ZIF-8/乙二醇体系分离捕集CO2溶解度的模拟计算

doi:10.11949/j.issn.0438-1157.20180236

化工学报 ›› 2018, Vol. 69 ›› Issue (10): 4276-4283.DOI: 10.11949/j.issn.0438-1157.20180236

ZIF-8/乙二醇体系分离捕集CO₂溶解度的模拟计算

宗杰, 马庆兰, 陈光进, 孙长宇

中国石油大学(北京)高压流体相态及物性研究实验室, 北京 102249

收稿日期:2018-03-06 修回日期:2018-07-09 出版日期:2018-10-05 发布日期:2018-10-05
通讯作者: 马庆兰
基金资助:
国家自然科学基金项目（U1162205，51576209）。

Simulation of solubility for separating carbon dioxide from gas mixture using ZIF-8/glycol slurry

ZONG Jie, MA Qinglan, CHEN Guangjin, SUN Changyu

High Pressure Fluid Phase Behavior & Property Research Laboratory, China University of Petroleum, Beijing 102249, China

Received:2018-03-06 Revised:2018-07-09 Online:2018-10-05 Published:2018-10-05
Supported by:
supported by the National Natural Science Foundation of China (U1162205, 51576209).

摘要/Abstract

摘要：

吸收-吸附耦合分离法在分离捕集CO₂方面表现出潜在的优势，应用Kurihara等提出的基于局部组成概念的混合规则与Patel-Teja状态方程相结合确定乙二醇与气体组分间的吸收平衡，由溶解度实验数据确定了混合规则中的二元交互作用参数；采用Langmuir等温吸附方程确定ZIF-8与气体组分间的吸附平衡，进而确定了ZIF-8表面乙二醇膜的选择渗透压与气体组分平衡逸度间的关联式。最后将热力学模型应用到了预测ZIF-8/乙二醇浆液分离捕集CO₂体系。

关键词: 二氧化碳, 吸收-吸附, 耦合分离, 热力学模型

Abstract:

The absorption-adsorption hybrid method has potential superiority on CO₂ separation and caption. In this work, the Patel-Teja equation of state coupled with the Kurihara mixing rule was used to describe the absorption equilibrium. The binary interaction coefficients between pure gas components and glycol were determined by correlating the experimental gas solubility data. Then, the Langmuir equation was applied to calculate the adsorption of gas in ZIF-8, and get the correlation of osmotic pressure of glycol liquid membrane on the surface of ZIF-8 with the equilibrium fugacity of gas component. Finally, the obtained model was applied to predict the separation of CO₂ from gas mixture using ZIF-8/glycol slurry.

Key words: carbon dioxide, absorption-adsorption, hybrid method, thermodynamic model

中图分类号:

TQ021.2

宗杰, 马庆兰, 陈光进, 孙长宇. ZIF-8/乙二醇体系分离捕集CO₂溶解度的模拟计算[J]. 化工学报, 2018, 69(10): 4276-4283.

ZONG Jie, MA Qinglan, CHEN Guangjin, SUN Changyu. Simulation of solubility for separating carbon dioxide from gas mixture using ZIF-8/glycol slurry[J]. CIESC Journal, 2018, 69(10): 4276-4283.

参考文献 31

[1]	CHOWDHURY F A, YAMADA H, HIGASHⅡ T, et al. CO2 capture by tertiary amine absorbents:a performance comparison study[J]. Industrial & Engineering Chemistry Research, 2013, 52(24):8323-8331.
[2]	GHIASI M M, MOHAMMADI A H. Rigorous modeling of CO2 equilibrium absorption in MEA, DEA, and TEA aqueous solutions[J]. Journal of Natural Gas Science & Engineering, 2014, 18(5):39-46.
[3]	ZENG S, ZHANG X, BAI L, et al. Ionic-liquid-based CO2 capture systems:structure, interaction and process[J]. Chemical Reviews, 2017, 117(14):9625-9673.
[4]	BAKHTIARI N, AZIZIAN S. Adsorption of copper ion from aqueous solution by nanoporous MOF-5:a kinetic and equilibrium study[J]. Journal of Molecular Liquids, 2015, 206:114-118.
[5]	CHEN C, KIM J, PARK D W, et al. Ethylenediamine grafting on a zeolite-like metal organic framework (ZMOF) for CO2 capture[J]. Materials Letters, 2013, 106:344-347.
[6]	RADA Z H, ABID H R, SHANG J, et al. Effects of amino functionality on uptake of CO2, CH4 and selectivity of CO2/CH4 on titanium based MOFs[J]. Fuel, 2015, 160:318-327.
[7]	KACEM M, PELLERANO M, DELEBARRE A. Pressure swing adsorption for CO2/N2 and CO2/CH4 separation:Comparison between activated carbons and zeolites performances[J]. Fuel Processing Technology, 2015, 138:271-283.
[8]	GEORGE G, BHORIA N, ALHALLAQ S, et al. Polymer membranes for acid gas removal from natural gas[J]. Separation and Purification Technology, 2016, 158:333-356.
[9]	汪东. 膜吸收法回收烟气中CO2的过程研究[J]. 化学工业与工程技术, 2014, 35(2):61-64. WANG D. Research on flue gas carbon capture with membrane absorption method[J]. Chemical Industry and Engineering Technology, 2014, 35(2):61-64.
[10]	LIU H, LIU B, LIN L C, et al. A hybrid absorption-adsorption method to efficiently capture carbon[J]. Nature Communications, 2014, 5:5147.
[11]	LEI Z, DAI C, SONG W. Adsorptive absorption:a preliminary experimental and modeling study on CO2 solubility[J]. Chemical Engineering Science, 2015, 127:260-268.
[12]	陈光进. 化工热力学[M]. 北京:石油工业出版社, 2006. CHEN G J. Chemical Engineering Thermodynamics[M]. Beijing:Petroleum Industry Press, 2006.
[13]	VARGAS D P, GIRALDO L, MORENO-PIRAJAN J C. CO2 adsorption on activated carbon honeycomb-monoliths:a comparison of Langmuir and Toth models[J]. International Journal of Molecular Sciences, 2012, 13(7):8388-8397.
[14]	MENDES P A P, RODRIGUES A E, HORCAJADA P, et al. Single and multicomponent adsorption of hexane isomers in the microporous ZIF-8[J]. Microporous Mesoporous Mat., 2014, 194:146-156.
[15]	AZIZIAN S, HAERIFAR M, BASIRI-PARSA J. Extended geometric method:a simple approach to derive adsorption rate constants of Langmuir-Freundlich kinetics[J]. Chemosphere, 2007, 68(11):2040-2046.
[16]	ZHAO Z, CUI X, MA J, et al. Adsorption of carbon dioxide on alkali-modified zeolite 13X adsorbents[J]. International Journal of Greenhouse Gas Control, 2007, 1(3):355-359.
[17]	PATEL N C, TEJA A S. A new cubic equation of state for fluids and fluid mixtures[J]. Chemical Engineering Science, 1982, 37:463-473.
[18]	KURIHARA K, TOCHIGI K, KOJIMA K. Mixing rule containing regular-solution and residual excess free energy[J]. J. Chem. Eng. Japan, 1987, 20:227-231.
[19]	MA Q L, CHEN G J, GUO T M. Modelling the gas hydrate formation of inhibitor containing systems[J]. Fluid Phase Equilibria, 2003, 205(2):291-302.
[20]	WILSON G M. Vapor-liquid equilibria(Ⅺ):new expression for the excess Gibbs energy of mixing[J]. J. Am. Chem. Soc., 1964, 86:127-130.
[21]	GUI X, TANG Z, FEI W. Solubility of CO2 in alcohols, glycols, ethers, and ketones at high pressures from (288.15 to 318.15) K[J]. Journal of Chemical & Engineering Data, 2011, 56(5):2420-2429.
[22]	JOU F Y, DESHMUKH R D, OTTO F D, et al. Vapor-liquid equilibria of H2S and CO2 and ethylene glycol at elevated pressures[J]. Chemical Engineering Communications, 1990, 87(1):223-231.
[23]	JOU F Y, OTTO F D, MATHER A E. Solubility of methane in glycols at elevated pressures[J]. Canadian Journal of Chemical Engineering, 1994, 72(1):130-133.
[24]	ZHENG D Q, MA W D, WEI R, et al. Solubility study of methane, carbon dioxide and nitrogen in ethylene glycol at elevated temperatures and pressures[J]. Fluid Phase Equilibria, 1999, 155(2):277-286.
[25]	ZHANG K, LIVELY R P, ZHANG C, et al. Exploring the framework hydrophobicity and flexibility of ZIF-8:from biofuel recovery to hydrocarbon separations[J]. J. Phys. Chem. Lett., 2013, 4(21):3618-3622.
[26]	ZHU J, JIANG L, DAI C, et al. Gas adsorption in shaped zeolitic imidazolate framework-8[J]. Chinese Journal of Chemical Engineering, 2015, 23(8):1275-1282.
[27]	ZHANG X X, XIAO P, ZHAN C H, et al. Separation of methane/ethylene gas mixtures using wet ZIF-8[J]. Industrial & Engineering Chemistry Research, 2015, 54(32):7890-7898.
[28]	DANACI D, SINGH R, XIAO P, et al. Assessment of ZIF materials for CO2 capture from high pressure natural gas streams[J]. Chemical Engineering Journal, 2015, 280:486-493.
[29]	PEREZ-PELLITERO J, AMROUCHE H, SIPERSTEIN F R, et al. Adsorption of CO2, CH4, and N2 on zeolitic imidazolate frameworks:experiments and simulations[J]. Chemistry, 2010, 16(5):1560-1571.
[30]	WU X, HUANG J, CAI W, et al. Force field for ZIF-8 flexible frameworks:atomistic simulation of adsorption, diffusion of pure gases as CH4, H2, CO2 and N2[J]. RSC Adv., 2014, 4(32):16503-16511.
[31]	刘煌. 吸收-水合及吸收-吸附耦合分离气体混合物应用基础研究[D]. 北京:中国石油大学(北京), 2015. LUI H. The research on the gas mixture using absorption-hydration and absorption-adsorption hybrid methods[D]. Beijing:China University of Petroleum, 2015.

ZIF-8/乙二醇体系分离捕集CO₂溶解度的模拟计算

Simulation of solubility for separating carbon dioxide from gas mixture using ZIF-8/glycol slurry

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