颜料二氧化钛光催化特性评价

doi:10.3969/j.issn.0438-1157.2013.07.020

化工学报 ›› 2013, Vol. 64 ›› Issue (7): 2453-2461.DOI: 10.3969/j.issn.0438-1157.2013.07.020

• 催化、动力学与反应器 • 上一篇下一篇

颜料二氧化钛光催化特性评价

赵琳, 高晗, 韦冰心, 王亭杰, 金涌

清华大学化学工程系, 北京 100084

收稿日期:2012-10-17 修回日期:2013-03-19 出版日期:2013-07-05 发布日期:2013-07-05
通讯作者: 王亭杰
作者简介:赵琳(1987- ),女,博士研究生。
基金资助:
国家自然科学基金项目(21176134)。

Evaluation of photocatalytic activity of pigmentary titania

ZHAO Lin, GAO Han, WEI Bingxin, WANG Tingjie, JIN Yong

Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2012-10-17 Revised:2013-03-19 Online:2013-07-05 Published:2013-07-05
Supported by:
supported by the National Natural Science Foundation of China (21176134).

摘要/Abstract

摘要： 采用悬浆外照式光催化反应器,研究了在紫外光照下低活性颜料二氧化钛光催化降解罗丹明B的反应动力学特性。考察了二氧化钛浓度、罗丹明B浓度、紫外线波长及光强对光催化反应速率的影响,确定了适合颜料二氧化钛光催化特性评价的优化检测条件。研究表明,颜料二氧化钛光催化降解罗丹明B具有一级反应动力学特性。确定颜料二氧化钛光催化特性检测方法的优化操作条件为二氧化钛浓度约为4 g·L^-1、罗丹明B浓度为2~10 mg·L^-1、紫外光源主发射波长为254 nm。实验检测了表面包硅二氧化钛样品的光催化特性,表明该检测方法能够对颜料二氧化钛及包膜二氧化钛的光催化特性进行快速定量的评价。

关键词: 二氧化钛, 光催化, 耐候性, 罗丹明B, 反应动力学

Abstract: The photocatalytic activity evaluation of submicron-sized pigmentary titania using the degradation of Rhodamine B under ultraviolet radiation in a slurry reactor was studied.The effects of titania concentration,Rhodamine B concentration,and wavelength and power of the light source on reaction rate were investigated.The optimal operation conditions for evaluating the photocatalytic activity of pigmentary titania particles were determined.The experimental results showed that the photocatalytic degradation of Rhodamine B by pigmentary titania was an apparent first order reaction.The photocatalytic reaction rate was high under the conditions of a titania concentration of 4 g·L^-1,Rhodamine B concentration in the range of 2—10 mg·L^-1,and the use of the main emission peak of the light source at 254 nm,which were suitable for evaluating the photocatalytic activity of pigmentary titania.The photocatalytic activity of titania particles with a dense silica coat was measured under these optimized reaction conditions,which showed that this method could be used to evaluate the photocatalytic activity of the pigmentary or film coated titania quantitatively and rapidly.

Key words: titania, photocatalysis, weather durability, Rhodamine B, reaction kinetics

中图分类号:

TQ426
O644

赵琳, 高晗, 韦冰心, 王亭杰, 金涌. 颜料二氧化钛光催化特性评价[J]. 化工学报, 2013, 64(7): 2453-2461.

ZHAO Lin, GAO Han, WEI Bingxin, WANG Tingjie, JIN Yong. Evaluation of photocatalytic activity of pigmentary titania[J]. CIESC Journal, 2013, 64(7): 2453-2461.

参考文献 32

[1]	GB/T 9276—1996.Methods of exposure to natural weathering of coating[S]
[2]	GB/T 1865—1997.Paints and varnishes—artificial weathering and exposure to artificial radiation—filtered xenon-arc radiation[S]
[3]	Berdahl P,Akbari H,Levinson R,Miller W A. Weathering of roofing materials-an overview[J].Construction and Building Materials,2008,22(4):423-433
[4]	Shirayama H,Tohezo Y,Taguchi S.Photodegradation of chlorinated hydrocarbons in the presence and absence of dissolved oxygen in water[J].Water Research,2001,35(8):1941-1950
[5]	Sobczynski A,Gimenez J,Cerveramarch S. Photodecomposition of phenol in a flow reactor:adsorption and kinetics[J].Monatshefte fur Chemie,1997,128(11):1109-1118
[6]	Tsai W T,Lee M K,Su T Y,Chang Y M. Photodegradation of bisphenol-A in a batch TiO2 suspension reactor[J].Journal of Hazardous Materials,2009,168(1):269-275
[7]	Chen L C,Chou T C.Kinetics of photodecolorization of methyl-orange using titanium-dioxide as catalyst[J].Industrial & Engineering Chemistry Research,1993, 32(7):1520-1527
[8]	Toor A P,Verma A,Jotshi C K,Bajpai P K,Singh V. Photocatalytic degradation of direct yellow 12 dye using UV/TiO2 in a shallow pond slurry reactor[J].Dyes and Pigments,2006,68(1):53-60
[9]	Nam W,Kim J,Han G Y.Photocatalytic oxidation of methyl orange in a three-phase fluidized bed reactor[J].Chemosphere,2002,47(9):1019-1024
[10]	Lachheb H,Puzenat E,Houas A,Ksibi M,Elaloui E,Guillard C,Herrmann J M.Photocatalytic degradation of various types of dyes (Alizarin S,Crocein Orange G,Methyl Red,Congo Red,Methylene Blue)in water by UV-irradiated titania[J].Applied Catalysis B-Environmental,2002,39(1):75-90
[11]	Molinari R,Pirillo F,Falco M,Loddo V,Palmisano L.Photocatalytic degradation of dyes by using a membrane reactor[J].Chemical Engineering and Processing,2004,43(9):1103-1114
[12]	Dijkstra M F J,Buwalda H,de Jong A W F,Michorius A,Winkelman J G M,Beenackers A A C M.Experimental comparison of three reactor designs for photocatalytic water purification[J].Chemical Engineering Science,2001, 56(2):547-555
[13]	Akyol A,Bayramoglu M.The degradation of an azo dye in a batch slurry photocatalytic reactor[J].Chemical Engineering and Processing,2008,47(12):2150-2156
[14]	Fujishima A,Zhang X,Tryk D A.TiO2 photocatalysis and related surface phenomena[J].Surface Science Reports,2008,63(12):515-582
[15]	Bhatkhande D S,Pangarkar V G,Beenackers A.Photocatalytic degradation for environmental applications —a review[J].Journal of Chemical Technology and Biotechnology,2002,77(1):102-116
[16]	Linsebigler A L,Lu G Q,Yates J T.Photocatalysis on TiO2 surfaces — principles,mechanisms,and selected results[J].Chemical Reviews,1995,95(3):735-758
[17]	Fox M A,Dulay M T.Heterogeneous photocatalysis[J].Chemical Reviews,1993,93(1):341-357
[18]	Herrmann J M.Heterogeneous photocatalysis:fundamentals and applications to the removal of various types of aqueous pollutants[J].Catalysis Today,1999,53(1):115-129
[19]	Zhang F L,Zhao J C,Shen T,Hidaka H,Pelizzetti E,Serpone N.TiO2-assisted photodegradation of dye pollutants(Ⅱ):Adsorption and degradation kinetics of eosin in TiO2 dispersions under visible light irradiation[J].Applied Catalysis B-Environmental,1998,15(1/2):147-156
[20]	Liu G M,Li X Z,Zhao J C,Hidaka H,Serpone N. Photooxidation pathway of sulforhodamine-B.Dependence on the adsorption mode on TiO2 exposed to visible light radiation[J].Environmental Science & Technology,2000,34(18):3982-3990
[21]	Gaya U I,Abdullah A H.Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide:a review of fundamentals,progress and problems[J].Journal of Photochemistry and Photobiology C-Photochemistry Reviews,2008,9(1):1-12
[22]	Subramanian M,Kannan A.Effect of dissolved oxygen concentration and light intensity on photocatalytic degradation of phenol[J].Korean Journal of Chemical Engineering,2008,25(6):1300
[23]	Cabrera M I,Alfano O M,Cassano A E.Scattering effects produced by inert particles in photochemical reactors(Ⅱ):A parametric study[J].Industrial and Engineering Chemistry Research,1995,34(2):500-509
[24]	Alfano O M,Negro A C,Cabrera M I,Cassano A E.Scattering effects produced by inert particles in photochemical reactors(Ⅰ):Model and experimental verification[J].Industrial and Engineering Chemistry Research,1995,34(2):488-499
[25]	Alfano O M,Cabrera M I,Cassano A E.Modeling of light scattering in photochemical reactors[J].Chemical Engineering Science,1994,49(24B):5327-5346
[26]	Wu C H,Chang H W,Chern J M.Basic dye decomposition kinetics in a photocatalytic slurry reactor[J].Journal of Hazardous Materials,2006,137(1):336-343
[27]	Sauer T,Neto G C,Jose H J,Moreira R F P M.Kinetics of photocatalytic degradation of reactive dyes in a TiO2 slurry reactor[J].Journal of Photochemistry and Photobiology A-Chemistry,2002,149(1/2/3):147-154
[28]	Jain R,Mathur M,Sikarwar S,Mittal A.Removal of the hazardous dye Rhodamine B through photocatalytic and adsorption treatments[J].Journal of Environmental Management,2007,85(4):956-964
[29]	Hou Yaqi (侯亚奇).Study on the photocatalytic degradation properties of titanium oxide film and its composite films.Beijing:Tsinghua University,2004
[30]	Tommasini S,Calabro M L,Donato P,Raneri D,Guglielmo G,Ficarra P,Ficarra R.Comparative photodegradation studies on 3-hydroxyflavone:influence of different media,pH and light sources[J].Journal of Pharmaceutical and Biomedical Analysis,2004,35(2):389-397
[31]	Hirahara Y,Ueno H,Nakamuro K.Comparative photodegradation study of fenthion and disulfoton under irradiation of different light sources in liquid-and solid-phases[J].Journal of Health Science,2001,47(2):129-135
[32]	Blazkova A,Csolleova I,Brezova V.Effect of light sources on the phenol degradation using Pt/TiO2 photocatalysts immobilized on glass fibres[J].Journal of Photochemistry and Photobiology A:Chemistry,1998,113(3):251-256

颜料二氧化钛光催化特性评价

Evaluation of photocatalytic activity of pigmentary titania

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