Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase

doi:10.3969/j.issn.0438-1157.2014.07.024

Abstract

Abstract: Recently emerged liquid-phase oxidation processes catalyzed by carbon nanomaterials as metal-free, low-cost catalysts, either for manufacture of chemicals or for elimination of organic pollutants are reviewed. Oxidations of hydrocarbon, alcohol, ketone, amine, etc. are involved, categorized by the oxidant used, such as O₂, H₂O₂, tert-butyl hydroperoxide, graphite oxide. The reaction processes and catalytic mechanisms are discussed to elucidate the role of carbon nanomaterials as a new class of catalyst.

Key words: carbon nanomaterials, oxidation, liquid-phase, catalysis

摘要： 纳米碳材料是广受关注的高性能材料，其作为无金属催化剂的应用近年来受到了广泛关注。综述了碳材料在不同氧化剂（O₂、H₂O₂、叔丁基过氧化氢、氧化石墨等）的作用下选择性催化氧化烃类、醇类、酮类、胺类等制备有机化学品和氧化降解有机污染物反应过程，着重阐述这些液相氧化反应体系的机理以及碳材料在其中所起的作用。

关键词: 纳米碳材料, 氧化, 液相, 催化

CLC Number:

TQ028.8

CAO Yonghai, LI Bo, YU Hao, PENG Feng, WANG Hongjuan. Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase[J]. CIESC Journal, 2014, 65(7): 2645-2656.

曹永海, 李博, 余皓, 彭峰, 王红娟. 纳米碳材料催化液相选择性氧化的研究进展[J]. 化工学报, 2014, 65(7): 2645-2656.

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