Correlations between alcohol content or solubilization parameter and equivalent alkane carbon number of oil mixtures for optimum middle phase microemulsions

doi:10.11949/j.issn.0438-1157.20151150

CIESC Journal ›› 2016, Vol. 67 ›› Issue (4): 1399-1404.DOI: 10.11949/j.issn.0438-1157.20151150

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Correlations between alcohol content or solubilization parameter and equivalent alkane carbon number of oil mixtures for optimum middle phase microemulsions

WU Zhanghui, MA Yanbing, LIU Hui'e, CHEN Shuang, DING Chuanqin, QI Xuanliang

State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266580, Shandong, China

Received:2015-07-17 Revised:2015-11-18 Online:2016-04-05 Published:2016-04-05
Supported by:
supported by the National Natural Science Foundation of China(21106187), the Promotive Research Funds for Excellent Young and Middle-aged Scientists of Shandong Province(BS2011NJ021), the Fundamental Research Funds for the Central Universities(14CX05031A) and the Project of Huangdao District (2014-1-49).

微乳液最佳中相醇用量和增溶能力与油相等效烷基碳数的定量关系

吴章辉, 马雁冰, 刘会娥, 陈爽, 丁传芹, 齐选良

中国石油大学(华东)重质油国家重点实验室, 山东青岛 266580

通讯作者: 刘会娥
基金资助:
国家自然科学基金青年基金项目(21106187);山东省优秀中青年科学家奖励基金项目(BS2011NJ021);中央高校基本科研业务费专项资金项目(14CX05031A);黄岛区科技项目(2014-1-49)。

Abstract

Abstract:

The solubilization behavior of mixed oils was examined using two kinds of surfactants, octadecyl trimethyl ammonium chloride (OTAC) and sodium dodecyl sulfate (SDS). Equivalent alkyl carbon number (EACN) was adjusted through mixing of different kinds of hydrocarbons, including two-component and four-component hydrocarbons. Both of the relations between EACN and the optimum dosage of alcohol (A*) and the relations between EACN and optimal solubilization parameter (SP*) were investigated. It was found that for both of the two kinds of surfactants used in this study, the A* vs EACN and the SP* vs EACN relations fit quadratic functions. For a certain surfactant under constant condition, the quadratic functions were the same no matter what kinds of hydrocarbons were used.

Key words: microemulsions, alcohol, alkane, mixtures, EACN

摘要：

主要考察了十八烷基三甲基氯化铵(OTAC)和十二烷基硫酸钠(SDS)对油相的增溶规律。通过不同烃类混合,包括两种烃类的混合和4种烃类混合,调整混合油相的等效烷基碳数(EACN),探索最佳中相醇用量(A*)、最佳增溶量(SP*)与EACN的关系。A*、SP*与EACN在两类表面活性剂条件下都呈现二次函数的关系,且在同一表面活性剂体系中,控制其他组分含量恒定的情况下,函数关系与所用的烃无关。

关键词: 微乳液, 醇, 烷烃, 混合物, 等效烷基碳数

CLC Number:

O648.23

WU Zhanghui, MA Yanbing, LIU Hui'e, CHEN Shuang, DING Chuanqin, QI Xuanliang. Correlations between alcohol content or solubilization parameter and equivalent alkane carbon number of oil mixtures for optimum middle phase microemulsions[J]. CIESC Journal, 2016, 67(4): 1399-1404.

吴章辉, 马雁冰, 刘会娥, 陈爽, 丁传芹, 齐选良. 微乳液最佳中相醇用量和增溶能力与油相等效烷基碳数的定量关系[J]. 化工学报, 2016, 67(4): 1399-1404.

References 22

[1]	SCHULMAN J H, STOECKENIUS W, PRINCE L M. Mechanism of formation and structure of micro emulsions by electron microscopy[J]. Journal of Physical Chemistry, 1959, 63: 1677-1680.
[2]	秦娟, 辛寅昌, 马德华. 微乳液的油水分离和机理探讨及应用[J]. 化工学报, 2013, 64(5): 1797-1802. QIN J, XIN Y C, MA D H. Separation mechanism and application of oil-water microemulsion[J]. CIESC Journal, 2013, 64(5): 1797-1802.
[3]	OGINO K, ABE M. Microemulsion formation with some typical surfactant[J]. Surface and Colloid Science, 1993, 15: 85-123
[4]	袁迎, 刘会娥, 徐明明, 等. 十二烷基苯磺酸钠微乳液体系中无机盐的作用规律[J]. 化工学报, 2014, 65(10): 4025-4031. YUAN Y, LIU H E, XU M M, et al. Influence of inorganic salts on sodium dodecyl benzene sulfonate microemulsion system[J]. CIESC Journal, 2014, 65(10): 4025-4031.
[5]	穆国庆, 靖建歌, 刘会娥, 等. SDS-正戊醇与SDS-正丁醇微乳体系相行为模拟[J]. 化学研究与应用, 2015, (2): 122-126. MU G Q, JING J G, LIU H E, et al. Simulation on phase behavior of SDS-pentanol and SDS-butanol microemulsion[J]. Chemical Research and Application, 2015, (2): 122-126.
[6]	王军, 杨许召.乳化与微乳化技术[M].第2版.北京:化学工业出版社, 2012: 33-34 WANG J, YANG X Z. Emulsion and Microemulsion Technology[M]. 2nd ed. Beijing: Chemical Industry Press, 2012: 33-34
[7]	吴章辉, 穆国庆, 刘会娥, 等. 鱼状相图研究不同无机盐对微乳液的影响[J]. 化学研究与应用, 2015, 10: 1564-1568. WU Z H,MU G Q, LIU H E, et al. Study on the influence of different types of inorganic salts on microemulsion system using fishlike phase diagram[J]. Chemical Research and Application, 2015, 10: 1564-1568.
[8]	LIU H E, ZHANG X K, DING C Q, et al. Phase behavior of sodium dodecyl sulfate n-butanol-kerosene-water microemulsion system[J]. Chinese Journal of Chemical Engineering, 2014, 22(6): 699-705
[9]	夏雪, 刘会娥, 丁传芹, 等. 酸碱性对十二烷基硫酸钠-正丁醇-煤油-水微乳液体系的影响[J]. 石油化工, 2011, 40(10): 1110-1114. XIA X, LIU H E, DING C Q, et al.Influence of acidity and alkalinity on sodium dodecyl sulfate-n-butanol-kerosene-water microemulsion system[J]. Petrochemical Technology, 2011, 40(10): 1110-1114.
[10]	夏雪, 刘会娥, 夏晔, 等. SDS/正丁醇/煤油/水微乳液体系的相转变研究[J]. 高校化学工程学报, 2011, 25(6): 911-915. XIA X, LIU H E, XIA Y, et al. Phase inversion of sodium dodecyl sulfate (SDS)/n-butanol/kerosene/water microemulsion system[J]. Journal of Chemical Engineering of Chinese Universities, 2011, 25(6): 911-915
[11]	SCHECHTER R S, BOURREL M. Microemulsions and related systems: formulation, solvency, and physical properties//Surfactant Science Series[M]. New York: Marce Dekker Inc., 1988
[12]	TANTHAKIT P, CHAVADEJ S, SCAMEHORN J F, et al. Microemulsion formation and detergency with oily soil(Ⅳ): Effect of rinse cycle design[J]. Journal of Surfactants and Detergents, 2008, 11(2): 117-128
[13]	TONGCUMPOU C, ACOSTA E J, Quencer L B, et al. Microemulsion formation and detergency with oily soils(Ⅰ): Phase behavior and interfacial tension[J]. Journal of Surfactants and Detergents, 2003, 6(3): 191-203
[14]	陈中元, 鲁长波, 谷晓昱. 醇对柴油微乳液组成及热力学参数的影响[J]. 石油学报(石油加工), 2011, 27(3): 424-428. CHEN Z Y, LU C B, GU X Y. Effects of alcohol on the composition and thermodynamic properties of diesel oil microemulsion[J]. Acta Petrolei Sinica(Petroleum Processing Section), 2011, 27(3): 424-428.
[15]	MIYATA I, MIYAMOTO H, YONESE M. Effect of chain lengths of n-alcohol on the formation of single-phase microemulsions in n-heptane/n-alcohol/sodium dodecyl sulfate/water systems[J]. Chemical & Pharmaceutical Bulletin, 1996, 44: 1049-1055.
[16]	陈中元, 谷晓昱. 助表面活性剂醇对柴油微乳液的影响[J]. 石油化工, 2010, 39(4): 396-400. CHEN Z Y, GU X Y. Effect of cosurfactant-alkanol on diesel oil microemulsion[J]. Petrochemical Technology, 2010, 39(4): 396-400.
[17]	SALAGER J L, MORGAN J C, SCHECHTER R S, et al. Optimum formulation of surfactant/water/oil systems for minimum interfacial tension or phase behavior[J]. Society of Petroleum Engineers Journal, 1979, 19(2): 107-115.
[18]	SALAGER J L, MALDONADO L I, MINANA P M, et al. surfactant-oil-water systems near the affinity inversion(Ⅰ): Relationship between equilibrium phase behavior and emulsion type and stability[J]. Journal of Dispersion Science & Technology, 1982, 3(3): 279-292.
[19]	CASH L, CAYIAS J L, FOURNIER G, et al. The application of low interfacial tension scaling rules to binary hydrocarbon mixtures[J]. Journal of Colloid & Interface Science, 1977, 59: 39-44.
[20]	CAYIAS J L, SCHECHTER R S, WADE W H. Modeling crude oils for low interfacial tension[J]. Society of Petroleum Engineers Journal, 1976, 16(6): 351-357.
[21]	WADE W H, MORGAN J C, JACOBSON J K, et al. Low interfacial tensions involving mixtures of surfactants[J]. Society of Petroleum Engineers Journal, 1977, 17(2): 122-128.
[22]	BOUTON F, DURAND M, NARDELLO-RATAJ V, et al. A QSPR model for the prediction of the "fish-tail" temperature of CiE4/water/polar hydrocarbon oil systems[J]. Langmuir, 2010, 26(11): 7962-7970.

Correlations between alcohol content or solubilization parameter and equivalent alkane carbon number of oil mixtures for optimum middle phase microemulsions

微乳液最佳中相醇用量和增溶能力与油相等效烷基碳数的定量关系

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