蔡建国; 周展云; 邓修
CAI Jianguo; ZHOU Zhanyun; DENG Xiu
摘要: Microparticle formation and crystallization rate of 1,3,5,7-tetranitro-1,3,5,7-
tetraazacyclooctane (HMX) in acetone solution using supercritical carbon dioxide
antisolvent (GAS) recrystallization were studied. Scanning electronic microscopy, X-ray
diffraction and infrared radiation were used to examine particle size, crystallinity and
chemical structure. The results show that β-HMX microparticle in different average size
(2-9.5μm) and with narrow size distribution were obtained by controlling the
expansibility, expansion speed, initial concentration and temperature during
recrystallization of HMX. The formation of nuclei may be a main cause of consumption of
solute when the solution is expanded rapidly enough and the equilibrium concentration is
lower, in which almost monodisperse microparticle can be obtained.