化工学报 ›› 2008, Vol. 59 ›› Issue (10): 2518-2525.

• 催化、动力学与反应器 • 上一篇    下一篇

厌氧氨氧化固定床反应器脱氮性能和过程动力学特性

金仁村;郑平;唐崇俭   

  1. 浙江大学环境工程系;杭州师范大学环境科学系
  • 出版日期:2008-10-05 发布日期:2008-10-05

Performance and process kinetics characteristics of ANAMMOX fixed-bed reactor

IN Rencun;ZHENG Ping;Tang Chongjian   

  • Online:2008-10-05 Published:2008-10-05

摘要:

进行了厌氧氨氧化固定床反应器的运行性能试验,分析了其过程动力学特性。接种反硝化污泥,用模拟废水可成功启动该反应器。当进水总氮浓度为608 mg·L-1,水力停留时间为2 h,总氮负荷为7.34 kg·m-3·d-1时,反应器获得最大基质去除速率6.11 kg·m-3·d-1。二级动力学模型和改进的StoverKincannon模型均适用于非基质抑制状态下的厌氧氨氧化反应器过程模拟。StoverKincannon模型动力学分析表明,这种反应器的最大基质去除速率可达12.4 kg·m-3·d-1,具有较大的脱氮潜能。

关键词:

厌氧氨氧化, 固定床, Stover-Kincannon模型, 二级动力学, 生物脱氮

Abstract:

The performance of an ANAMMOX(anaerobic ammonium oxidation) fixed-bed reactor was tested and the process kinetics characteristics of the reactor was analyzedThe ANAMMOX reactor was successfully operated within 86 days with denitrifying activated sludge as inoculumWhen operated at a hydraulic retention time of 2 h and influent total nitrogen of 608 mg·L-1, corresponding to a nitrogen loading rate of 7.34 kg·m-3·d-1,the maximum total substrate removal rate of 6.11 kg·m-3·d-1 was observedSecondorder and a modified StoverKincannon models well fitted the ANAMMOX fixed reactor under the substrate noninhibition conditionsThe maximum total substrate removal rate achieved in this study was still far lower than the theoretical value 12.4 kg·m-3·d-1 deduced from the Stover Kincannon model, which indicated great potential in improving reactor performance.

Key words:

厌氧氨氧化, 固定床, Stover-Kincannon模型, 二级动力学, 生物脱氮