生物油金属水热原位加氢提质技术研究进展

doi:10.11949/0438-1157.20201102

化工学报 ›› 2021, Vol. 72 ›› Issue (4): 1783-1795.DOI: 10.11949/0438-1157.20201102

生物油金属水热原位加氢提质技术研究进展

颜蓓蓓^1,²(),王建¹,刘彬³,陈冠益^4,⁵,程占军^1,²()

^1.天津大学环境科学与工程学院，天津 300350
^2.天津市生物质废物利用重点实验室，天津 300350
^3.天津大学青岛海洋技术研究院，山东青岛 266235
^4.天津商业大学，天津 300134
^5.天津大学佐治亚理工深圳学院筹备办公室，广东深圳 518071

收稿日期:2020-08-03 修回日期:2020-09-21 出版日期:2021-04-05 发布日期:2021-04-05
通讯作者: 程占军
作者简介:颜蓓蓓（1981—），女，博士，教授，yanbeibei@tju.edu.cn
基金资助:
深圳市科技计划项目(KQTD20180413181724653);天津接力项目(18YFJLCG00090)

Research progress of bio-oil metal hydrothermal in-situ hydrogenation technology

YAN Beibei^1,²(),WANG Jian¹,LIU Bin³,CHEN Guanyi^4,⁵,CHENG Zhanjun^1,²()

^1.School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
^2.Tianjin Key Laboratory of Biomass Wastes Utilization, Tianjin 300350, China
^3.Qingdao Institute for Ocean Engineering of Tianjin University, Qingdao 266235, Shandong, China
^4.Tianjin University of Commerce, Tianjin 300134, China
^5.Preparation Office of Georgia Tech Tianjin University Shenzhen Institute, Shenzhen 518071, Guangdong, China

Received:2020-08-03 Revised:2020-09-21 Online:2021-04-05 Published:2021-04-05
Contact: CHENG Zhanjun

摘要/Abstract

摘要：

水热液化技术可以将秸秆等木质纤维素类生物质转化为生物油，生物油提质可制备液体燃料和高附加值化学品。但生物油成分复杂，研发适宜的提质方法与工艺是当前的热点。金属水热原位加氢提质是一种新兴生物油提质技术，具有原料适应性广、成本低和效率高等优势，受到国内外广泛关注。本文从木质纤维素类生物质水热加氢提质原理、金属水热原位加氢最新研究进展及相关数值模拟方法三方面进行了综述，在此基础上指出目前该技术存在的主要问题，并指明未来研究方向。目前金属水热原位加氢提质过程活性氢和氢气作用机制尚不明晰；明确加氢催化剂与金属/金属氧化物的相互作用是制备高效加氢催化剂的关键；集总动力学和分子模拟等方法是金属水热原位加氢提质技术在理论计算领域未来的发展方向，有待进行深入研究。

关键词: 木质纤维素, 生物油, 水热液化, 金属水解, 原位加氢脱氧

Abstract:

Hydrothermal liquefaction technology can convert lignocellulosic biomass such as straws into bio-oil, and it can be upgraded to produce liquid fuels and high value-added chemicals. But it is accompanied by inherent drawbacks, such as high oxygen content and high viscosity. Thus, it is crucial to develop upgrading method which can be suitable for bio-oils with variable composition. In recent years, the facile method for bio-oil upgrading by zero-valent metals (Al, Fe, Mg and Zn) as an international burgeoning technology is proposed, that has superiority in material adaptability, cost and efficiency. In this paper, the principle, classification and research progress of in-situ hydrogenation of bio-oils by metal hydrolysis are systematically reviewed. Combined with the numerical simulation method, the main problems of in-situ hydrogenation of bio-oils by metal hydrolysis are analyzed and the research directions are proposed. The role of active hydrogen and hydrogen gas in bio-oil in-situ hydrodeoxygenation upgrading is still not clear. The successful cooperation of hydrogenation catalyst and metal/metallic oxide plays an important role in in-situ hydrodeoxygenation upgrading process. The mechanism of hydrothermal liquefaction and upgrading should be further investigated by theoretical calculations, such as lumping kinetics and molecular simulation.

Key words: lignocellulose, bio-oils, hydrothermal liquefaction, metal hydrolysis, in-situ hydrodeoxygenation

中图分类号:

TQ 028.8

颜蓓蓓, 王建, 刘彬, 陈冠益, 程占军. 生物油金属水热原位加氢提质技术研究进展[J]. 化工学报, 2021, 72(4): 1783-1795.

YAN Beibei, WANG Jian, LIU Bin, CHEN Guanyi, CHENG Zhanjun. Research progress of bio-oil metal hydrothermal in-situ hydrogenation technology[J]. CIESC Journal, 2021, 72(4): 1783-1795.

图/表 4

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生物油金属水热原位加氢提质技术研究进展

Research progress of bio-oil metal hydrothermal in-situ hydrogenation technology

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