CIESC Journal ›› 2019, Vol. 70 ›› Issue (4): 1620-1627.DOI: 10.11949/j.issn.0438-1157.20181041

• Material science and engineering, nanotechnology • Previous Articles     Next Articles

Preparation of homogeneous anion exchange membrane based on quaternized PVC for electrodialysis

Chao WANG1,2(),Nengxiu PAN1,2,Dan LU1,Junbin LIAO1,2(),Jiangnan SHEN1,2,Congjie GAO1,2   

  1. 1. Ocean College, Zhejiang University of Technology, Hangzhou 310014, Zhejiang, China
    2. Centre of Membrane Science and Water Technology, Zhejiang University of Technology, Hangzhou 310014, Zhejiang, China
  • Received:2018-09-18 Revised:2019-01-09 Online:2019-04-05 Published:2019-04-05
  • Contact: Junbin LIAO

电渗析用季铵化聚氯乙烯均相阴离子交换膜的制备

王超1,2(),潘能修1,2,鲁丹1,廖俊斌1,2(),沈江南1,2,高从堦1,2   

  1. 1. 浙江工业大学海洋学院,浙江 杭州 310014
    2. 浙江工业大学膜分离与水科学技术中心,浙江 杭州 310014
  • 通讯作者: 廖俊斌
  • 作者简介:<named-content content-type="corresp-name">王超</named-content>(1996—),男,硕士研究生,<email>879977706@qq.com</email>|廖俊斌(1985—),男,博士,助理研究员,<email>jbliao@zjut.edu.cn</email>
  • 基金资助:
    国家自然科学基金项目(21676249,21878273)

Abstract:

This work presents the preparation of homogeneous anion exchange membrane (AEM) based on quaternized polyvinyl chloride (PVC) via straight forward quaternization of PVC with 1-methylimidazole (N-MI). In particular, the preparation avoids the use of toxic chloromethylation. The optimized AEM PVC-N-MI-5 shows ion-exchange capacity (IEC) and transport number of 2.89 mmol·g–1 and 98.4%, respectively. The water uptake and swelling ratio are 4.24% and 0.21%, lower than the commercial AEM JAM-5 (4.87% and 3.33%). The NaCl removal ratio, current efficiency and energy consumption of the as-prepared AEM were 98.38%、55.8% and 5.1 kW·h·(kg NaCl)-1, respectively, comparable to commerical JAM-5(93.0%, 55.2% and 4.6 kW·h·(kg NaCl)-1). The cost-effective PVC and relatively good performance are suggestive of the potential electrodialysis application.

Key words: polyvinyl chloride, 1-methylimidazole, homogeneous anion exchange membrane, electrodialysis

摘要:

以1-甲基咪唑(N-MI)为季铵化试剂一步法对聚氯乙烯(PVC)功能化改性,并制备了均相PVC阴离子交换膜,避免了传统阴离子交换膜制备过程中的氯甲基化步骤。通过对比研究,优化后的PVC-N-MI-5表现出较好的综合性能。离子交换容量和迁移数分别高达2.89 mmol·g–1和98.4%;吸水率和溶胀率分别为4.24%和0.21%,低于商业JAM-5阴离子交换膜(4.87%和3.33%);脱盐率、电流效率以及能耗分别为98.38%、55.8%和5.1 kW·h·(kg NaCl)–1,可与商业JAM-5(93.0%、55.2%和4.6 kW·h·(kg NaCl)–1)相比较。低廉的原料与简便的制备过程以及相对良好的电渗析应用性能,表明所制备的PVC-N-MI-5具有一定的应用前景。

关键词: 聚氯乙烯, 1-甲基咪唑, 均相阴离子交换膜膜, 电渗析

CLC Number: