CIESC Journal ›› 2016, Vol. 67 ›› Issue (8): 3415-3421.DOI: 10.11949/j.issn.0438-1157.20160200

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FCC reaction performance using β zeolite catalysts synthesized by various methods

PANG Xinmei, LIU Qiwu, WANG Xiaohua, CUI Yan, XING Xin, GUO Chengyu, WANG Qian, LI Zhaofei, LI Fayong   

  1. Petrochemical Research Institute of PetroChina, Beijing 102206, China
  • Received:2016-02-23 Revised:2016-06-06 Online:2016-08-05 Published:2016-08-05
  • Supported by:

    supported by the National Basic Research Program of China (2012CB215001) and the Major Science and Technology Projects of PetroChina (2010E-1908).

不同方法合成β沸石的FCC反应性能

庞新梅, 刘其武, 王晓化, 崔岩, 邢昕, 郭成玉, 王骞, 李兆飞, 李发永   

  1. 中国石油石油化工研究院, 北京 102206
  • 通讯作者: 庞新梅
  • 基金资助:

    国家重点基础研究发展计划项目(2012CB215001);中国石油天然气股份有限公司重大科技专项(2010E-1908)。

Abstract:

β zeolites synthesized by various methods were used to study the FCC (fluid catalytic cracking) reactions and to explore the impact of silicon/aluminum ratio in β zeolites on FCC product distributions. Compared to high silicon-containing ZSM-5 zeolites, β zeolites in FCC increased both octane number and yield of gasoline. Also, β zeolite showed a stronger functionality of isomerization with enhanced yields of iso-butane and olefin isomers (or tert-olefins)in light gasoline, which enriched raw material resources for alkylation and etherification processes.

Key words: zeolite, catalyst, petroleum, catalytic cracking

摘要:

报道了不同方法合成β沸石的FCC反应性能,并考察了β沸石的硅铝比对FCC反应产品分布的影响。结果表明:β沸石应用于FCC,与高硅ZSM-5相比,具有提高汽油产率及辛烷值的功能;另外β沸石较高硅ZSM-5表现出更强的异构化功能,具有提高异丁烷和轻汽油异构烯烃(或叔碳烯烃)产率的作用,可丰富烷基化技术和醚化技术的原料来源。

关键词: 沸石, 催化剂, 石油, 催化裂化

CLC Number: