氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

doi:10.3969/j.issn.0438-1157.2013.11.052

化工学报 ›› 2013, Vol. 64 ›› Issue (11): 4269-4273.DOI: 10.3969/j.issn.0438-1157.2013.11.052

• 材料化学工程与纳米技术 • 上一篇

氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

谭军¹, 王华金², 沙宝祥^1,3, 韦晓燕¹, 俞强³

1. 嘉兴学院生物与化学工程学院, 浙江嘉兴 314001;
2. 嘉兴学院材料与纺织工程学院, 浙江嘉兴 314001;
3. 常州大学材料科学与工程学院, 江苏常州 213164

收稿日期:2013-05-06 修回日期:2013-07-21 出版日期:2013-11-05 发布日期:2013-11-05
通讯作者: 谭军
作者简介:谭军(1979-),男,博士,副教授。
基金资助:
嘉兴市科技计划项目(2009AY2003,2012AY1025);国家自然科学基金项目(20906038)。

Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane

TAN Jun¹, WANG Huajin², SHA Baoxiang^1,3, WEI Xiaoyan¹, YU Qiang³

1. School of Biological and Chemical Engineering, Jiaxing University, Jiaxing 314001, Zhejiang, China;
2. School of Materials and Textile Engineering, Jiaxing University, Jiaxing 314001, Zhejiang, China;
3. School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China

Received:2013-05-06 Revised:2013-07-21 Online:2013-11-05 Published:2013-11-05
Supported by:
supported by the Science and Technology Project Foundation of Jiaxing City(2009AY2003,2012AY1025)and the National Natural Science Foundation of China(20906038).

摘要/Abstract

关键词: 氯甲基倍半硅氧烷, 环氧树脂, 固化反应, 热性能, 力学性能

Abstract: Hybrid epoxy resin composite materials were prepared from choromethyl polyhedral silsesquioxane(CM-POSS),bisphenol epoxy(E-51),MeTHPA and TEA.The curing reaction of hybrid epoxy,and mechanical and thermal properties of the cured epoxy were characterized by Fourier transform infrared spectroscopy(FT-IR),differential scanning calorimetry(DSC),thermogravimetric analysis(TGA)and heat distortion temperature tester.CM-POSS was connected in cross-linked epoxy resin system by chemical reaction in the curing reaction process.Thermal properties,tensile,bending and impact strengthes of the cured hybrid resin were improved with increased content of CM-POSS.Addition of CM-POSS could make the T_g and rigidity of epoxy resin increase but had little effect on tenacity.

Key words: chloromethyl polyhedral silsesquioxane, epoxy resin, curing reaction, thermal properties, mechanical properties

中图分类号:

谭军, 王华金, 沙宝祥, 韦晓燕, 俞强. 氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能[J]. 化工学报, 2013, 64(11): 4269-4273.

TAN Jun, WANG Huajin, SHA Baoxiang, WEI Xiaoyan, YU Qiang. Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane[J]. CIESC Journal, 2013, 64(11): 4269-4273.

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氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane

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