Measurement of multi-parameter of liquid film for urea-water-solutions with laser absorption spectroscopy

doi:10.11949/j.issn.0438-1157.20160913

CIESC Journal ›› 2017, Vol. 68 ›› Issue (1): 79-86.DOI: 10.11949/j.issn.0438-1157.20160913

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Measurement of multi-parameter of liquid film for urea-water-solutions with laser absorption spectroscopy

SHI Jianwei^1,2, WU Wei^1,2, YANG Huinan^1,2, SU Mingxu^1,2, CAI Xiaoshu^1,2

1 School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China;
2 Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering, Shanghai 200093, China

Received:2016-07-04 Revised:2016-10-14 Online:2017-01-05 Published:2017-01-05
Contact: 10.11949/j.issn.0438-1157.20160913
Supported by:
supported by the National Natural Science Foundation of China (51676130, 51306123), the Joint Specialized Research Found for the Doctoral Program of Higher Education (20133120120008),the Shanghai Science and Technology Commission of China (13DZ2260900) and the Cultivation of Young Teachers in Colleges and Universities Funded Program in Shanghai.

基于激光光谱法的尿素水溶液液膜多参数测量

石建伟^1,2, 吴威^1,2, 杨荟楠^1,2, 苏明旭^1,2, 蔡小舒^1,2

1 上海理工大学能源与动力工程学院, 上海 200093;
2 上海市动力工程多相流动与传热重点实验室, 上海 200093

通讯作者: 杨荟楠
基金资助:
国家自然科学基金项目（51676130，51306123）；博士点基金联合资助课题新教师类项目（20133120120008）；上海市科委科研计划项目（13DZ2260900）；上海高校青年教师培养资助计划项目。

Abstract

Abstract:

In selective catalytic reduction(SCR) system, quantitative analysis of multi-parameter of liquid film(film thickness, temperature and mass fraction) for urea-water-solutions is crucial to control the formation of liquid film, improve the efficiency of SCR system and reduce the NO_x emissions.A new method based on Beer-Lambert law was developed to simultaneously measure the thickness and mass fraction of liquid film for urea-water-solutions at constant temperature, and the thickness and temperature at constant mass fraction by combining two different wavelengths, 1420 nm and 1488 nm, respectively.Furthermore, measurement accuracy of this method was validated by a calibration tool which provided liquid film with known film thickness, temperature and mass fraction, respectively.It was found that the averaged deviation of film thickness and mass fraction measured simultaneously at constant temperature was 0.82% and 3.93%, respectively.It also revealed that the mean deviation of film thickness and temperature measured simultaneously at constant mass fraction was 0.79% and 2.58%, respectively.

Key words: laser spectroscopy, liquid film, aqueous solution, SCR, experimental validation, measurement

摘要：

在选择性催化还原（SCR）系统中，对尿素水溶液液膜多个参数（厚度、浓度及温度）进行高精度的定量分析，对减少液膜形成、提高SCR系统的催化反应效率、降低NO_x对环境的污染至关重要。基于比尔-朗伯定律，通过结合1420 nm和1488 nm两个波长的半导体激光器，提出一种恒温度条件下尿素水溶液液膜厚度和浓度同步测量，以及恒浓度条件下尿素水溶液液膜厚度和温度同步测量的新方法。并在此基础上，利用标准具验证了该方法的测量精度。结果表明恒温度条件下，该方法同步测量尿素水溶液液膜厚度和浓度的平均测量误差分别为0.82%和3.93%；恒浓度条件下，同步测量尿素水溶液液膜厚度和温度的平均测量误差分别为0.79%和2.58%。

关键词: 激光光谱, 液膜, 水溶液, 选择性催化还原, 实验验证, 测量

CLC Number:

TK31

SHI Jianwei, WU Wei, YANG Huinan, SU Mingxu, CAI Xiaoshu. Measurement of multi-parameter of liquid film for urea-water-solutions with laser absorption spectroscopy[J]. CIESC Journal, 2017, 68(1): 79-86.

石建伟, 吴威, 杨荟楠, 苏明旭, 蔡小舒. 基于激光光谱法的尿素水溶液液膜多参数测量[J]. 化工学报, 2017, 68(1): 79-86.

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Measurement of multi-parameter of liquid film for urea-water-solutions with laser absorption spectroscopy

基于激光光谱法的尿素水溶液液膜多参数测量

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