化工学报 ›› 2016, Vol. 67 ›› Issue (S1): 379-383.DOI: 10.11949/j.issn.0438-1157.20160565

• 材料化学工程与纳米技术 • 上一篇    下一篇

化学沉淀法制备纳米SiO2颗粒

胡彦伟, 程珙, 李浩然, 何玉荣   

  1. 哈尔滨工业大学能源科学与工程学院, 黑龙江 哈尔滨 150001
  • 收稿日期:2016-04-28 修回日期:2016-05-08 出版日期:2016-08-31 发布日期:2016-08-31
  • 通讯作者: 何玉荣,rong@hit.edu.cn
  • 基金资助:

    国家自然科学基金优秀青年基金项目(51322601);国家自然科学基金创新研究群体项目(51421063);哈尔滨科技创新人才研究专项基金杰出青年基金项目(2014RFYXJ004)。

Synthesis of SiO2 nanoparticles by chemical precipitation

HU Yanwei, CHENG Gong, LI Haoran, HE Yurong   

  1. School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China
  • Received:2016-04-28 Revised:2016-05-08 Online:2016-08-31 Published:2016-08-31
  • Supported by:

    supported by National Natural Science Foundation of China (51322601), the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (51421063), and the Science Creative Foundation for Distinguished Young Scholars in Harbin (2014RFYXJ004).

摘要:

二氧化硅以其优越的耐热隔热性能引起各个行业的广泛关注。以硅酸钠为硅源、氯化铵为沉淀剂、十六烷基三甲基溴化铵(CTAB)为分散剂,采用化学沉淀法合成二氧化硅纳米颗粒。采用TG-DSC测试分散剂CTAB的分解温度,并用傅里叶红外光谱、X射线以及扫描电镜对制备的二氧化硅粉末进行表征。结果表明,此方法制备的二氧化硅颗粒为无定形态纳米颗粒,平均粒径为80 nm。

关键词: 化学沉淀法, 合成, 纳米粒子, 特性表征, 粒度分布

Abstract:

With excellent physical characteristics such as heat proof, thermal insulation and abrasion resistance, etc., silica nanoparticles have attracted a lot interesting from various industries. Many methods have been proposed to formulate SiO2 nanoparticles, for example, aerosol method, chemical precipitation method, microemulsion method and sol-gel method. Compared with other methods, chemical precipitation uses cheaper materials and is easily to be industrialized. In present work, based on the chemical precipitation method, SiO2 nanoparticles were prepared using sodium silicate (Na2SiO3) as silicon source, ammonium chloride (NH4Cl) as precipitant and cetyl trimethyl ammonium bromide (CTAB) as dispersant. TG-DSC was used to determine the decomposition temperature of CTAB. After the preparation, SiO2 nanoparticles were characterized using Fourier Transform Infrared Spectrometer (FTIR Spectrometer), X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM). Results show that SiO2 nanoparticles formulated by chemical precipitation were amorphous state with an average diameter of 80 nm.

Key words: chemical precipitation, synthesis, nanoparticles, characterization, size distribution

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