Preparation of high specific surface area magnetic ordered mesoporous carbons and adsorption property of methylene blue

doi:10.3969/j.issn.0438-1157.2012.12.049

CIESC Journal ›› 2012, Vol. 63 ›› Issue (12): 4082-4088.DOI: 10.3969/j.issn.0438-1157.2012.12.049

Previous Articles Next Articles

Preparation of high specific surface area magnetic ordered mesoporous carbons and adsorption property of methylene blue

TIAN Yong, ZHONG Guoying, WANG Xiufang, LIN Hansen

School of Pharmacy, Guangdong Pharmaceutical University, Guangzhou 510006, Guangdong, China

Received:2012-04-27 Revised:2012-07-04 Online:2012-12-05 Published:2012-12-05
Supported by:
supported by the National Natural Science Foundation of China(50802017),the Higher Education Talents Introducing Fund of Guangdong Province(2011),the Natural Science Foundation of Guangdong Province(S2012010009416),the Foundation for Distinguished Young Talents in Higher Education of Guangdong(2012LYM_0085)and the Planned Project of Science and Technology of Guangdong Province(2012B020316007).

高比表面磁性有序介孔炭的合成及对亚甲基蓝的吸附性能

田勇, 钟国英, 王秀芳, 林汉森

广东药学院药科学院, 广东广州 510006

通讯作者: 王秀芳
作者简介:田勇(1977-),男,博士,副教授。
基金资助:
国家自然科学基金项目(50802017);广东省高等学校高层次人才项目(2011年度);广东省自然科学基金项目(S2012010009416);广东高校优秀青年创新人才培养计划项目(2012LYM_085);广东省科技计划项目(2012B020316007)。

Abstract

Abstract: Magnetic Fe-containing ordered mesoporous carbons(Fe/OMCs)with high surface area and large pore volume provide an easy and effective way for the treatment of dye in waste water.Fe/OMCs were synthesized by the soft-template route,wherein phenolic resin was used as a carbon precursor,triblock copolymer F127 as a template agent,tetraethylorsilicate(TEOS)as a silica precursor and hydrated iron nitrate as an iron source.The effects of Fe(NO₃)₃?9H₂O loading on the morphology,structural parameters,and magnetic properties of the Fe/OMCs were evaluated by X-ray diffraction(XRD),N₂ sorption analysis,transmission electron microscopy(TEM)and physical property measurements.By using methylene blue(MB)as model dye,the adsorption of MB on the obtained Fe/OMCs was investigated.The experimental results showed that the ordering,specific surface area and total pore volume decreased with the increase of Fe(NO₃)₃?9H₂O loading.The Fe/OMCs had fast adsorption ability for MB.The adsorption of MB on the obtained Fe/OMCs followed the Sips adsorption equation and the corresponding parameters were obtained.

Key words: ordered mesoporous carbon, synthesis, adsorption, methylene blue

摘要： 具有高比表面积、大孔容的铁磁性有序介孔炭(Fe/OMCs)对含染料废水的处理提供了一种简单有效的方法。采用苯酚树脂作炭源,三嵌段共聚物F127为模板剂,正硅酸乙酯为硅前驱体,硝酸铁为磁源,通过软模路线合成了Fe/OMCs。利用X射线衍射仪(XRD),氮气吸附仪,透射电镜(TEM)和综合物性测试仪研究了硝酸铁加入量对Fe/OMCs的相态、孔结构参数和磁性的影响;并以亚甲基蓝(MB)为染料探针分子,研究了Fe/OMCs对MB的吸附行为。结果表明材料有序性、比表面和孔容随着硝酸铁加入量的增加而降低,而饱和磁化强度明显增强。Fe/OMCs对MB有快速吸附能力,其行为符合Sips吸附方程。

关键词: 有序介孔炭, 合成, 吸附, 亚甲基蓝

CLC Number:

O647
TQ424.1

TIAN Yong, ZHONG Guoying, WANG Xiufang, LIN Hansen. Preparation of high specific surface area magnetic ordered mesoporous carbons and adsorption property of methylene blue[J]. CIESC Journal, 2012, 63(12): 4082-4088.

田勇, 钟国英, 王秀芳, 林汉森. 高比表面磁性有序介孔炭的合成及对亚甲基蓝的吸附性能[J]. 化工学报, 2012, 63(12): 4082-4088.

References 31

[1]	Gao Tingting(高婷婷),Ji Guangbin(姬广斌).Synthesis of Pd/CMK-3 and its application in Suzuki-Miyaura carbon-carbon coupling reaction[J].CIESC Journal(化工学报),2011,62(2):515-519
[2]	Tian Y,Liu P,Wang X F,et al.Adsorption of malachite green from aqueous solutions onto ordered mesoporous carbons[J].Chem. Eng. J.,2011,171:1263-1269
[3]	Kim B C,Lee J,Um W,et al.Magnetic mesoporous materials for removal of environmental wastes[J].J. Hazard. Mater.,2011,192:1140-1147
[4]	Tian Y,Wang X F,Pan Y F.Simple synthesis of Ni-containing ordered mesoporous carbons and their adsorption/desorption of methylene orange[J].J. Hazard. Mater.,2012,213/214(30):361-368
[5]	Zhai Y P,Dou Y Q,Liu X X,et al.One-pot synthesis of magnetically separable ordered mesoporous carbon[J].J. Mater. Chem.,2009,19:3292-3300
[6]	Wang X F,Liu P,Tian Y.Ordered mesoporous carbons for ibuprofen drug loading and release behavior[J].Micropor. Mesopor. Mater.,2011,142:334-340
[7]	Fulvio P F,Jaroniec M,Liang C D,et al.Polypyrrole-based nitrogen-doped carbon replicas of SBA-15 and SBA-16 containing magnetic nanoparticles[J].J. Phys. Chem. C,2008,112:13126-13133
[8]	Guo L M,Cui X Z,Li Y S,et al.Hollow mesoporous carbon spheres with magnetic cores and their performance as separable bilirubin adsorbents[J].Chem. Asian J.,2009,4:1480-1485
[9]	Fuertes A B,Centeno T A.Mesoporous carbons with graphitic structures fabricated by using porous silica materials as templates and iron-impregnated polypyrrole as precursor[J].J. Mater. Chem.,2005,15:1079-1083
[10]	Park I S,Choi M,Kim T W,et al.Synthesis of magnetically separable ordered mesoporous carbons using furfuryl alcohol and cobalt nitrate in a silica template[J].J. Mater. Chem.,2006,16:3409-3416
[11]	Wang X F,Liu P,Tian Y,et al.Novel synthesis of Fe-containing mesoporous carbons and their release of ibuprofen[J].Micropor. Mesopor. Mater.,2011,145:98-103
[12]	Dong X P,Chen H R,Zhao W R,et al.Synthesis and magnetic properties of mesostructured-Fe2O3/carbon composites by a Co-casting method[J].Chem. Mater.,2007,19:3484-3490
[13]	Lee J W,Jin S M,Hwang Y S,et al.Simple synthesis of mesoporous carbon with magnetic nanoparticles embedded in carbon rods[J].Carbon,2005,43(12):2536-2543
[14]	Zhang T M,Zhao D L,Yin L,Shen Z M.Synthesis and magnetic properties of iron nanoparticles confined in highly ordered mesoporous carbons[J].J. Alloy. Compd.,2010,508:147-151
[15]	Li J S,Gu J,Li H J,et al.Synthesis of highly ordered Fe-containing mesoporous carbon materials using soft templating routes[J].Micropor. Mesopor. Mater.,2010,128:144-149
[16]	Tian Yong,Liu Ping,Wang Jia,Wang Xiufang,Lin Hansen.Synthesis and characterization of magnetic FeNi mesoporous carbon by simple one pot method[J].Mater.,Lett.,2012,82:19-21
[17]	Wang Z L,Liu X J,Lv M F,et al.Simple synthesis of magnetic mesoporous FeNi/carbon composites with a large capacity for the immobilization of biomolecules[J].Carbon,2010,48(11):3182-3189
[18]	Zhai Y P,Dou Y Q,Liu X X,et al.Soft-template synthesis of ordered mesoporous carbon/nanoparticle nickel composites with a high surface area[J].Carbon,2011,49:545-555
[19]	Meng Y,Gu D,Zhang F Q,et al.Ordered mesoporous polymers and homologous carbon frameworks:amphiphilic surfactant templating and direct transformation[J].Angew. Chem. Int. Ed.,2005,44:7053-7059
[20]	Huber D L.Synthesis,properties,and applications of iron nanoparticles[J].Small,2005,1:482-501
[21]	Yao J Y,Li L X,Song H H,et al.Synthesis of magnetically separable ordered mesoporous carbons from F127/[Ni(H2O)6](NO3)2/resorcinol-formaldehyde composites[J].Carbon,2009,47:436-444
[22]	Weisweiler W,Subramanian N,Terwiesch B.Catalytic influence of metal melts on the graphitization of monolithic glasslike carbon[J].Carbon,1971,9:755-758
[23]	Cushing B L,Kolesnichenko V L,Connor J C O.Recent advances in the liquid-phase syntheses of inorganic nanoparticles[J].Chem. Rev.,2004,104:3893-3946
[24]	Celik O,Dag O A.New lyotropic liquid crystalline system:oligo(ethylene oxide)surfactants with[M(H2O)em>n]Xem>m transition metal complexes[J].Angew. Chem. Int. Ed.,2001,40:3799-3803
[25]	Wang X Q,Liang C D,Dai S.Facile synthesis of ordered mesoporous carbons with high thermal stability by self-assembly of resorcinol-formaldehyde and block copolymers under highly acidic conditions[J].Langmuir,2008,24:7500-7505
[26]	Liu R L,Shi Y F,Wan Y,et al.Triconstituent co-assembly to ordered mesostructured polymer-silica and carbon-silica nanocomposites and large-pore mesoporous carbons with high surface areas[J].J. Am. Chem. Soc.,2006,128:11652-11662
[27]	Meng Y,Gu D,Zhang F Q,et al.A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly[J].Chem. Mater.,2006,18:4447-4464
[28]	Jang J,Yoon H.Multigram-scale fabrication of monodisperse conducting polymer and magnetic carbon nanoparticles[J].Small,2005,1:1195-1199
[29]	Diandra L,Pelecky L,Rieke R D.Magnetic properties of nanostructured materials[J].Chem. Mater.,1996,8:1770-1783
[30]	Derylo-Marczewska A,Marczewski A W,Winter S Z,et al. Studies of adsorption equilibria and kinetics in the systems:aqueous solution of dyes-mesoporous carbons[J].Appl. Surf. Sci.,2010,256:5164-5170
[31]	Do D D.Adsorption Analysis:Equilibrium and Kinetics[M].London:Imperial College Press,1988

Preparation of high specific surface area magnetic ordered mesoporous carbons and adsorption property of methylene blue

高比表面磁性有序介孔炭的合成及对亚甲基蓝的吸附性能

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References 31

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Qi WANG, Bin ZHANG, Xiaoxin ZHANG, Hujian WU, Haitao ZHAN, Tao WANG. Synthesis of isoxepac and 2-ethylanthraquinone catalyzed by chloroaluminate-triethylamine ionic liquid/P₂O₅ [J]. CIESC Journal, 2023, 74(S1): 245-249.
[2]	Yan GAO, Peng WU, Chao SHANG, Zejun HU, Xiaodong CHEN. Preparation of magnetic agarose microspheres based on a two-fluid nozzle and their protein adsorption properties [J]. CIESC Journal, 2023, 74(8): 3457-3471.
[3]	Bingchun SHENG, Jianguo YU, Sen LIN. Study on lithium resource separation from underground brine with high concentration of sodium by aluminum-based lithium adsorbent [J]. CIESC Journal, 2023, 74(8): 3375-3385.
[4]	Ruihang ZHANG, Pan CAO, Feng YANG, Kun LI, Peng XIAO, Chun DENG, Bei LIU, Changyu SUN, Guangjin CHEN. Analysis of key parameters affecting product purity of natural gas ethane recovery process via ZIF-8 nanofluid [J]. CIESC Journal, 2023, 74(8): 3386-3393.
[5]	Ji CHEN, Ze HONG, Zhao LEI, Qiang LING, Zhigang ZHAO, Chenhui PENG, Ping CUI. Study on coke dissolution loss reaction and its mechanism based on molecular dynamics simulations [J]. CIESC Journal, 2023, 74(7): 2935-2946.
[6]	Bin LI, Zhenghu XU, Shuang JIANG, Tianyong ZHANG. Clean and efficient synthesis of accelerator CBS by hydrogen peroxide catalytic oxidation method [J]. CIESC Journal, 2023, 74(7): 2919-2925.
[7]	Jiali GE, Tuxiang GUAN, Xinmin QIU, Jian WU, Liming SHEN, Ningzhong BAO. Synthesis of FeF₃ nanoparticles covered by vertical porous carbon for high performance Li-ion battery cathode [J]. CIESC Journal, 2023, 74(7): 3058-3067.
[8]	Jie WANG, Xiaolin QIU, Ye ZHAO, Xinyang LIU, Zhongqiang HAN, Yong XU, Wenhan JIANG. Preparation and properties of polyelectrolyte electrostatic deposition modified PHBV antioxidant films [J]. CIESC Journal, 2023, 74(7): 3068-3078.
[9]	Yuming TU, Gaoyan SHAO, Jianjie CHEN, Feng LIU, Shichao TIAN, Zhiyong ZHOU, Zhongqi REN. Advances in the design, synthesis and application of calcium-based catalysts [J]. CIESC Journal, 2023, 74(7): 2717-2734.
[10]	Tan ZHANG, Guang LIU, Jinping LI, Yuhan SUN. Performance regulation strategies of Ru-based nitrogen reduction electrocatalysts [J]. CIESC Journal, 2023, 74(6): 2264-2280.
[11]	Shaoyun CHEN, Dong XU, Long CHEN, Yu ZHANG, Yuanfang ZHANG, Qingliang YOU, Chenglong HU, Jian CHEN. Preparation and adsorption properties of monolayer polyaniline microsphere arrays [J]. CIESC Journal, 2023, 74(5): 2228-2238.
[12]	Caihong LIN, Li WANG, Yu WU, Peng LIU, Jiangfeng YANG, Jinping LI. Effect of alkali cations in zeolites on adsorption and separation of CO₂/N₂O [J]. CIESC Journal, 2023, 74(5): 2013-2021.
[13]	Chenxin LI, Yanqiu PAN, Liu HE, Yabin NIU, Lu YU. Carbon membrane model based on carbon microcrystal structure and its gas separation simulation [J]. CIESC Journal, 2023, 74(5): 2057-2066.
[14]	Yu PAN, Zihang WANG, Jiayun WANG, Ruzhu WANG, Hua ZHANG. Heat and moisture performance study of Cur-LiCl coated heat exchanger [J]. CIESC Journal, 2023, 74(3): 1352-1359.
[15]	Feng WANG, Yu CHEN, Hongyan PEI, Dongdong LIU, Jing ZHANG, Lixin ZHANG. Design, synthesis and anti-fungal activity of 1,2,4-oxadiazole derivatives [J]. CIESC Journal, 2023, 74(3): 1390-1398.