Ammonium removal by struvite precipitation with cheap magnesia

doi:10.11949/j.issn.0438-1157.20150857

CIESC Journal ›› 2015, Vol. 66 ›› Issue (12): 5040-5044.DOI: 10.11949/j.issn.0438-1157.20150857

Previous Articles Next Articles

Ammonium removal by struvite precipitation with cheap magnesia

YU Rongtai¹, HUANG Ping¹, REN Hongqiang², XIE Zhipeng³, WANG Chang'an³, MA Xiang¹

1 School of Materials Science and Engineering, Jingdezhen Ceramic College, Jingdezhen 333001, Jiangxi, China;
2 State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, Jiangsu, China;
3 School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

Received:2015-06-08 Revised:2015-07-03 Online:2015-12-05 Published:2015-12-05
Supported by:
supported by the National Natural Science Foundation of China (51178216).

廉价氧化镁回收废水中氨氮

余荣台¹, 黄平¹, 任洪强², 谢志鹏³, 汪长安³, 马湘¹

1 景德镇陶瓷学院材料科学与工程学院, 江西景德镇 333001;
2 南京大学污染控制与资源化研究国家重点实验室, 江苏南京 210023;
3 清华大学材料学院, 北京 100084

通讯作者: 余荣台
基金资助:
国家自然科学基金项目(51178216)。

Abstract

Abstract:

The high cost of magnesium is one of the key problems for the practical application of struvite chemical precipitation. Ammonium in wastewater was recycled by changing the initial conditions of struvite precipitation with cheap magnesia. The results showed that when the initial pH was 2, the removal rate of ammonium was above 90% by struvite precipitation technology with cheap magnesia as magnesium, which was above 82% at the conditions of the mole ratio of Mg²⁺:NH₄⁺:PO₄^3-, 1:1:1 and calcination temperature of magnesia of 200-400℃. The XRD and FTIR results also showed that the crystal structure of magnesia was distorted with changed bond length of Mg O at different calcination temperature, leading to redshift and blueshift. A direct correlation was found between Mg O bond length and ammonium removal ratio.

Key words: cheap magnesia, struvite, chemical processes, recovery, wastewater

摘要：

药剂成本过高是阻碍磷酸铵镁结晶技术推广应用的关键难题之一。通过改变结晶反应的初始条件,采用廉价氧化镁为镁盐,有效回收废水中的氨氮。研究结果表明,起始pH为2时,氧化镁为镁盐时,废水氨氮去除效率达到90%以上;采用Mg²⁺:NH₄⁺:PO₄^3- 摩尔比为1:1:1,煅烧温度在200～400℃时,氨氮回收率超过82%;XRD和FTIR分析结果表明,不同温度条件下,氧化镁的晶体结构出现畸变,导致Mg O键键长出现变化,红外光谱出现红移及蓝移现象,而Mg O键键长的变化与沉氨效率存在直接的相关性。

关键词: 廉价氧化镁, 磷酸铵镁, 化学过程, 回收, 废水

CLC Number:

X703

YU Rongtai, HUANG Ping, REN Hongqiang, XIE Zhipeng, WANG Chang'an, MA Xiang. Ammonium removal by struvite precipitation with cheap magnesia[J]. CIESC Journal, 2015, 66(12): 5040-5044.

余荣台, 黄平, 任洪强, 谢志鹏, 汪长安, 马湘. 廉价氧化镁回收废水中氨氮[J]. 化工学报, 2015, 66(12): 5040-5044.

References 20

	[
[1]	] Yu Rongtai, Ren Hongqiang, Wang Yanru, Ding Lili, Geng Jinju, Xu Ke, Zhang Yan. Ammonium removal from wastewater via struvite pyrolysate recycling with Mg(OH)2 addition [J]. Water Sci. Technol., 2013, 68: 2661-2667.
[2]	Cusick R D, Ullery M L, Dempsey B A, Logan B E. Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial electrolysis cell [J]. Water Research, 2014, 54 (1): 297-306.
[3]	Rahaman M S, Mavinic D S, Meikleham A, Ellis N. Modeling phosphorus removal and recovery from anaerobic digester supernatant through struvite crystallization in a fluidized bed reactor [J]. Water Research, 2014, 51 (15): 1-10.
[4]	Ariyanto E, Sen T K, Ang H M. The influence of various physico-chemical process parameters on kinetics and growth mechanism of struvite crystallization [J]. Advanced Powder Technology, 2014, 25 (2): 682-694.
[5]	Yu R T, Geng J J, Ren H Q, Wang Y R, Xu K. Combination of struvite pyrolysate recycling with mixed-base technology for removing ammonium from fertilizer wastewater [J]. Bioresour. Techlol., 2012, 124: 292-298.
[6]	Stratful I, Scrimshaw M D, Lester J N C. Conditins influencing the precipitation of magnesium ammonium phosphate [J]. Water Research, 2001, 35 (17): 4191-4199.
[7]	Jaffer Y, Clark T A, Pearce P, Parsons S A. Potential phosphorus recovery by struvite formation [J]. Water Research, 2002, 36 (7): 1834-1842.
[8]	Corre K S L, Valsami-Jones E, Hobbs P, Parsons S A. Impact of calcium on struvite crystal size, shape and purity [J]. Journal of Crystal Growth, 2005, 283 (3/4): 514-522.
[9]	Johnston A E, Richards I R. Effectiveness of different precipitated phosphates as phosphorus sources for plants [J]. Soil Use and Management, 2003, 19 (1): 45-49.
[10]	Shu L, Schneider P, Jegatheesan V, Johnson J. An economic evaluation of phosphorus recovery as struvite from digester supernatant [J]. Bioresource Technology, 2006, 97(17): 2211-2216.
[11]	Huang H M, Xu C L, Zhang W. Removal of nutrients from piggery wastewater using struvite precipitation and pryogenation technology [J]. Bioresource Technology, 2011, 102 (3): 2523-2528.
[12]	Huang H M, Yang J, Li D. Recovery and removal of ammonia-nitrogen and phosphate from swine wastewater by internal recycling of struvite chlorination product [J]. Bioresource Technology, 2014, 172: 253- 259.
[13]	Gunay A, Karadag D, Tosun I, Ozturk M. Use of magnesit as a magnesium source for ammonium removal from leachate [J]. Journal of Hazardous Materials, 2008, 156 (1/2/3): 619-623.
[14]	Ozturk I, Altinbas M, Koyuncu I, Arikan O, Gomec-Yangin C. Advanced physic-chemical treatment experiences on young municipal landfill leachates [J]. Waste Mangement, 2003, 23 (5): 441-446.
[15]	Romero-Güiza M S, Astals S, Mata-Alvarez J, Chimenos J M. Feasibility of coupling anaerobic digestion and struvite precipitation in the reactor: evaluation of different magnesium sources [J]. Chemical Engineering Journal, 2015, 270 (15): 542-548.
[16]	Huang Haiming, Chen Yongqian, Jiang Yang, Ding Li. Treatment of swine wastewater combined with MgO-saponification wastewater by struvite precipitation technology [J]. Chemical Engineering Journal, 2014, 254 (15): 418-425.
[17]	Stolzenburg P, Capdevielle A, Teychené S, Biscans B. Struvite precipitation with MgO as a precursor: application to wastewater treatment [J]. Chemical Engineering Journal, 2015, 133 (8): 9-15.
[18]	Yu Rongtai, Geng Jinju, Ren Hongqiang, Wang Yanru, Xu Ke. Struvite pyrolysate recycling combined with dry pyrolysis for ammonium removal from wastewater [J]. Bioresour. Technol., 2013, 132: 154-159.
[19]	Liu Guoliang(刘国良), Zhu Yimin(朱一民), Fang Xin(房鑫), Zhang Weijia(张维佳). Preparation of MgO with different nanoparticle sizes and their infrared wave absorptivities [J]. Journal of Northeastern University: Natural Science (东北大学学报: 自然科学版), 2010, 31 (8): 1192-1195.
[20]	Wang Xiaoyu(王小宇). Preparation of nano-MgO and investigation of its infrared absorption propertie [D]. Shenyang: Northeastern University, 2009.

Related Articles 15

[1]	Congqi HUANG, Yimei WU, Jianye CHEN, Shuangquan SHAO. Simulation study of thermal management system of alkaline water electrolysis device for hydrogen production [J]. CIESC Journal, 2023, 74(S1): 320-328.
[2]	Jiayi ZHANG, Jiali HE, Jiangpeng XIE, Jian WANG, Yu ZHAO, Dongqiang ZHANG. Research progress of pervaporation technology for N-methylpyrrolidone recovery in lithium battery production [J]. CIESC Journal, 2023, 74(8): 3203-3215.
[3]	Ruihang ZHANG, Pan CAO, Feng YANG, Kun LI, Peng XIAO, Chun DENG, Bei LIU, Changyu SUN, Guangjin CHEN. Analysis of key parameters affecting product purity of natural gas ethane recovery process via ZIF-8 nanofluid [J]. CIESC Journal, 2023, 74(8): 3386-3393.
[4]	Weiming SHAO, Wenxue HAN, Wei SONG, Yong YANG, Can CHEN, Dongya ZHAO. Dynamic soft sensor modeling method based on distributed Bayesian hidden Markov regression [J]. CIESC Journal, 2023, 74(6): 2495-2502.
[5]	Jianhua ZHANG, Mengmeng CHEN, Yawen SUN, Yongzhen PENG. Efficient nitrogen and phosphorus removal from domestic wastewater via simultaneous partial nitritation and phosphorus removal combined Anammox [J]. CIESC Journal, 2023, 74(5): 2147-2156.
[6]	Lanhe ZHANG, Qingyi LAI, Tiezheng WANG, Xiaozhuo GUAN, Mingshuang ZHANG, Xin CHENG, Xiaohui XU, Yanping JIA. Effect of H₂O₂ on nitrogen removal and sludge properties in SBR [J]. CIESC Journal, 2023, 74(5): 2186-2196.
[7]	Cheng YUN, Qianlin WANG, Feng CHEN, Xin ZHANG, Zhan DOU, Tingjun YAN. Deep-mining risk evolution path of chemical processes based on community structure [J]. CIESC Journal, 2023, 74(4): 1639-1650.
[8]	Ruizhe CHEN, Leilei CHENG, Jing GU, Haoran YUAN, Yong CHEN. Research progress in chemical recovery technology of fiber-reinforced polymer composites [J]. CIESC Journal, 2023, 74(3): 981-994.
[9]	Yue HU, Shoujun MA, Xigao JIAN, Zhihuan WENG. Study on curing phthalonitrile resin with novel poly(phthalazinone ether nitrile) [J]. CIESC Journal, 2023, 74(2): 871-882.
[10]	Wan XU, Zhenbin CHEN, Huijuan ZHANG, Fangfang NIU, Ting HUO, Xingsheng LIU. Study on synthesis, adsorption and desorption performance of linear temperature-sensitive segment polymer regulated intelligent $R e O 4 -$ ion-imprinted polymer [J]. CIESC Journal, 2023, 74(2): 941-952.
[11]	Chengwei LI, Huayong LUO, Mingxuan ZHANG, Peng LIAO, Qian FANG, Hongwei RONG, Jingyin WANG. Microfludically-generated lanthanum hydroxide cross-linked chitosan microspheres for phosphate removal [J]. CIESC Journal, 2022, 73(9): 3929-3939.
[12]	Yujun MA, Xiangjun LIU. Theoretical studies of water recovery from flue gas by using ceramic membrane [J]. CIESC Journal, 2022, 73(9): 4103-4112.
[13]	Caifeng LI, Xiao WANG, Gangjian LI, Junzhang LIN, Weidong WANG, Qinglin SHU, Yanbin CAO, Meng XIAO. Synergistic relationship between hydrocarbon degrading and emulsifying strain SL-1 and endogenous bacteria during oil displacement [J]. CIESC Journal, 2022, 73(9): 4095-4102.
[14]	Xinyi LUO, Chao FENG, Jing LIU, Yu QIAO. Phosphorus recovery from products of sewage sludge via different thermal treatment processes [J]. CIESC Journal, 2022, 73(9): 4034-4044.
[15]	Xingang QI, Libo LU, Yunan CHEN, Zhiwei GE, Liejin GUO. Review of black liquor supercritical water gasification for hydrogen production with high value-added chemicals recovery [J]. CIESC Journal, 2022, 73(8): 3338-3354.

Ammonium removal by struvite precipitation with cheap magnesia

廉价氧化镁回收废水中氨氮

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References 20

Related Articles 15

Recommended Articles

Metrics

Comments