改性碳纳米管/壳聚糖复合材料的制备及防污性能

doi:10.11949/j.issn.0438-1157.20150458

化工学报 ›› 2015, Vol. 66 ›› Issue (11): 4689-4695.DOI: 10.11949/j.issn.0438-1157.20150458

• 材料化学工程与纳米技术 • 上一篇下一篇

改性碳纳米管/壳聚糖复合材料的制备及防污性能

陈守刚, 刘丹, 王洪芬

中国海洋大学材料科学与工程研究院, 山东青岛 266100

收稿日期:2015-04-13 修回日期:2015-05-25 出版日期:2015-11-05 发布日期:2015-11-05
通讯作者: 陈守刚
基金资助:
国家自然科学基金项目(51072188,51572249);山东省科技攻关计划项目(2013GHY11508)。

Preparation of modified multiwalled carbon nanotubes/chitosan composites and their antifouling properties

CHEN Shougang, LIU Dan, WANG Hongfen

Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, Shandong, China

Received:2015-04-13 Revised:2015-05-25 Online:2015-11-05 Published:2015-11-05
Supported by:
supported by the National Natural Science Foundation of China (51072188, 51572249) and the Shandong Province Programs for Science and Technology Development (2013GHY11508).

摘要/Abstract

摘要：

通过控制溶液的pH,在酸性条件下制备了单层多巴胺改性的多壁碳纳米管,然后以戊二醛作为反应中间桥梁,共价接枝制备得到碳纳米管/壳聚糖复合材料。通过透射电子显微镜(TEM)、红外光谱(FTIR)和热重分析法(TGA)对复合材料的结构和性能进行表征,结果表明碳纳米管的管壁外面和管端都被均匀包覆起来,包覆层厚度在6 nm左右;采用多巴胺单层膜包覆碳纳米管,达到了减小对碳纳米管结构造成破坏同时增加表面活性基团数量的目的,使得复合材料中壳聚糖的接枝量增加到71.78%。复合材料兼具了壳聚糖和碳纳米管在抑菌性、缓释、硅藻生长抑制方面优异的性能,在对大肠杆菌、金黄色葡萄球菌、鳗弧菌及小舟形藻、成排舟形藻的防污性能实验中,复合材料在抑菌及抑制硅藻生长方面均表现出广谱、长效的抑制性能。

关键词: 复合材料, 制备, 纳米材料, 多巴胺, 多壁碳纳米管, 壳聚糖

Abstract:

By controlling the pH of the solution, single-layer dopamine modified multiwalled carbon nanotubes (micaDA-MWCNTs) were prepared under acid condition. Multiwalled carbon nanotubes/chitosan (CS/micaDA-MWCNTs) composites were prepared by covalent grafting method with glutaraldehyde as a bridge material between chitosan and multi-walled carbon nanotubes (MWCNTs). The structure and nature of CS/micaDA-MWCNTs composites were characterized by transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR) and thermal gravimetric analysis (TGA). The results showed that about 6 nm membrane layer of chitosan was well-distributively coated on the surface and the end of MWCNTs. The effective biocompatible strategy of dopamine monolayer film coated carbon nanotubes can not only achieve the purpose of modification with less damage of carbon nanotube structure, but also increase significant amounts of surface active groups of MWCNTs, thereby increasing the content of grafted chitosan. Thermogravimetry analysis (TGA) data showed the chitosan graft was approximately 71.78%. CS/micaDA-MWCNTs had the advantages of both CS and MWCNTs in bacteriostasis, sustained-release effect and diatom growth inhibition. Antifouling experiments indicated that the composites had an efficient broad-spectrum of antibacterial activity against E. coli, S. aureus, Vibrio anguillarum, Navicula parva and Navicula rows.

Key words: composites, preparation, nanomaterials, dopamine, MWCNTs, chitosan

中图分类号:

陈守刚, 刘丹, 王洪芬. 改性碳纳米管/壳聚糖复合材料的制备及防污性能[J]. 化工学报, 2015, 66(11): 4689-4695.

CHEN Shougang, LIU Dan, WANG Hongfen. Preparation of modified multiwalled carbon nanotubes/chitosan composites and their antifouling properties[J]. CIESC Journal, 2015, 66(11): 4689-4695.

参考文献 26

[1]	No H K, Park N Y, Lee S H, Meyers S P. Antibacterial activity of chitosans and chitosan oligomers with different molecular weights [J]. International Journal of Food Microbiology, 2002, 74 (1/2): 65-72.
[2]	Xie Yuliang (谢瑜亮), Wang Mingjun (王明君), Yao Shanjing (姚善泾). Layer-by-layer self-assembly complex membrane composed of sodium cellulose sulfate-chitosan [J]. Journal of Chemical Industry and Engineering (China) (化工学报), 2008, 59 (11): 2910-2915.
[3]	Baran T, Mente? A, Arslan H. Synthesis and characterization of water soluble O-carboxymethyl chitosan Schiff bases and Cu(Ⅱ) complexes [J]. International Journal of Biological Macromolecules, 2015, 72: 94-103.
[4]	Li Junhong (李俊宏), Xu Yuting (徐玉婷), Tang Chengli (唐成黎), Liu Xiong (刘雄), Tan Yunfei (谭芸妃), Dong Lichun (董立春). Preparation and characterization of sulfonated crosslinked chitosan resin as solid acidic catalyst [J]. CIESC Journal (化工学报), 2013, 64 (5): 1645-1641.
[5]	Hu H, Xin J H, Hu H, Chan A, He L. Glutaraldehyde-chitosan and poly (vinyl alcohol) blends, and fluorescence of their nano-silica composite films [J]. Carbohydrate Polymers, 2013, 91 (1): 305-313.
[6]	Wan Peng (万鹏), Zhang Hua (张华), Yu Chang (于畅), Qiu Jieshan (邱介山). Preparation of carbon-based monolith with macro-pore from chitosan and its adsorption performance for trace SO2 [J]. CIESC Journal (化工学报), 2012,64 (1): 357-364.
[7]	Bulwan M, Wójcik K, Zapotoczny S, Nowakowska M. Chitosan-based ultrathin films as antifouling, anticoagulant and antibacterial protective coatings [J]. Journal of Biomaterials Science, 2012, 23: 1963-1980.
[8]	Heuser M, Cardenas G. Chitosan-copper paint types as antifouling [J]. Journal of the Chilean Chemical Society, 2014, 59 (2): 2415-2419.
[9]	Feng Y, Lin X, Li H, He L, Sridhar T, Suresh A K, Bellare J, Wang H. Synthesis and characterization of chitosan-grafted BPPO ultrafiltration composite membranes with enhanced antifouling and antibacterial properties [J]. Industrial & Engineering Chemistry Research, 2014, 53: 14974-14981.
[10]	Pelletier E, Bonnet C, Lemarchand K. Biofouling growth in cold estuarine waters and evaluation of some chitosan and copper anti-fouling paints [J]. International Journal of Molecular Sciences, 2009, 10 (7): 3209-3223.
[11]	Kumar R, Isloor A M, Ismail A F, Rashidc S A, Matsuura T. Polysulfone-chitosan blend ultrafiltration membranes: preparation, characterization, permeation and antifouling properties [J]. RSC Advances, 2013, 3: 7855-7861.
[12]	Wang L N, Jia X L, Li Y F, Yang F, Zhang L Q, Liu L P, Ren X, Yang H T. Synthesis and microwave absorption property of flexible magnetic film based on graphene oxide/carbon nanotubes and Fe3O4 nanoparticles [J]. Journal of Materials Chemistry A, 2014, 2: 14940-14946.
[13]	Wang Jia (王佳), Li Junhua (李俊华), Zhou Jian (周健). Electrochemistry of glucose oxidase on modified carbon nanotubes [J]. CIESC Journal (化工学报), 2014, 65 (5): 1771-1776.
[14]	Aryaei A, Jayatissa A H, Jayasuriya A C. Mechanical and biological properties of chitosan/carbon nanotube nanocomposite films [J]. Journal of Biomedical Materials Research Part A, 2014, 102: 2704-2712.
[15]	Numnuam A, Thavarungkul P, Kanatharana P. An amperometric uric acid biosensor based on chitosan-carbon nanotubes electrospun nanofiber on silver nanoparticles [J]. Analytical and Bioanalytical Chemistry, 2014, 406:3763-3772.
[16]	Carson L, Brown C K, Stewart M, Oki A, Regisford G, Luo Z, Bakhmutov V I. Synthesis and characterization of chitosan-carbon nanotube composites [J]. Materials Letters, 2009, 63 (6/7):617-620.
[17]	Wang S F, Shen L, Zhang W D, Tong Y J. Preparation and mechanical properties of chitosan/carbon nanotubes composites [J]. Biomacromolecules, 2005, 6: 3067-3072.
[18]	Faure E, Falentin-Daudré C, Jérôme C, Lyskawa J, Fournier D, Woisel P, Detrembleur C. Catechols as versatile platforms in polymer chemistry [J]. Progress in Polymer Science, 2013, 38: 236-270.
[19]	Fan Rongyu (范荣玉), Zheng Ximing (郑细鸣), Li Binbin (李彬彬). Surface mineralized modification of microporous polypropylene membrane and its hydrophilic properties [J]. CIESC Journal (化工学报), 2015, 66 (2): 626-634.
[20]	Liu Y, Yu B, Hao J C, Zhou F. Amination of surfaces via self-assembly of dopamine [J]. Journal of Colloid and Interface Science, 2011, 362 (1): 127-134.
[21]	Hu H, Yu B, Ye Q, Gu Y, Zhou F. Modification of carbon nanotubes with a nanothin polydopamine layer and polydimethylamino-ethyl methacrylate brushes [J]. Carbon, 2010, 48 (8): 2347-2353.
[22]	Fei B, Qian B, Yang Z, Wang R, Liu W C, Mak C L, Xin J H. Coating carbon nanotubes by spontaneous oxidative polymerization of dopamine [J]. Carbon, 2008, 46 (13): 1792-1828.
[23]	Shieh Y T, Yang Y F. Significant improvements in mechanical property and water stability of chitosan by carbon nanotubes [J]. European Polymer Journal, 2006, 42: 3162-3170.
[24]	Beigbeder A, Degee P. Conlan S L, Mutton R J, Clare A S, Pettitt M E, Callow M E, Callow J A, Dubois P. Preparation and characterisation of silicone-based coatings filled with carbon nanotubes and natural sepiolite and their application as marine fouling-release coatings [J]. Biofouling, 2008, 24 (4): 291-302.
[25]	Shieh Y T, Yang Y F. Significant improvements in mechanical property and water stability of chitosan by carbon nanotubes [J]. Macromolecular Nanotechnology, 2006, 42: 3162-3170.
[26]	Wu Z, Feng W, Feng Y, Liu Q, Xu X, Sekino T, Fujii A, Ozaki M. Preparation and characterization of chitosan-grafted multiwalled carbon nanotubes and their electrochemical properties [J]. Carbon, 2007, 45 (4): 1212-1218.

改性碳纳米管/壳聚糖复合材料的制备及防污性能

Preparation of modified multiwalled carbon nanotubes/chitosan composites and their antifouling properties

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 26

相关文章 15

编辑推荐

Metrics

本文评价

[1]	刘远超, 关斌, 钟建斌, 徐一帆, 蒋旭浩, 李耑. 单层XSe₂（X=Zr/Hf）的热电输运特性研究[J]. 化工学报, 2023, 74(9): 3968-3978.
[2]	胡兴枝, 张皓焱, 庄境坤, 范雨晴, 张开银, 向军. 嵌有超小CeO₂纳米粒子的碳纳米纤维的制备及其吸波性能[J]. 化工学报, 2023, 74(8): 3584-3596.
[3]	陈佳起, 赵万玉, 姚睿充, 侯道林, 董社英. 开心果壳基碳点的合成及其对Q235碳钢的缓蚀行为研究[J]. 化工学报, 2023, 74(8): 3446-3456.
[4]	吴文涛, 褚良永, 张玲洁, 谭伟民, 沈丽明, 暴宁钟. 腰果酚生物基自愈合微胶囊的高效制备工艺研究[J]. 化工学报, 2023, 74(7): 3103-3115.
[5]	邢美波, 张中天, 景栋梁, 张洪发. 磁调控水基碳纳米管协同多孔材料强化相变储/释能特性[J]. 化工学报, 2023, 74(7): 3093-3102.
[6]	余娅洁, 李静茹, 周树锋, 李清彪, 詹国武. 基于天然生物模板构建纳米材料及集成催化剂研究进展[J]. 化工学报, 2023, 74(7): 2735-2752.
[7]	王志龙, 杨烨, 赵真真, 田涛, 赵桐, 崔亚辉. 搅拌时间和混合顺序对锂离子电池正极浆料分散特性的影响[J]. 化工学报, 2023, 74(7): 3127-3138.
[8]	葛加丽, 管图祥, 邱新民, 吴健, 沈丽明, 暴宁钟. 垂直多孔碳包覆的FeF₃正极的构筑及储锂性能研究[J]. 化工学报, 2023, 74(7): 3058-3067.
[9]	张澳, 罗英武. 低模量、高弹性、高剥离强度丙烯酸酯压敏胶[J]. 化工学报, 2023, 74(7): 3079-3092.
[10]	王杰, 丘晓琳, 赵烨, 刘鑫洋, 韩忠强, 许雍, 蒋文瀚. 聚电解质静电沉积改性PHBV抗氧化膜的制备与性能研究[J]. 化工学报, 2023, 74(7): 3068-3078.
[11]	朱风, 陈凯琳, 黄小凤, 鲍银珠, 李文斌, 刘嘉鑫, 吴玮强, 高王伟. KOH改性电石渣脱除羰基硫的性能研究[J]. 化工学报, 2023, 74(6): 2668-2679.
[12]	蔡斌, 张效林, 罗倩, 党江涛, 左栗源, 刘欣梅. 导电薄膜材料的研究进展[J]. 化工学报, 2023, 74(6): 2308-2321.
[13]	董茂林, 陈李栋, 黄六莲, 吴伟兵, 戴红旗, 卞辉洋. 酸性助水溶剂制备木质纳米纤维素及功能应用研究进展[J]. 化工学报, 2023, 74(6): 2281-2295.
[14]	崔张宁, 胡紫璇, 吴雷, 周军, 叶干, 刘田田, 张秋利, 宋永辉. 可降解纤维素基材料的耐水性能研究进展[J]. 化工学报, 2023, 74(6): 2296-2307.
[15]	杨琴, 秦传鉴, 李明梓, 杨文晶, 赵卫杰, 刘虎. 用于柔性传感的双形状记忆MXene基水凝胶的制备及性能研究[J]. 化工学报, 2023, 74(6): 2699-2707.