化工学报 ›› 2013, Vol. 64 ›› Issue (1): 173-181.DOI: 10.3969/j.issn.0438-1157.2013.01.020

• 综述与专论 • 上一篇    下一篇

基于膜表面与界面作用的膜污染控制方法

邢卫红, 仲兆祥, 景文珩, 范益群   

  1. 南京工业大学膜科学技术研究所,国家特种分离膜工程技术研究中心,江苏 南京 210009
  • 收稿日期:2012-07-31 修回日期:2012-09-14 出版日期:2013-01-05 发布日期:2013-01-05
  • 通讯作者: 邢卫红
  • 作者简介:邢卫红(1968—),女,博士,研究员。
  • 基金资助:

    国家自然科学基金项目(21125629,21076102);国家重点基础研究发展计划项目(2009CB623400);中国工程院咨询研究项目。

Controlling of membrane fouling based on membrane interface interactions

XING Weihong, ZHONG Zhaoxiang, JING Wenheng, FAN Yiqun   

  1. Research Center of Membrane Science and Technology, National Engineering Research Center for Special Separation Membranes, Nanjing University of Technology, Nanjing 210009, Jiangsu, China
  • Received:2012-07-31 Revised:2012-09-14 Online:2013-01-05 Published:2013-01-05
  • Supported by:

    supported by the National Natural Science Foundation of China (21125629,21076102),the National Basic Research Program of China (2009CB623400) and the Consulting and Research Program of Chinese Academy of Engineering.

摘要: 膜污染控制是膜技术能否成功应用的关键因素之一。讨论了膜面粗糙度、亲水性和荷电性等性质对膜分离性能的影响,介绍了膜表面性质参数的表征方法,分析了颗粒污染物团聚、颗粒与胶体吸附、胶体大分子的变形等对膜污染形成的影响。最后对面向应用过程的陶瓷膜材料表面与界面控制方法进行了总结。膜污染的研究已从操作参数调节发展到表面与界面作用的控制,对提高膜分离性能,促进膜过程在更多领域的推广应用有重要意义。

关键词: 膜污染, 粗糙度, 亲水性, 荷电性, 颗粒, 胶体

Abstract: Membrane fouling control is one of the key factors affecting the applicability and profitability of a membrane system.In this study, the effects of membrane surface roughness, hydrophilicity and charge on the membrane performance are discussed.New surface characterization techniques are introduced.Studies on interfacial interactions between foulants and membranes are reviewed.The effects of particle aggregation, adsorption of colloids onto particles and deformation of colloidal molecules on the fouling formation are analyzed.Finally, the theory and method of application-oriented membrane surface design are proposed.The studies on membrane fouling control are from the adjustment of operating parameters to surface and interface control, which play an increasingly important role in membrane performance improvement and industrial applications.

Key words: membrane fouling, roughness, hydrophilicity, charge, particle, colloid

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