Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO2

doi:10.3969/j.issn.0438-1157.2013.02.028

CIESC Journal ›› 2013, Vol. 64 ›› Issue (2): 616-623.DOI: 10.3969/j.issn.0438-1157.2013.02.028

Previous Articles Next Articles

Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂

AI Ning^1,2, JIANG Zhe¹, XU Qian³, QIAN Qifeng³, WU Xi¹, WANG Jiawei³

1. College of Chemical Engineering and Material Science, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China;
2. State Key Laboratory of Chemical Engineering, Tsinghua University, Beijing 100084, China;
3. Division of Engineering, University of Nottingham Ningbo China, Ningbo 315100, Zhejiang, China

Received:2012-07-31 Revised:2012-10-10 Online:2013-02-05 Published:2013-02-05
Supported by:
supported by the State Key Laboratory of Chemical Engineering in Tsinghua University, China(SKL-ChE-11A02).

氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理

艾宁^1,2, 姜哲¹, 徐茜³, 钱琪枫³, 伍希¹, 王家炜³

1. 浙江工业大学化学工程与材料学院,浙江杭州 310032;
2. 清华大学,化学工程联合国家重点实验室,北京 100084;
3. 宁波诺丁汉大学工程学院,浙江宁波 315100

通讯作者: 王家炜
作者简介:艾宁(1977—),男,博士,副教授。
基金资助:
化学工程联合国家重点实验室开放课题项目(SKL-ChE-11A02)。

Abstract

Abstract: An amine modified NiMgAl layered double hydroxide was synthesized via an exfoliation and grafting method.The samples were characterized by elemental analysis, X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and thermogravimetric analysis (TGA).Adsorption of carbon dioxide on the modified layered double hydroxide was investigated by TGA at 25—150℃.NiMgAl N2 shows a maximum CO₂ adsorption capacity of 2.02 mmol·g^-1 in pure CO₂ and 1.89 mmol·g^-1 in 15% CO₂/N₂ at 80℃.The optimum desorption temperature is 140℃ for NiMgAl N2 according to adsorption/desorption experiments.By in-situ DRIFTS, the adsorption of CO₂ on NiMgAl N2 follows the mechanism of formation of ammonium carbamate ion pairs.

Key words: carbon dioxide, adsorption, in-situ infrared spectrometer, layered double hydroxide, amine

摘要： 以氨基硅烷为改性剂,采用超声剥脱的方法合成了氨基改性的层状双氢氧化物。利用元素分析、X射线衍射(XRD)、漫反射红外傅里叶变换光谱(DRIFTS)和热重分析(TGA)等技术对样品进行了表征。研究了样品在25～150℃温度范围内的二氧化碳吸附能力。在80℃下,NiMgAl N2在纯CO₂和15% CO₂/N₂混合气中达到最大吸附容量,分别为2.02 mmol·g^-1和1.89 mmol·g^-1。吸附/脱附再生实验显示140℃为最佳的脱附温度。利用原位漫反射傅里叶红外光谱对二氧化碳在样品上的吸附进行了机理研究。

关键词: 二氧化碳, 吸附, 原位红外光谱, 层状双氢氧化物, 氨基

CLC Number:

TQ028

AI Ning, JIANG Zhe, XU Xi, QIAN Qifeng, WU Xi, WANG Jiawei. Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂[J]. CIESC Journal, 2013, 64(2): 616-623.

艾宁, 姜哲, 徐茜, 钱琪枫, 伍希, 王家炜. 氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理[J]. 化工学报, 2013, 64(2): 616-623.

References 28

[1]	IPCC. Climate change 2007:the physical science basis.Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change.Cambridge:C.U.Press, 2007
[2]	Drage T C, Snape C E, Stevens L A, Wood J, Wang J W, Cooper A I, Dawson R, Guo X, Satterley C,Irons R.Materials challenges for the development of solid sorbents for post-combustion carbon capture[J].Journal of Materials Chemistry, 2012, 22(7):2815-2823
[3]	Fei Weiyang(费维扬), Ai Ning(艾宁),Chen Jian(陈健).Capture and separation of greenhouse gases CO2—the challenge and opportunity for separation technology[J].Chemical Industry and Engineering Progress(化工进展), 2005, 24(1):1-4
[4]	Choi S, Drese J H,Jones C W.Adsorbent materials for carbon dioxide capture from large anthropogenic point sources[J].Chem.Sus.Chem., 2009, 2(9):796-854
[5]	Wang Q, Luo J, Zhong Z,Borgna A.CO2 capture by solid adsorbents and their applications:current status and new trends[J].Energy & Environmental Science, 2011, 4(1):42-55
[6]	Forano C, Hibino T, Lexoux F,Taviot-Gueho C.Layered double hydroxides//Bergaya F, Theng B K G,Lagaly G.Handbook of Clay Science[M].Oxford:Elsevier Science, 2006:1021-1095
[7]	Wang J, Stevens L A, Drage T C, Snape C E,Wood J. Preparation and CO2 adsorption of amine modified layered double hydroxide via anionic surfactant-mediated route[J].Chemical Engineering Journal, 2012, 181/182:267-275
[8]	Wang J, Stevens L A, Drage T C,Wood J.Preparation and CO2 adsorption of amine modified Mg-Al LDH via exfoliation route[J].Chemical Engineering Science, 2012, 68(1):424-431
[9]	Aschenbrenner O, McGuire P, Alsamaq S, Wang J, Supasitmongkol S, Al-Duri B, Styring P,Wood J. Adsorption of carbon dioxide on hydrotalcite-like compounds of different compositions[J].Chemical Engineering Research and Design, 2011, 89(9):1711-1721
[10]	Knoefel C, Descarpentries J, Benzaouia A, Zelenak V, Mornet S, Llewellyn P L,Hornebecq V.Functionalised micro-/mesoporous silica for the adsorption of carbon dioxide[J].Microporous and Mesoporous Materials, 2007, 99(1/2):79-85
[11]	Harlick P J E,Sayari A.Applications of pore-expanded mesoporous silicas(3):Triamine silane grafting for enhanced CO2 adsorption[J].Industrial & Engineering Chemistry Research, 2006, 45(9):3248-3255
[12]	Chuayplod P,Trakarnpruk W.Transesterification of rice bran oil with methanol catalyzed by Mg(Al)La hydrotalcites and metal/MgAl oxides[J].Industrial & Engineering Chemistry Research, 2009, 48(9):4177-4183
[13]	Xu Z, Liu Q,Finch J A.Silanation of stability of 3-aminopropyl triethoxy silane on nanosized superparamagnetic particles(Ⅰ):Direct silanation[J].Applied Surface Science, 1997, 120:269-278
[14]	Wypych F, Bail A, Halma M,Nakagaki S.Immobilization of iron(Ⅲ)porphyrins on exfoliated MgAl layered double hydroxide, grafted with(3-aminopropyl)triethoxysilane[J].Journal of Catalysis, 2005, 234(2):431-437
[15]	White L D,Tripp C P.Reaction of(3-aminopropyl)dimethylethoxysilane with amine catalysts on silica surfaces[J].Journal of Colloid and Interface Science, 2000, 232:400-407
[16]	Dobson K D, Roddick-Lanzilotta A D,McQuillan A J.An in situ infrared spectroscopic investigation of adsorption of sodium dodecylsulfate and of etyltrimethylammonium bromide surfactants to TiO2, ZrO2, Al2O3, and Ta2O5 particle films from aqueous solutions[J].Vibrational Spectroscopy, 2000, 24:287-295
[17]	Crepaldi E L, Pavan P C, Tronto J,Valim J B.Chemical, structural, and thermal properties of Zn(Ⅱ)-Cr(Ⅲ)layered double hydroxides intercalated with sulfated and sulfonated surfactants[J].Journal of Colloid and Interface Science, 2002, 248(2):429-442
[18]	da Fonseca M G, Silva C R,Airoldi C.Aminated phyllosilicates synthesized via a sol-gel process[J].Langmuir, 1999, 15:5048-5055
[19]	Kulikova G A,Parfenyuk E V.Surface properties of modified nanosized silica and their influence on human serum albumin immobilization[J].Protection of Metals and Physical Chemistry of Surfaces, 2010, 46(5):546-549
[20]	Romero A A, Alba M D, Zhou W,Klinowski J.Synthesis and characterization of the mesoporous silicate molecular sieve MCM-48[J].Journal of Physical Chemistry B, 1997, 101:5294-5300
[21]	Tao Q, He H, Frost R L, Yuan P,Zhu J.Nanomaterials based upon silylated layered double hydroxides[J].Applied Surface Science, 2009, 255(7):4334-4340
[22]	Gupta H,Fan L S.Carbonation-calcination cycle using high reactivity calcium oxide for carbon dioxide separation from flue gas[J].Industrial & Engineering Chemistry Research, 2002, 41(16):4035-4042
[23]	Drage T C, Arenillas A, Smith K M,Snape C E.Thermal stability of polyethylenimine based carbon dioxide adsorbents and its influence on selection of regeneration strategies[J].Microporous and Mesoporous Materials, 2008, 116(1/2/3):504-512
[24]	Bacsik Z, Ahlsten N, Ziadi A, Zhao G, Garcia-Bennett A E, Martín-Matute B,Hedin N.Mechanisms and kinetics for sorption of CO2 on bicontinuous mesoporous silica modified with n-propylamine[J].Langmuir, 2011, 27(17):11118-11128
[25]	Knofel C, Martin C, Hornebecq V,Llewellyn P L.Study of carbon dioxide adsorption on mesoporous aminopropylsilane-functionalized silica and titania combining microcalorimetry and in situ infrared spectroscopy[J].Journal of Physical Chemistry C, 2009, 113(52):21726-21734
[26]	Chang A C C, Chuang S S C, Gray M,Soong Y.In-situ infrared study of CO2 adsorption on SBA-15 grafted with 3-(aminopropyl)triethoxysilane[J].Energy and Fuels, 2003, 17(2):468-473
[27]	Khatri R A, Chuang S S C, Soong Y,Gray M.Carbon dioxide capture by diamine-grafted SBA-15:a combined Fourier transform infrared and mass spectrometry study[J].Industrial & Engineering Chemistry Research, 2005, 44(10):3702-3708
[28]	Wang X, Schwartz V, Clark J C, Ma X, Overbury S H, Xu X,Song C.Infrared study of CO2 sorption over "molecular basket" sorbent consisting of polyethylenimine-modified mesoporous molecular sieve[J].Journal of Physical Chemistry C, 2009, 113(17):7260-7268

Preparation of amine modified layered double hydroxide and its adsorption mechanism for CO₂

氨基改性层状双氢氧化物的制备及其二氧化碳吸附机理

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References 28

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yifei ZHANG, Fangchen LIU, Shuangxing ZHANG, Wenjing DU. Performance analysis of printed circuit heat exchanger for supercritical carbon dioxide [J]. CIESC Journal, 2023, 74(S1): 183-190.
[2]	Ruitao SONG, Pai WANG, Yunpeng WANG, Minxia LI, Chaobin DANG, Zhenguo CHEN, Huan TONG, Jiaqi ZHOU. Numerical simulation of flow boiling heat transfer in pipe arrays of carbon dioxide direct evaporation ice field [J]. CIESC Journal, 2023, 74(S1): 96-103.
[3]	Zehao MI, Er HUA. DFT and COSMO-RS theoretical analysis of SO₂ absorption by polyamines type ionic liquids [J]. CIESC Journal, 2023, 74(9): 3681-3696.
[4]	Yepin CHENG, Daqing HU, Yisha XU, Huayan LIU, Hanfeng LU, Guokai CUI. Application of ionic liquid-based deep eutectic solvents for CO₂ conversion [J]. CIESC Journal, 2023, 74(9): 3640-3653.
[5]	Bingchun SHENG, Jianguo YU, Sen LIN. Study on lithium resource separation from underground brine with high concentration of sodium by aluminum-based lithium adsorbent [J]. CIESC Journal, 2023, 74(8): 3375-3385.
[6]	Ruihang ZHANG, Pan CAO, Feng YANG, Kun LI, Peng XIAO, Chun DENG, Bei LIU, Changyu SUN, Guangjin CHEN. Analysis of key parameters affecting product purity of natural gas ethane recovery process via ZIF-8 nanofluid [J]. CIESC Journal, 2023, 74(8): 3386-3393.
[7]	Rui HONG, Baoqiang YUAN, Wenjing DU. Analysis on mechanism of heat transfer deterioration of supercritical carbon dioxide in vertical upward tube [J]. CIESC Journal, 2023, 74(8): 3309-3319.
[8]	Yan GAO, Peng WU, Chao SHANG, Zejun HU, Xiaodong CHEN. Preparation of magnetic agarose microspheres based on a two-fluid nozzle and their protein adsorption properties [J]. CIESC Journal, 2023, 74(8): 3457-3471.
[9]	Ji CHEN, Ze HONG, Zhao LEI, Qiang LING, Zhigang ZHAO, Chenhui PENG, Ping CUI. Study on coke dissolution loss reaction and its mechanism based on molecular dynamics simulations [J]. CIESC Journal, 2023, 74(7): 2935-2946.
[10]	Qiyu ZHANG, Lijun GAO, Yuhang SU, Xiaobo MA, Yicheng WANG, Yating ZHANG, Chao HU. Recent advances in carbon-based catalysts for electrochemical reduction of carbon dioxide [J]. CIESC Journal, 2023, 74(7): 2753-2772.
[11]	Jie WANG, Xiaolin QIU, Ye ZHAO, Xinyang LIU, Zhongqiang HAN, Yong XU, Wenhan JIANG. Preparation and properties of polyelectrolyte electrostatic deposition modified PHBV antioxidant films [J]. CIESC Journal, 2023, 74(7): 3068-3078.
[12]	Caihong LIN, Li WANG, Yu WU, Peng LIU, Jiangfeng YANG, Jinping LI. Effect of alkali cations in zeolites on adsorption and separation of CO₂/N₂O [J]. CIESC Journal, 2023, 74(5): 2013-2021.
[13]	Chenxin LI, Yanqiu PAN, Liu HE, Yabin NIU, Lu YU. Carbon membrane model based on carbon microcrystal structure and its gas separation simulation [J]. CIESC Journal, 2023, 74(5): 2057-2066.
[14]	Chenxi LI, Yongfeng LIU, Lu ZHANG, Haifeng LIU, Jin’ou SONG, Xu HE. Quantum chemical analysis of n-heptane combustion mechanism under O₂/CO₂ atmosphere [J]. CIESC Journal, 2023, 74(5): 2157-2169.
[15]	Shaoyun CHEN, Dong XU, Long CHEN, Yu ZHANG, Yuanfang ZHANG, Qingliang YOU, Chenglong HU, Jian CHEN. Preparation and adsorption properties of monolayer polyaniline microsphere arrays [J]. CIESC Journal, 2023, 74(5): 2228-2238.