Research progress on modification strategy of g-C3N4 and g-C3N4/Ti3C2 heterojunction

doi:10.11949/0438-1157.20200550

Abstract

Abstract:

Graphite phase carbon nitride (g-C₃N₄) is a kind of metal-free semiconductor material with a forbidden band width of about 2.7 eV and has visible light response capability. Attributed to its good thermal and chemical stability, adjustable morphology and chemical structure, it is widely used in the field of photocatalysis. However, due to its low specific surface area and wide band gap, its response range to visible light is narrow and the recombination rate of photogenerated carriers is high, resulting in a low photocatalytic efficiency, which can be effectively improved by modification. The two-dimensional material Ti₃C₂ has a narrower band gap compared with other semiconductor materials, and the heterogeneous junction between Ti₃C₂ and g-C₃N₄ is expected to obtain a wider range of visible light absorption and higher photocatalytic efficiency. This article reviews the modification methods of g-C₃N₄ including morphology control, doping and constructing heterojunctions, as well as the action mechanism, preparation methods and applications of g-C₃N₄/Ti₃C₂ heterojunction in photocatalytic hydrogen evolution, organics degradation and synthesis, etc.

Key words: modification, catalyze, composite material, activity, g-C₃N₄/Ti₃C₂

摘要：

石墨相氮化碳（g-C₃N₄）禁带宽度约为2.7 eV，具有可见光响应能力。由于其良好的热和化学稳定性，且形貌和化学结构可调，在光催化领域应用广泛。但由于其带隙宽，对可见光响应范围窄，且光生载流子的复合率高，导致其光催化效率低，可通过改性来改善。本文综述了对g-C₃N₄形貌调控、掺杂和构建异质结等改性策略，以及g-C₃N₄/Ti₃C₂异质结的作用机理、制备方法和在光催化析氢、有机物降解及合成等领域的应用。

关键词: 改性, 催化, 复合材料, 活性, g-C₃N₄/Ti₃C₂

CLC Number:

TQ 426.7

Danyang SUN, Tingting ZHAI, Hansheng LI, Wenfang LIU. Research progress on modification strategy of g-C₃N₄ and g-C₃N₄/Ti₃C₂ heterojunction[J]. CIESC Journal, 2020, 71(S2): 1-11.

孙丹阳, 翟婷婷, 黎汉生, 刘文芳. g-C₃N₄的改性策略以及g-C₃N₄/Ti₃C₂异质结研究进展[J]. 化工学报, 2020, 71(S2): 1-11.

Figures/Tables 6

References 81

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Research progress on modification strategy of g-C₃N₄ and g-C₃N₄/Ti₃C₂ heterojunction

g-C₃N₄的改性策略以及g-C₃N₄/Ti₃C₂异质结研究进展

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