稀土元素（RE： Nd、Sm、Eu、Er、Tm）修饰B-TiO2氧空位特性及其催化性能研究

doi:10.11949/0438-1157.20250182

化工学报 ›› 2025, Vol. 76 ›› Issue (10): 5162-5175.DOI: 10.11949/0438-1157.20250182

• 催化、动力学与反应器 • 上一篇下一篇

稀土元素（RE： Nd、Sm、Eu、Er、Tm）修饰B-TiO₂氧空位特性及其催化性能研究

王燕子¹(), 代佳楠¹^,², 马晶¹(), 张腾月¹, 梁子莉¹

^1.西安建筑科技大学化学与化工学院，陕西西安 710055
^2.西安建筑科技大学环境与市政工程学院，陕西西安 710055

收稿日期:2025-02-26 修回日期:2025-04-23 出版日期:2025-10-25 发布日期:2025-11-25
通讯作者: 马晶
作者简介:王燕子（1998—），女，硕士研究生，1139338723@qq.com
基金资助:
国家自然科学基金项目(62374130);陕西省秦创原 “科学家+工程师”队伍建设项目(2025QCY-KXJ-100);陕西省国际合作项目(2022KW-33);西安高校人才服务企业项目(23GXFW0044);陕西化学与生物基础科学研究项目(22JHQ014)

Oxygen vacancy characteristics and photocatalytic performance of rare earth elements (RE: Nd, Sm, Eu, Er, Tm) doped B-TiO₂

Yanzi WANG¹(), Jia’nan DAI¹^,², Jing MA¹(), Tengyue ZHANG¹, Zili LIANG¹

^1.School of Chemistry and Chemical Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, Shaanxi, China
^2.School of Environmental and Municipal Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, Shaanxi, China

Received:2025-02-26 Revised:2025-04-23 Online:2025-10-25 Published:2025-11-25
Contact: Jing MA

摘要/Abstract

摘要：

近年来，稀土元素改性二氧化钛（TiO₂）在环境催化领域展现出巨大潜力。采用溶剂热法制备了一系列稀土元素修饰的RE-B-TiO₂（RE：Nd、Sm、Eu、Er、Tm）纳米催化剂，并系统探究了其在可见光下降解盐酸四环素（TCH）的性能与机理。其中Er-B-TiO₂展现出最优的可见光催化性能。多尺度表征技术（XRD、TEM、XPS等）证实，Er-B-TiO₂由具有双晶面暴露特征的双锥体纳米单元自组装形成纳米棒结构，这种独特的晶体构型显著促进了光生载流子的空间分离效率。在可见光照射下，Er-B-TiO₂对TCH的降解效率在120 min内达到93.2%。深入研究表明，Er³⁺掺杂通过以下协同效应显著提升催化性能：（1）引入丰富的氧空位缺陷；（2）有效抑制光生电子-空穴复合；（3）通过4f能级调控将光响应范围扩展至可见光区。系统考察了环境因素对降解效率的影响，发现溶液pH和特定阴离子（如Cl^-、 $S O 4 2 -$ ）对反应过程具有显著调控作用。结合自由基捕获实验和EPR分析，证实超氧自由基（· $O 2 -$ ）是降解过程中的主要活性物种。通过高效液相色谱-质谱（HPLC-MS）的分析揭示了TCH的降解路径，毒性评估表明降解中间体的生态毒性显著降低。本研究阐明了稀土元素通过能带工程增强TiO₂光催化活性的内在机制，可为设计高效稳定的可见光响应型环境催化剂提供新思路。

关键词: 催化剂, 稀土, B-TiO₂, 氧空位, 自由基, 水热

Abstract:

In recent years, rare earth element-modified titanium dioxide (TiO₂) has demonstrated remarkable potential in environmental catalysis. In this study, a series of rare earth element modified RE-B-TiO₂ (RE = Nd, Sm, Eu, Er, Tm) nanocatalysts were prepared by a solvothermal method, and their performance and mechanism of degradation of tetracycline hydrochloride (TCH) under visible light were systematically investigated. Among these catalysts, Er-B-TiO₂ exhibited the highest photocatalytic activity under visible light irradiation. Multiscale characterization techniques (XRD, TEM, XPS) revealed that Er-B-TiO₂ possesses a distinctive self-assembled nanorod architecture composed of bipyramidal nanocrystals with dual crystal-facet exposure. This unique configuration facilitates enhanced spatial separation efficiency of photogenerated charge carriers. Under visible light illumination, Er-B-TiO₂ achieved 93.2% TCH degradation efficiency within 120 min. Mechanistic studies demonstrated that Er³⁺ doping synergistically enhances catalytic performance through three critical pathways: (1) introducing abundant oxygen vacancy defects, (2) effectively suppressing electron-hole recombination, and (3) extending light absorption to the visible spectrum via 4f-orbital-mediated bandgap engineering. Environmental parameter analysis revealed significant regulatory effects of solution pH and specific anions (e.g., Cl^-, $S O 4 2 -$ ) on the degradation process. Radical trapping experiments combined with EPR spectroscopy identified superoxide radicals (· $O 2 -$ ) as the dominant reactive species. HPLC-MS analysis elucidated the TCH degradation pathway, while toxicity assessment confirmed substantial reduction in ecological toxicity of degradation intermediates. This work not only clarifies the intrinsic mechanism of rare earth elements in enhancing TiO₂ photocatalytic activity through band structure modulation, but also provides new insights for designing efficient and stable visible-light-responsive environmental catalysts.

Key words: catalyst, rare-earth, B-TiO₂, oxygen vacancies, free radical, hydrothermal

中图分类号:

O 643.36

王燕子, 代佳楠, 马晶, 张腾月, 梁子莉. 稀土元素（RE： Nd、Sm、Eu、Er、Tm）修饰B-TiO₂氧空位特性及其催化性能研究[J]. 化工学报, 2025, 76(10): 5162-5175.

Yanzi WANG, Jia’nan DAI, Jing MA, Tengyue ZHANG, Zili LIANG. Oxygen vacancy characteristics and photocatalytic performance of rare earth elements (RE: Nd, Sm, Eu, Er, Tm) doped B-TiO₂[J]. CIESC Journal, 2025, 76(10): 5162-5175.

图/表 12

图1 B-TiO2和RE-B-TiO2的XRD谱图

Fig.1 XRD patterns of B-TiO2 and RE-B-TiO2

图2 B-TiO2和RE-B-TiO2 的拉曼光谱图

Fig.2 Raman spectra of B-TiO2 and RE-B-TiO2

图3 样品的SEM图

Fig.3 SEM images of samples

图4 (a)~(c) Er-B-TiO2的TEM谱图；Er-B-TiO2的元素分布图：(d) HAACT, (e) B, (f) Ti, (g) O, (h) Er

Fig.4 (a)—(c) TEM images of Er-B-TiO2; Element mapping of Er-B-TiO2：(d) HAACT, (e) B, (f) Ti, (g) O, (h) Er

图5 Er-B-TiO2的XPS光谱：（a）B 1s;（b）Ti 2p；（c）O 1s；（d）Er 4d

Fig.5 Representative high-resolution XPS spectra of Er-B-TiO2：（a）B 1s;（b）Ti 2p；（c）O 1s；（d）Er 4d

图6 B-TiO2和RE-B-TiO2的(a)UV-vis DRS和(b)外推能带谱

Fig.6 (a) UV-vis DRS and (b) tauc plots of B-TiO2 and RE-B-TiO2

图7 B-TiO2和RE-B-TiO2的PL谱图

Fig.7 PL spectra of B-TiO2 and RE-B-TiO2

图9 (a) 光催化降解TCH循环实验；(b) 循环前后的XRD谱图

Fig.9 (a) Cycling experiments of photocatalytic degradation of TCH and (b) XRD patterns before and after reaction of Er-B-TiO2

图10 降解效率影响因素

Fig.10 Factors influencing degradation efficiency

图11 (a) B-TiO2和Er-B-TiO2的价带谱；(b) TCH降解的自由基捕获实验；(c) RE-B-TiO2的EPR谱图；(d) B-TiO2和Er-B-TiO2的氧空位谱图

Fig.11 (a) Valence band spectrum of B-TiO2 and Er-B-TiO2; (b) Free radical capture experiment for degradation of TCH; (c) EPR spectra of RE-B-TiO2; (d) OVs spectra of B-TiO2 and Er-B-TiO2

图12 Er-B-TiO2催化体系降解TCH可能的光催化机理和反应途径

Fig.12 Possible photocatalytic mechanism and reaction pathway of TCH degradation by Er-B-TiO2

图13 (a)水蚤大LC50（48 h）、(b)诱变性、(c)发育毒性和(d)生物积累因子对Er-B-TiO2的降解中间体的毒性评价

Fig.13 Toxicity evaluation of TCH and its degradation intermediates for Er-B-TiO2: (a) Daphnia magna LC50 (48 h), (b) mutagenicity, (c) development toxicity, and (d) bioaccumulation factor

参考文献 50

[1]	Gao Y W, Chen Z H, Zhu Y, et al. New insights into the generation of singlet oxygen in the metal-free peroxymonosulfate activation process: important role of electron-deficient carbon atoms[J]. Environmental Science & Technology, 2020, 54(2): 1232-1241.
[2]	Zhan X Y, Zeng Y X, Zhang H, et al. The coral-like carbon nitride array: rational design for efficient photodegradation of tetracycline under visible light[J]. Journal of Environmental Chemical Engineering, 2023, 11(1): 109201.
[3]	Mustafa F S, Aziz K H H. Heterogeneous catalytic activation of persulfate for the removal of rhodamine B and diclofenac pollutants from water using iron-impregnated biochar derived from the waste of black seed pomace[J]. Process Safety and Environmental Protection, 2023, 170: 436-448.
[4]	Du S W, Zou H, Bao Y F, et al. Homogeneous nitrogen-doped (111)-type layered Sr₅Nb₄O_15– _x N _x as a visible-light-responsive photocatalyst for water oxidation[J]. Nano Research, 2022, 15(12): 9976-9984.
[5]	Wang L J, Zhang Z, Guan R Q, et al. Synergistic CO₂reduction and tetracycline degradation by CuInZnS-Ti₃C₂T _x in one photoredox cycle[J]. Nano Research, 2022, 15(9): 8010-8018.
[6]	梁梦欣,郭艳,王世栋,等.氮化碳负载钯催化剂的制备及对SBS选择性催化加氢性能的研究[J].化工学报,2023,74(2):766-775.
	Liang M X, Guo Y, Wang S D, et al. Study on preparation of Pd catalyst supported on carbon nitride for the selective hydrogenation of SBS[J]. CIESC Journal, 2023, 74(2): 766-775.
[7]	谈朋, 李雪梅, 刘晓勤,等. 基于柔性MOFs的磁响应复合材料及其丙烯吸附性能研究[J]. 化工学报, 2025, 76(5): 2230-2240.
	Tan P, Li X M, Liu X Q, et al. Study on magnetically responsive composite materials based on flexible MOFs and their propylene adsorption performance[J]. CIESC Journal, 2025, 76(5): 2230-2240.
[8]	Hu D K, Qiu D P, Zeng L W, et al. Solar-driven nitrogen fixation catalyzed by stable radical-containing MOFs: improved efficiency induced by a structural transformation[J]. Angewandte Chemie International Edition, 2020, 59(46): 20666-20671.
[9]	Liang P L, Yuan L Y, Du K, et al. Photocatalytic reduction of uranium(Ⅵ) under visible light with 2D/1D Ti₃C₂/CdS[J]. Chemical Engineering Journal, 2021, 420: 129831.
[10]	Zhang J, Gao M T, Wang R Y, et al. Switching of CO₂ hydrogenation selectivity via chlorine poisoning over Ru/TiO₂ catalyst[J]. Nano Research, 2023, 16(4): 4786-4792.
[11]	吴云, 龚海峰. 疏水改性羰基铁负载TiO₂光催化降解石油烃污染物[J]. 化工学报, 2024: 75(12): 4555-4562.
	Wu Y, Gong H F. Carbonyl iron loaded TiO₂ photocatalyst by hydrophobic modification for degradation of petroleum hydrocarbon pollutants in water[J]. CIESC Journal, 2024, 75(12): 4555-4562.
[12]	Yavuz C, Ela S E. Fabrication of g-C₃N₄-reinforced CdS nanosphere-decorated TiO₂nanotablet composite material for photocatalytic hydrogen production and dye-sensitized solar cell application[J]. Journal of Alloys and Compounds, 2023, 936: 168209.
[13]	Mazierski P, Mikolajczyk A, Bajorowicz B, et al. The role of lanthanides in TiO₂-based photocatalysis: a review[J]. Applied Catalysis B: Environmental, 2018, 233: 301-317.
[14]	Ru Y X, Chen Y J, Yu X Y, et al. Enhanced charge separation of Cu-BTC@CuSe@TiO₂ hollow octahedrons for efficient CO₂ photoreduction with superior CO selectivity[J]. Separation and Purification Technology, 2024, 349: 127784.
[15]	Kumaravel V, Mathew S, Bartlett J, et al. Photocatalytic hydrogen production using metal doped TiO₂: a review of recent advances[J]. Applied Catalysis B: Environmental, 2019, 244: 1021-1064.
[16]	Bilgin Simsek E. Solvothermal synthesized boron doped TiO₂ catalysts: photocatalytic degradation of endocrine disrupting compounds and pharmaceuticals under visible light irradiation[J]. Applied Catalysis B: Environmental, 2017, 200: 309-322.
[17]	Feng N, Zheng A, Wang Q, et al. Boron environments in B-doped and (B, N)-codoped TiO₂photocatalysts: a combined solid-state NMR and theoretical calculation study[J]. The Journal of Physical Chemistry C, 2011, 115(6): 2709-2719.
[18]	Christoforidis D K C, Montini D T, Fittipaldi D M, et al. Photocatalytic hydrogen production by boron modified TiO₂/carbon nitride heterojunctions[J]. ChemCatChem, 2019, 11(24): 6408-6416.
[19]	Wu D P, Guo J, Wang H J, et al. Green synthesis of boron and nitrogen co-doped TiO₂ with rich BN motifs as Lewis acid-base couples for the effective artificial CO₂ photoreduction under simulated sunlight[J]. Journal of Colloid and Interface Science, 2021, 585: 95-107.
[20]	Liu C W, Hao D, Ye J, et al. Knowledge-driven design and lab-based evaluation of B-doped TiO₂ photocatalysts for ammonia synthesis[J]. Advanced Energy Materials, 2023, 13(8): 2204126.
[21]	Mo Z, Miao Z H, Yan P C, et al. Electronic and energy level structural engineering of graphitic carbon nitride nanotubes with B and S co-doping for photocatalytic hydrogen evolution[J]. Journal of Colloid and Interface Science, 2023, 645: 525-532.
[22]	Rong W, Ding M, Wang Y, et al. Porous biochar with a tubular structure for photothermal CO₂ cycloaddition: one-step doping versus two-step doping[J]. Separation and Purification Technology, 2025, 353: 128427.
[23]	Zheng B Z, Fan J Y, Chen B, et al. Rare-earth doping in nanostructured inorganic materials[J]. Chemical Reviews, 2022, 122(6): 5519-5603.
[24]	Tiwari D, Lee S M, Kim D J, et al. Photocatalytic degradation of amoxicillin and tetracycline by template synthesized nano-structured Ce³⁺@TiO₂ thin film catalyst[J]. Environmental Research, 2022, 210: 112914.
[25]	Prakash J, Samriti, Kumar A, et al. Novel rare earth metal–doped one-dimensional TiO₂ nanostructures: fundamentals and multifunctional applications[J]. Materials Today Sustainability, 2021, 13: 100066.
[26]	Wu Q, Zhang Q, Li W P, et al. Tailoring of visible light driven photocatalytic activities of Bi₂MoO₆ flower-like microspheres via synergistic effect of doping and surface Plasmon resonance[J]. Chemical Engineering Journal, 2023, 475: 146192.
[27]	Chen L Y, Zhang P K, Kuo D H, et al. Synergism of heterovalent valence state and oxygen vacancy defect engineering in Co/S co-doped TiO₂ for nitrogen photoreduction to ammonia[J]. Journal of Materials Chemistry A, 2024, 12(16): 9871-9885.
[28]	Chen Y, Liu K R. Fabrication of Ce/N co-doped TiO₂/diatomite granule catalyst and its improved visible-light-driven photoactivity[J]. Journal of Hazardous Materials, 2017, 324: 139-150.
[29]	Ma K W, Zhang M Y, Sun W J, et al. Revealing different depth boron substitution on interfacial charge transfer in TiO₂ for enhanced visible-light H₂ production[J]. Applied Catalysis B: Environmental, 2022, 315: 121570.
[30]	Das D, Shyam S. Reduced work function in anatase <101> TiO₂ films self-doped by O-vacancy-dependent Ti³⁺ bonds controlling the photocatalytic dye degradation performance[J]. Langmuir, 2024, 40(20): 10502-10517.
[31]	Wang R, Xu M, Xie J W, et al. A spherical TiO₂-Bi₂WO₆ composite photocatalyst for visible-light photocatalytic degradation of ethylene[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020, 602: 125048.
[32]	Acharya L, Pattnaik S P, Behera A, et al. Exfoliated boron nitride (e-BN) tailored exfoliated graphitic carbon nitride (e-CN): an improved visible light mediated photocatalytic approach towards TCH degradation and H₂ evolution[J]. Inorganic Chemistry, 2021, 60(7): 5021-5033.
[33]	Mikolajczyk A, Wyrzykowska E, Mazierski P, et al. Visible-light photocatalytic activity of rare-earth-metal-doped TiO₂: experimental analysis and machine learning for virtual design[J]. Applied Catalysis B: Environment and Energy, 2024, 346: 123744.
[34]	张佳颖, 王聪, 王雅君. CNT-Co/Bi₂O₃催化剂光催化协同过硫酸盐活化高效降解四环素[J]. 化工学报, 2024, 75(9): 3163-3175.
	Zhang J Y, Wang C, Wang Y J. CNT-Co/Bi₂O₃ catalyst photocatalytic synergistic activation of persulfate for efficient degradation of tetracycline[J]. CIESC Journal, 2024, 75(9): 3163-3175.
[35]	Sengottiyan S, Mikolajczyk A, Jagiełło K, et al. Core, coating, or corona? The importance of considering protein coronas in nano-QSPR modeling of zeta potential[J]. ACS Nano, 2023, 17(3): 1989-1997.
[36]	Ren X H, Yao H, Tang R, et al. Modification of TiO₂ by Er³⁺ and rGO enhancing visible photocatalytic degradation of arsanilic acid[J]. Environmental Science and Pollution Research International, 2023, 30(12): 35023-35033.
[37]	Parnicka P, Lisowski W, Klimczuk T, et al. Visible-light-driven lanthanide-organic-frameworks modified TiO₂ photocatalysts utilizing up-conversion effect[J]. Applied Catalysis B: Environmental, 2021, 291: 120056.
[38]	Zhang S Q, Zhang J, Sun J, et al. Capillary microphotoreactor packed with TiO₂-coated glass beads: an efficient tool for photocatalytic reaction[J]. Chemical Engineering and Processing - Process Intensification, 2020, 147: 107746.
[39]	Parrino F, Bellardita M, García-López E I, et al. Heterogeneous photocatalysis for selective formation of high-value-added molecules: some chemical and engineering aspects[J]. ACS Catalysis, 2018, 8(12): 11191-11225.
[40]	皮若冰, 周云龙. 直接Z型异质结体系光催化还原二氧化碳研究进展[J]. 化工学报, 2024, 75(10): 3379-3400.
	Pi R B, Zhou Y L. Research progress on photocatalytic reduction of carbon dioxide in direct Z-scheme heterojunctions system[J]. CIESC Journal, 2024, 75(10): 3379-3400.
[41]	Lin Z T, Ye S J, Xu Y B, et al. Construction of a novel efficient Z-scheme BiVO₄/EAQ heterojunction for the photocatalytic inactivation of antibiotic-resistant pathogens: Performance and mechanism[J]. Chemical Engineering Journal, 2023, 453: 139747.
[42]	Reszczyńska J, Grzyb T, Wei Z S, et al. Photocatalytic activity and luminescence properties of RE³⁺-TiO₂ nanocrystals prepared by sol-gel and hydrothermal methods[J]. Applied Catalysis B: Environmental, 2016, 181: 825-837.
[43]	Tian K G, Jin L J, Mahmood A, et al. Lattice distortion promotes carrier separation to improve the photoelectrochemical water splitting performance of bismuth vanadate photoanode[J]. Advanced Functional Materials, 2024, 34(51): 2410548.
[44]	Fang W J, Yan J W, Wei Z D, et al. Account of doping photocatalyst for water splitting[J]. Chinese Journal of Catalysis, 2024, 60: 1-24.
[45]	Zhao D X, Cai C. Layered Ti₃C₂ MXene modified two-dimensional Bi₂WO₆ composites with enhanced visible light photocatalytic performance[J]. Materials Chemistry Frontiers, 2019, 3(11): 2521-2528.
[46]	Liu F, Feng N D, Wang Q, et al. Transfer channel of photoinduced holes on a TiO₂ surface As revealed by solid-state nuclear magnetic resonance and electron spin resonance spectroscopy[J]. Journal of the American Chemical Society, 2017, 139(29): 10020-10028.
[47]	Zhang L, Tan L, Yuan Z X, et al. Engineering of Bi₂O₂CO₃/Ti₃C₂T _x heterojunctions co-embedded with surface and interface oxygen vacancies for boosted photocatalytic degradation of levofloxacin[J]. Chemical Engineering Journal, 2023, 452: 139327.
[48]	Chen L, Ji H D, Qi J J, et al. Degradation of acetaminophen by activated peroxymonosulfate using Co(OH)₂ hollow microsphere supported titanate nanotubes: insights into sulfate radical production pathway through CoOH⁺ activation[J]. Chemical Engineering Journal, 2021, 406: 126877.
[49]	Mao S, Zhao P, Wu Y, et al. Promoting charge migration of Co(OH)₂/ g-C₃N₄ by hydroxylation for improved PMS activation: catalyst design, DFT calculation and mechanism analysis[J]. Chemical Engineering Journal, 2023, 451: 138503.
[50]	Li H, Ji H D, Liu J J, et al. Interfacial modulation of ZnIn₂S₄ with high active Zr-S₄ sites for boosting photocatalytic activation of oxygen and degradation of emerging contaminant[J]. Applied Catalysis B: Environmental, 2023, 328: 122481.

稀土元素（RE： Nd、Sm、Eu、Er、Tm）修饰B-TiO₂氧空位特性及其催化性能研究

Oxygen vacancy characteristics and photocatalytic performance of rare earth elements (RE: Nd, Sm, Eu, Er, Tm) doped B-TiO₂

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 12

参考文献 50

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张圣美, 李明, 张莹, 易茜, 杨依婷, 刘雅莉. 乳化剂和温度对相变微胶囊性能的影响分析[J]. 化工学报, 2025, 76(S1): 444-452.
[2]	赵维, 邢文乐, 韩朝旭, 袁兴中, 蒋龙波. g-C₃N₄基非金属异质结光催化降解水中有机污染物的研究进展[J]. 化工学报, 2025, 76(9): 4752-4769.
[3]	钱慧慧, 王文婕, 陈文尧, 周兴贵, 张晶, 段学志. 聚丙烯定向转化制芳烃：金属-分子筛协同催化机制[J]. 化工学报, 2025, 76(9): 4838-4849.
[4]	佟丽丽, 陈英, 艾敏华, 舒玉美, 张香文, 邹吉军, 潘伦. ZnO/WO₃异质结光催化环烯烃［2+2］环加成制备高能量密度燃料[J]. 化工学报, 2025, 76(9): 4882-4892.
[5]	巢欣旖, 陈文尧, 张晶, 钱刚, 周兴贵, 段学志. 甲醇和乙酸甲酯一步法制丙酸甲酯催化剂的可控制备与性能调控[J]. 化工学报, 2025, 76(8): 4030-4041.
[6]	张荟钦, 赵泓竣, 付正军, 庄力, 董凯, 贾添智, 曹雪丽, 孙世鹏. 纳滤膜在离子型稀土浸出液提浓中的应用研究[J]. 化工学报, 2025, 76(8): 4095-4107.
[7]	范夏雨, 孙建辰, 李可莹, 姚馨雅, 商辉. 机器学习驱动液态有机储氢技术的系统优化[J]. 化工学报, 2025, 76(8): 3805-3821.
[8]	杨宁, 李皓男, LIN Xiao, GEORGIADOU Stella, LIN Wen-Feng. 从塑料废弃物到能源催化剂：塑料衍生碳@CoMoO₄复合材料在电解水析氢反应中的应用[J]. 化工学报, 2025, 76(8): 4081-4094.
[9]	林嘉豪, 付芳忠, 叶昊辉, 胡金, 姚明灿, 范鹤林, 王旭, 王瑞祥, 徐志峰. NdF₃含量对NdF₃-LiF熔盐局域结构和输运性质的影响[J]. 化工学报, 2025, 76(8): 3834-3841.
[10]	陆学瑞, 周帼彦, 方琦, 俞孟正, 张秀成, 涂善东. 固体氧化物燃料电池外重整器积炭效应数值模拟研究[J]. 化工学报, 2025, 76(7): 3295-3304.
[11]	赵世颖, 左志帅, 贺梦颖, 安华良, 赵新强, 王延吉. Co-Pt/HAP的制备及其催化1，2-丙二醇氨化反应[J]. 化工学报, 2025, 76(7): 3305-3315.
[12]	李愽龙, 蒋雨希, 任傲天, 秦雯琪, 傅杰, 吕秀阳. TS-1/In-TS-1催化果糖一步法醇解制备乳酸甲酯连续化试验[J]. 化工学报, 2025, 76(6): 2678-2686.
[13]	何军, 李勇, 赵楠, 何孝军. 碳负载硒掺杂硫化钴在锂硫电池中的性能研究[J]. 化工学报, 2025, 76(6): 2995-3008.
[14]	宋粉红, 王文光, 郭亮, 范晶. C元素修饰g-C₃N₄对TiO₂的调控及复合材料光催化产氢性能研究[J]. 化工学报, 2025, 76(6): 2983-2994.
[15]	茅雨洁, 路晓飞, 锁显, 杨立峰, 崔希利, 邢华斌. 工业气体中微量氧深度脱除催化剂研究进展[J]. 化工学报, 2025, 76(5): 1997-2010.