CH₄	260 μmol/g(8 h)	[78]
TiO₂/碳纳米球/N-LaFeO₃	水热法，热解法	CO/CH₄	150/110 μmol/g(8 h)	[81]
Fe–TiO₂	水热法	CH₄	7.73 μmol/g(12 h)	[85]
Fe–TiO₂	溶胶-凝胶法	CH₃OH	约2125 μmol/g(12 h)	[86]
Fe-N-TiO₂	溶胶-凝胶法	CH₄/CH₃OH	38.72/1.73 μmol/(g·h)	[87]
Fe–CeO₂	纳米铸造法	CO/CH₄	12.38/2.88 μmol/(g·h)	[17]

References 87

5	张睿哲, 李可可, 张凯博, 等. 煤基碳量子点/氮化碳复合材料制备及其光催化还原CO₂性能[J]. 化工学报, 2020, 71(6): 2788-2794.
	Zhang R Z, Li K K, Zhang K B, et al. Coal-based carbon quantum dots/carbon nitride composites for photocatalytic CO₂ reduction[J]. CIESC Journal, 2020, 71(6): 2788-2794.
6	Ismael M. A review on graphitic carbon nitride (g-C₃N₄) based nanocomposites: synthesis, categories, and their application in photocatalysis[J]. Journal of Alloys and Compounds, 2020, 846: 156446.
7	Wang Y O, Liu X, Han X Y, et al. Unique hole-accepting carbon-dots promoting selective carbon dioxide reduction nearly 100% to methanol by pure water[J]. Nature Communications, 2020, 11: 2531.
8	张轩, 黄耀桢, 邵秀丽, 等. 结构化铜基催化剂电化学还原CO₂为多碳产物研究进展[J]. 化工进展, 2021, 40(7): 3736-3746.
	Zhang X, Huang Y Z, Shao X L, et al. Recent progress in structured Cu-based catalysts for electrochemical CO₂ reduction to C²⁺ products[J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3736-3746.
9	Li B, Sun L Q, Bian J, et al. Controlled synthesis of novel Z-scheme iron phthalocyanine/porous WO₃ nanocomposites as efficient photocatalysts for CO₂ reduction[J]. Applied Catalysis B: Environmental, 2020, 270: 118849.
10	Zhang X H, Zhang L, Deng B W, et al. Visible light-responding perovskite oxide catalysts for photo-thermochemical CO₂ reduction[J]. Catalysis Communications, 2020, 138: 105955.
11	Lehn J M, Ziessel R. Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation[J]. Proceedings of the National Academy of Sciences of the United States of America, 1982, 79(2): 701-704.
12	Lingampalli S R, Ayyub M M, Rao C N R. Recent progress in the photocatalyticr reduction of carbon dioxide[J]. ACS Omega, 2017, 2(6): 2740-2748.
13	Ren X H, Philo D, Li Y X, et al. Recent advances of low-dimensional phosphorus-based nanomaterials for solar-driven photocatalytic reactions[J]. Coordination Chemistry Reviews, 2020, 424: 213516.
14	Tjandra A D, Huang J. Photocatalytic carbon dioxide reduction by photocatalyst innovation[J]. Chinese Chemical Letters, 2018, 29(6): 734-746.
15	Chan S L F, Lam T L, Yang C, et al. A robust and efficient cobalt molecular catalyst for CO₂ reduction[J]. Chemical Communications (Cambridge, England), 2015, 51(37): 7799-7801.
1	Cao S W, Li Y, Zhu B C, et al. Facet effect of Pd cocatalyst on photocatalytic CO₂ reduction over g-C₃N₄[J]. Journal of Catalysis, 2017, 349: 208-217.
2	Liu H M, Song H, Zhou W, et al. A promising application of optical hexagonal TaN in photocatalytic reactions[J]. Angewandte Chemie International Editon, 2018, 57(51): 16781-16784.
16	Khalil M, Gunlazuardi J, Ivandini T A, et al. Photocatalytic conversion of CO₂ using earth-abundant catalysts: a review on mechanism and catalytic performance[J]. Renewable and Sustainable Energy Reviews, 2019, 113: 109246.
17	Wang Y G, Wang F, Chen Y T, et al. Enhanced photocatalytic performance of ordered mesoporous Fe-doped CeO₂ catalysts for the reduction of CO₂ with H₂O under simulated solar irradiation[J]. Applied Catalysis B: Environmental, 2014, 147: 602-609.
18	Sun L T, Tang Y M, Zuo W. Coronavirus pushes education online[J]. Nature Materials, 2020, 19(6): 687.
19	Li K, Peng B S, Peng T Y. Recent advances in heterogeneous photocatalytic CO₂ conversion to solar fuels[J]. ACS Catalysis, 2016, 6(11): 7485-7527.
20	Karamian E, Sharifnia S. On the general mechanism of photocatalytic reduction of CO₂[J]. Journal of CO₂ Utilization, 2016, 16: 194-203.
21	Kang Y F, Li Y H, Fang Y W, et al. Carbon quantum dots for zebrafish fluorescence imaging[J]. Scientific Reports, 2015, 5: 11835.
22	Li K, An X Q, Park K H, et al. A critical review of CO₂ photoconversion: catalysts and reactors[J]. Catalysis Today, 2014, 224: 3-12.
23	Ma Y J, Wang Z M, Xu X F, et al. Review on porous nanomaterials for adsorption and photocatalytic conversion of CO₂[J]. Chinese Journal of Catalysis, 2017, 38(12): 1956-1969.
24	Iqbal F, Mumtaz A, Shahabuddin S, et al. Photocatalytic reduction of CO₂ to methanol over ZnFe₂O₄/TiO₂ (p-n) heterojunctions under visible light irradiation[J]. Journal of Chemical Technology & Biotechnology, 2020, 95(8): 2208-2221.
25	Sekizawa K, Sato S, Arai T, et al. Solar-driven photocatalytic CO₂ reduction in water utilizing a ruthenium complex catalyst on p-type Fe₂O₃ with a multiheterojunction[J]. ACS Catalysis, 2018, 8(2): 1405-1416.
26	Sahara G, Ishitani O. Efficient photocatalysts for CO₂ reduction[J]. Inorganic Chemistry, 2015, 54(11): 5096-5104.
27	Kulandaivalu T, Mohamed A R, Ali K A, et al. Photocatalytic carbon dioxide reforming of methane as an alternative approach for solar fuel production—a review[J]. Renewable and Sustainable Energy Reviews, 2020, 134: 110363.
28	Vu N N, Kaliaguine S, Do T O. Critical aspects and recent advances in structural engineering of photocatalysts for sunlight-driven photocatalytic reduction of CO₂ into fuels[J]. Advanced Functional Materials, 2019, 29(31): 1901825.
29	Yamazaki Y, Takeda H, Ishitani O. Photocatalytic reduction of CO₂ using metal complexes[J]. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2015, 25: 106-137.
30	Sokol K, Robinson W E, Oliveira A R, et al. Photoreduction of CO₂ with a formate dehydrogenase driven by photosystem II using a semi-artificial Z-scheme architecture[J]. Journal of the American Chemical Society, 2018, 140(48): 16418-16422.
31	He Y, Zhang L, Teng B, et al. New application of Z-scheme Ag₃PO₄/g-C₃N₄ composite in converting CO₂ to fuel[J]. Environmental Science & Technology, 2015, 49(1): 649-656.
32	Yu W L, Xu D F, Peng T Y. Enhanced photocatalytic activity of g-C₃N₄ for selective CO₂ reduction to CH₃OH via facile coupling of ZnO: a direct Z-scheme mechanism[J]. Journal of Materials Chemistry A, 2015, 3(39): 19936-19947.
33	Yamamoto M, Yoshida T, Yamamoto N, et al. Photocatalytic reduction of CO₂ with water promoted by Ag clusters in Ag/Ga₂O₃ photocatalysts[J]. Journal of Materials Chemistry A, 2015, 3(32): 16810-16816.
34	Wang Z Y, Luan D Y, Madhavi S, et al. Assembling carbon-coated α-Fe₂O₃ hollow nanohorns on the CNT backbone for superior lithium storage capability[J]. Energy Environ Sci, 2012, 5(1): 5252-5256.
35	Wang J S, Qin C L, Wang H J, et al. Exceptional photocatalytic activities for CO₂ conversion on ALO bridged g-C₃N₄/α- Fe₂O₃ z-scheme nanocomposites and mechanism insight with isotopesZ[J]. Applied Catalysis B: Environmental, 2018, 221: 459-466.
36	Guo H W, Chen M Q, Zhong Q, et al. Synthesis of Z-scheme α-Fe₂O₃/g-C₃N₄ composite with enhanced visible-light photocatalytic reduction of CO₂ to CH₃OH[J]. Journal of CO₂ Utilization, 2019, 33: 233-241.
37	Kumar A, Prajapati P K, Pal U, et al. Ternary rGO/InVO₄/ Fe₂O₃Z-scheme heterostructured photocatalyst for CO₂ reduction under visible light irradiation[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(7): 8201-8211.
38	Zhao X J, Chen W, Li G H, et al. Gas-phase CO₂ photoreduction via iron/ZSM-5 composites[J]. Applied Catalysis A: General, 2020, 595: 117503.
39	何小刚, 齐高璨. 铁酸盐的形貌调控及其催化还原CO₂的性能研究[J]. 天津理工大学学报, 2020, 36(2): 59-64.
	He X G, Qi G C. Morphology control of ferrites and its catalytic reduction of CO₂[J]. Journal of Tianjin University of Technology, 2020, 36(2): 59-64.
40	Gao H Y, Wang J Y, Jia M Y, et al. Construction of TiO₂ nanosheets/tetra (4-carboxyphenyl) porphyrin hybrids for efficient visible-light photoreduction of CO₂[J]. Chemical Engineering Journal, 2019, 374: 684-693.
41	Yadav N G, Chaudhary L S, Sakhare P A, et al. Impact of collected sunlight on Zn₂FeO₄ nanoparticles for photocatalytic application[J]. Journal of Colloid and Interface Science, 2018, 527: 289-297.
42	Xiao J, Yang W Y, Gao S, et al. Fabrication of ultrafine Zn₂FeO₄ nanoparticles for efficient photocatalytic reduction CO₂ under visible light illumination[J]. Journal of Materials Science & Technology, 2018, 34(12): 2331-2336.
43	Tahir M. Well-designed Zn₂FeO₄/Ag/ TiO₂ nanorods heterojunction with Ag as electron mediator for photocatalytic CO₂ reduction to fuels under UV/visible light[J]. Journal of CO₂ Utilization, 2020, 37: 134-146.
44	Chen L, Guo Z, Wei X G, et al. Molecular catalysis of the electrochemical and photochemical reduction of CO₂ with earth-abundant metal complexes, selective production of CO vs HCOOH by switching of the metal center[J]. Journal of the American Chemical Society, 2015, 137(34): 10918-10921.
45	Grodkowski J, Dhanasekaran T, Neta P, et al. Reduction of cobalt and iron phthalocyanines and the role of the reduced species in catalyzed photoreduction of CO₂[J]. The Journal of Physical Chemistry A, 2000, 104(48): 11332-11339.
46	Sorokin A B. Phthalocyanine metal complexes in catalysis[J]. Chemical Reviews, 2013, 113(10): 8152-8191.
47	Lin L, Hou C C, Zhang X H, et al. Highly efficient visible-light driven photocatalytic reduction of CO₂ over g-C₃N₄ nanosheets/tetra(4-carboxyphenyl)porphyrin iron(Ⅲ) chloride heterogeneous catalysts[J]. Applied Catalysis B: Environmental, 2018, 221: 312-319.
48	Grodkowski J, Neta P. Ferrous ions as catclysts for photochemical reduction of CO₂ in homogeneous solutions[J]. The Journal of Physical Chemistry A, 2000, 104(19): 4475-4479.
49	Takeda H, Ohashi K, Sekine A, et al. Photocatalytic CO₂ reduction using Cu(Ⅰ) photosensitizers with a Fe(Ⅱ) catalyst[J]. Journal of the American Chemical Society, 2016, 138(13): 4354-4357.
50	Grodkowski J, Behar D, Neta P, et al. Iron porphyrin-catalyzed reduction of CO_2. photochemical and radiation chemical studies[J]. The Journal of Physical Chemistry A, 1997, 101(3): 248-254.
51	Rao H, Bonin J, Robert M. Toward visible-light photochemical CO₂-to-CH₄ conversion in aqueous solutions using sensitized molecular catalysis[J]. The Journal of Physical Chemistry C, 2018, 122(25): 13834-13839.
52	Rao H, Bonin J, Robert M. Non-sensitized selective photochemical reduction of CO₂ to CO under visible light with an iron molecular catalyst[J]. Chemical Communications, 2017, 53(19): 2830-2833.
53	Rao H, Schmidt L C, Bonin J, et al. Visible-light-driven methane formation from CO₂ with a molecular iron catalyst[J]. Nature, 2017, 548(7665): 74-77.
54	Bonin J, Robert M, Routier M. Selective and efficient photocatalytic CO₂ reduction to CO using visible light and an iron-based homogeneous catalyst[J]. Journal of the American Chemical Society, 2014, 136(48): 16768-16771.
55	Alsabeh P G, Rosas-Hernández A, Barsch E, et al. Iron-catalyzed photoreduction of carbon dioxide to synthesis gas[J]. Catalysis Science & Technology, 2016, 6(10): 3623-3630.
56	Rosas-Hernández A, Alsabeh P G, Barsch E, et al. Highly active and selective photochemical reduction of CO₂ to CO using molecular-defined cyclopentadienone iron complexes[J]. Chemical Communications, 2016, 52(54): 8393-8396.
57	Rosas-Hernández A, Steinlechner C, Junge H, et al. Earth-abundant photocatalytic systems for the visible-light-driven reduction of CO₂ to CO[J]. Green Chemistry, 2017, 19(10): 2356-2360.
58	Guo Z G, Cheng S W, Cometto C, et al. Highly efficient and selective photocatalytic CO₂ reduction by iron and cobalt quaterpyridine complexes[J]. Journal of the American Chemical Society, 2016, 138(30): 9413-9416.
59	Cometto C, Kuriki R, Chen L J, et al. A carbon nitride/Fe quaterpyridine catalytic system for photostimulated CO₂-to-CO conversion with visible light[J]. Journal of the American Chemical Society, 2018, 140(24): 7437-7440.
60	Gewirth A A, Varnell J A, DiAscro A M. Nonprecious metal catalysts for oxygen reduction in heterogeneous aqueous systems[J]. Chemical Reviews, 2018, 118(5): 2313-2339.
61	Lian S, Kodaimati M S, Weiss E A. Photocatalytically active superstructures of quantum dots and iron porphyrins for reduction of CO₂ to CO in water[J]. ACS Nano, 2018, 12(1): 568-575.
62	Alkhatib I I, Garlisi C, Pagliaro M, et al. Metal-organic frameworks for photocatalytic CO₂ reduction under visible radiation: a review of strategies and applications[J]. Catalysis Today, 2020, 340: 209-224.
63	Dhakshinamoorthy A, Asiri A M, Garcia H. Metall-organische Gerüstverbindungen: Photokatalysatoren für Redoxreaktion und Die Produktion von Solarbrennstoffen[J]. Angewandte Chemie, 2016, 128(18): 5504-5535.
64	Luo Y H, Dong L Z, Liu J, et al. From molecular metal complex to metal-organic framework: the CO₂ reduction photocatalysts with clear and tunable structure[J]. Coordination Chemistry Reviews, 2019, 390: 86-126.
65	封啸, 任颜卫, 江焕峰. 金属-有机框架材料在光催化二氧化碳还原中的应用[J]. 化学进展, 2020, 32(11): 1697-1709.
	Feng X, Ren Y W, Jiang H F. Application of metal-organic framework materials in the photocatalytic carbon dioxide reduction[J]. Progress in Chemistry, 2020, 32(11): 1697-1709.
66	Laurier K G M, Vermoortele F, Ameloot R, et al. Iron(Ⅲ)-based metal-organic frameworks as visible light photocatalysts[J]. Journal of the American Chemical Society, 2013, 135(39): 14488-14491.
67	Wang D K, Huang R K, Liu W J, et al. Fe-based MOFs for photocatalytic CO₂ reduction: role of coordination unsaturated sites and dual excitation pathways[J]. ACS Catalysis, 2014, 4(12): 4254-4260.
68	Dao X Y, Guo J H, Wei Y P, et al. Solvent-free photoreduction of CO₂ to CO catalyzed by Fe-MOFs with superior selectivity[J]. Inorganic Chemistry, 2019, 58(13): 8517-8524.
69	Chen H, Liu Y T, Cai T, et al. Boosting photocatalytic performance in mixed-valence MIL-53(Fe) by changing FeⅡ/FeⅢ ratio[J]. ACS Applied Materials & Interfaces, 2019, 11(32): 28791-28800.
70	Wu L Y, Mu Y F, Guo X X, et al. Encapsulating perovskite quantum dots in iron-based metal-organic frameworks (MOFs) for efficient photocatalytic CO₂ reduction[J]. Angewandte Chemie International Esition, 2019, 58(28): 9491-9495.
71	Dao X Y, Xie X F, Guo J H, et al. Boosting photocatalytic CO₂ reduction efficiency by heterostructures of NH₂-MIL-101(Fe)/g-C₃N₄[J]. ACS Applied Energy Materials, 2020, 3(4): 3946-3954.
72	Wang S S, Huang H H, Liu M, et al. Encapsulation of single iron sites in a metal-porphyrin framework for high-performance photocatalytic CO₂ reduction[J]. Inorganic Chemistry, 2020, 59(9): 6301-6307.
73	王丽梅, 刘宇威, 周杰, 等. 钙钛矿材料光催化还原CO₂综述[J]. 分子科学学报, 2020, 36(2): 96-101.
	Wang L M, Liu Y W, Zhou J, et al. Photocatalytic reduction of CO₂via perovskite materials: a review[J]. Journal of Molecular Science, 2020, 36(2): 96-101.
74	赵润, 杨浩. 多铁性钙钛矿薄膜的氧空位调控研究进展[J]. 物理学报, 2018, 67(15): 156101.
	Zhao R, Yang H. Oxygen vacancies induced tuning effect on physical properties of multiferroic perovskite oxide thin films[J]. Acta Physica Sinica, 2018, 67(15): 156101.
75	Hu Z J, Chen D, Wang S, et al. Facile synthesis of Sm-doped BiFeO₃ nanoparticles for enhanced visible light photocatalytic performance[J]. Materials Science and Engineering: B, 2017, 220: 1-12.
76	李鑫, 何世育, 李忠. 碳纳米管改性铁酸铋光催化还原CO₂合成甲醇[J]. 硅酸盐学报, 2009, 37(11): 1869-1872.
	Li X, He S Y, Li Z. Methanol synthesis in the catalytic reduction of CO₂ under the visible light by BiFeO₃ modified with carbon nanotubes[J]. Journal of the Chinese Ceramic Society, 2009, 37(11): 1869-1872.
77	Karamian E, Sharifnia S. Enhanced visible light photocatalytic activity of BiFeO₃-ZnO p-n heterojunction for CO₂ reduction[J]. Materials Science and Engineering: B, 2018, 238: 142-148.
78	Kumar A, Sharma G, Naushad M, et al. Highly visible active Ag₂CrO₄/Ag/BiFeO₃@RGO nano-junction for photoreduction of CO₂ and photocatalytic removal of ciprofloxacin and bromate ions: the triggering effect of Ag and RGO[J]. Chemical Engineering Journal, 2019, 370: 148-165.
79	Liu Y, Ma Y J, Liu W W, et al. Facet and morphology dependent photocatalytic hydrogen evolution with CdS nanoflowers using a novel mixed solvothermal strategy[J]. Journal of Colloid and Interface Science, 2018, 513: 222-230.
80	Rather R A, Khan M, Lo I M C. High charge transfer response of g-C₃N₄/Ag/AgCl/BiVO₄ microstructure for the selective photocatalytic reduction of CO₂ to CH₄ under alkali activation[J]. Journal of Catalysis, 2018, 366: 28-36.
81	Humayun M, Qu Y, Raziq F, et al. Exceptional visible-light activities of TiO₂-coupled N-doped porous perovskite LaFeO₃ for 2, 4-dichlorophenol decomposition and CO₂ conversion[J]. Environmental Science & Technology, 2016, 50(24): 13600-13610.
3	郭红霞, 崔继方, 刘利. 氧空位增强光催化还原CO₂性能方面的研究进展[J]. 应用化学, 2020, 37(3): 256-263.
	Guo H X, Cui J F, Liu L. Research progress in photocatalytic reduction of CO₂ enhanced by oxygen vacancy[J]. Chinese Journal of Applied Chemistry, 2020, 37(3): 256-263.
4	Wu Y A, McNulty I, Liu C, et al. Facet-dependent active sites of a single Cu₂O particle photocatalyst for CO₂ reduction to methanol[J]. Nature Energy, 2019, 4(11): 957-968.
82	Ileperuma O A, Tennakone K, Dissanayake W. Photocatalytic behavior of metal-doped titanium dioxide: studies on the photochemical synthesis of ammonia on Mg/TiO₂ catalyst systems[J]. Applied Catalysis, 1990, 62: 1-5.
83	Abdullah H, Khan M M R, Ong H R, et al. Modified TiO₂ photocatalyst for CO₂ photocatalytic reduction: an overview[J]. Journal of CO₂ Utilization, 2017, 22: 15-32.
84	Shehzad N, Tahir M, Johari K, et al. A critical review on TiO₂ based photocatalytic CO₂ reduction system: strategies to improve efficiency[J]. Journal of CO₂ Utilization, 2018, 26: 98-122.
85	Xu M, Wu H, Tang Y W, et al. One-step in situ synthesis of porous Fe³⁺-doped TiO₂ octahedra toward visible-light photocatalytic conversion of CO₂ into solar fuel[J]. Microporous and Mesoporous Materials, 2020, 309: 110539.
86	Chen X Y, Ye X Z, He J X, et al. Preparation of Fe³⁺-doped TiO₂ aerogels for photocatalytic reduction of CO₂ to methanol[J]. Journal of Sol-Gel Science and Technology, 2020, 95(2): 353-359.
87	Khalilzadeh A, Shariati A. Photoconversion of CO₂ over Fe-N-Ti@xSBA nanocomposite to produce hydrocarbon fuels[J]. Journal of CO₂ Utilization, 2019, 33: 21-30.

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Research progress in photocatalytic reduction of CO₂ with iron-based catalysts

铁基催化剂光催化还原CO₂研究进展

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