化工学报 ›› 2021, Vol. 72 ›› Issue (7): 3445-3465.DOI: 10.11949/0438-1157.20210073
韩笑1(),陈雨亭1,苏宝根1,2,鲍宗必1,2,张治国1,2,杨亦文1,2,任其龙1,2,杨启炜1,2()
收稿日期:
2021-01-12
修回日期:
2021-04-20
出版日期:
2021-07-05
发布日期:
2021-07-05
通讯作者:
杨启炜
作者简介:
韩笑(1995—),女,硕士研究生,基金资助:
HAN Xiao1(),CHEN Yuting1,SU Baogen1,2,BAO Zongbi1,2,ZHANG Zhiguo1,2,YANG Yiwen1,2,REN Qilong1,2,YANG Qiwei1,2()
Received:
2021-01-12
Revised:
2021-04-20
Online:
2021-07-05
Published:
2021-07-05
Contact:
YANG Qiwei
摘要:
己烷异构体的高效分离是石化行业生产高辛烷值汽油的关键过程之一。己烷异构体分子的化学性质不活泼,极化率、沸点相近,分离极具挑战。目前,基于5A分子筛的吸附分离技术在工业上得到了广泛应用,但5A分子筛的吸附容量较低,且无法实现单支链异构体与双支链异构体的选择性分离,限制了汽油辛烷值的进一步提高。金属-有机框架材料等新型多孔材料的结构多样性和高度可设计性使其可以精准识别异构体分子在形状和性质上的微小差异,展现出良好的分离性能和应用前景。重点综述了金属-有机框架材料在己烷异构体分离中的研究进展,归纳了分离机理和影响因素,并对该领域中存在的问题和未来发展方向进行了探讨。
中图分类号:
韩笑,陈雨亭,苏宝根,鲍宗必,张治国,杨亦文,任其龙,杨启炜. 己烷异构体吸附分离材料研究进展[J]. 化工学报, 2021, 72(7): 3445-3465.
HAN Xiao,CHEN Yuting,SU Baogen,BAO Zongbi,ZHANG Zhiguo,YANG Yiwen,REN Qilong,YANG Qiwei. Advances in adsorbents for hexane isomers separation[J]. CIESC Journal, 2021, 72(7): 3445-3465.
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