Progress of Pb2+-recognition-responsive smart polymeric functional materials

doi:10.3969/j.issn.0438-1157.2014.05.003

Abstract

Abstract: Some of the anaerobic bacterium fermented bio-methane can adsorb heavy metals, such as Pb²⁺, which are enriched in biogas slurry and residue. For this reason, the detection and removal of heavy metal ions, such as Pb²⁺ ion in biogas slurry and residue is one of the key problems in the study of bio-methane systems. 18-crown-6 has remarkable recognition ability towards Pb²⁺ ion. The Pb²⁺ ion-recognition-responsive smart materials composed of 18-crown-6 and poly(N-isopropylacrylamide) (PNIPAM) have been developed. In this paper, the progress of investigation on Pb²⁺ ion-recognition-responsive smart polymeric materials based on 18-crown-6 and poly(N-isopropylacrylamide) for detection and removal of Pb²⁺ is reviewed.

Key words: Pb²⁺-recognition, sorption, membranes, polymers

摘要： 发酵生物甲烷的菌群可以吸附Pb²⁺等重金属而在沼液和沼渣中富集；因此，在生物甲烷系统研究过程中，Pb²⁺等重金属离子的检测和处理是沼液和沼渣处理的关键问题之一。18-冠-6具有选择性络合Pb²⁺的能力，研究者们将18-冠-6的Pb²⁺识别特性与聚N-异丙基丙烯酰胺的相变行为特性相结合制备了一系列Pb²⁺识别响应型智能高分子功能材料。本文综述了基于18-冠-6和聚N-异丙基丙烯酰胺的离子识别响应型智能高分子材料在检测和去除Pb²⁺等方面的研究进展。

关键词: Pb²⁺识别, 吸附, 膜, 聚合物

CLC Number:

TB381

LIU Zhuang, JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin. Progress of Pb²⁺-recognition-responsive smart polymeric functional materials[J]. CIESC Journal, 2014, 65(5): 1571-1576.

刘壮, 巨晓洁, 谢锐, 汪伟, 褚良银. Pb²⁺识别响应型智能高分子功能材料的研究进展[J]. 化工学报, 2014, 65(5): 1571-1576.

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Progress of Pb²⁺-recognition-responsive smart polymeric functional materials

Pb²⁺识别响应型智能高分子功能材料的研究进展

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