钙钛矿型复合氧化物对甲烷的部分氧化及在混合太阳能氧化还原过程的应用

doi:10.3969/j.issn.0438-1157.2014.07.035

化工学报 ›› 2014, Vol. 65 ›› Issue (7): 2741-2750.DOI: 10.3969/j.issn.0438-1157.2014.07.035

• 催化、动力学与反应器 • 上一篇下一篇

钙钛矿型复合氧化物对甲烷的部分氧化及在混合太阳能氧化还原过程的应用

陈彦广^1,2, 何峰¹, Daga Shivalik¹, 李凡星¹

1. 北卡莱罗纳州立大学化工与生物分子工程系, 北卡莱罗纳罗利 27695-7905;
2. 东北石油大学化学化工学院, 黑龙江省石油与天然气化工重点实验室, 黑龙江大庆 163318

收稿日期:2014-05-26 修回日期:2014-06-06 出版日期:2014-07-05 发布日期:2014-07-05
通讯作者: 李凡星, 陈彦广
基金资助:
美国国家自然科学基金项目（CBET-1254351）；国家自然科学基金项目（51204057）。

Redox conversion of methane with Fe₂O₃-CaTi_xM₁_-xO₃ composite oxides for hydrogen and liquid fuel co-production

CHEN Yanguang^1,2, HE Feng¹, DAGA Shivalik¹, LI Fanxing¹

1. Department of Chemical and Biomolecular Engineering, North Carolina State University, Raleigh 27695-7905, United States;
2. School of Chemistry and Chemical Engineering, Northeast Petroleum University, Provincial Key Laboratory of Oil & Gas Chemical Technology, Daqing 163318, Heilongjiang, China

Received:2014-05-26 Revised:2014-06-06 Online:2014-07-05 Published:2014-07-05
Supported by:
supported by the U.S. National Science Foundation (CBET-1254351) and the National Natural Science Foundation of China (51204057).

摘要/Abstract

摘要： 利用固相法合成了3种钙钛矿型复合氧化物Fe₂O₃-CaTi_xM₁_-xO₃，研究了其结构、晶型和氧化还原活性。在固定床反应器中考察了该氧化物对两步法甲烷催化氧化制合成气及水分解制氢的活性及选择性。X射线衍射结果表明3种钙钛型复合氧化物均由正交晶系钙钛矿相和赤铁矿相组成。3种钙钛矿复合氧化物对甲烷的氧化活性顺序为Fe₂O₃-CaTi_0.85Ni_0.15O₃ >Fe₂O₃-CaTi_0.85Co_0.15O₃ >Fe₂O₃-CaTi_0.85Fe_0.15O₃。固定床反应结果表明，以Fe₂O₃-CaTi_0.85Ni_0.15O₃为氧载体催化剂，CH₄转化率可达96%，CO和H₂产率达71%，同时水分解反应的转化率为40%。利用Aspen Plus^®对Fe₂O₃-CaTi_0.85Ni_0.15O₃在混合太阳能氧化还原过程的效率及合成油和H₂产率进行了模拟。模拟计算结果证明基于复合氧化物的混合太阳能氧化还原过程可以有效提高CH₄利用率。

关键词: 钙钛矿型复合氧化物, 甲烷, 催化氧化, 制氢

Abstract: Structural, crystalline phase, and redox properties of three composite oxides with a general formula of Fe₂O₃-CaTi_xM₁_-xO₃ were investigated. Integral and differential bed reactors were used to investigate methane partial oxidation and water-splitting reactions. In their oxidized form, all three composites consisted of orthorhombic perovskite phase and hematite phase. Activities for methane partial oxidation followed the sequence: Fe₂O₃-CaTi_0.85Ni_0.15O₃ > Fe₂O₃-CaTi_0.85Co_0.15O₃ > Fe₂O₃-CaTi_0.85Fe_0.15O₃. Fixed bed results indicated that Fe₂O₃-CaTi_0.85Ni_0.15O₃ was capable of converting 96% CH₄ with syngas yield of 71%. Steam to hydrogen conversion in water-splitting was 40%. ASPEN Plus^® simulations indicated that Fe₂O₃-CaTi_0.85Ni_0.15O₃, when used in the hybrid solar-redox process, could signficantly enhance methane utilization efficiency for liquid fuel and H₂ co-production.

Key words: perovskite composite, methane, catalytic oxidation, hydrogen production

中图分类号:

O643.36

陈彦广, 何峰, Daga Shivalik, 李凡星. 钙钛矿型复合氧化物对甲烷的部分氧化及在混合太阳能氧化还原过程的应用[J]. 化工学报, 2014, 65(7): 2741-2750.

CHEN Yanguang, HE Feng, DAGA Shivalik, LI Fanxing. Redox conversion of methane with Fe₂O₃-CaTi_xM₁_-xO₃ composite oxides for hydrogen and liquid fuel co-production[J]. CIESC Journal, 2014, 65(7): 2741-2750.

参考文献 29

[1]	Kharton V V, Patrakeev M V, Waerenborgh J C, Sobyanin V A, Veniaminov S A, Yaremchenko A A, Gaczyński P, Belyaev V D, Semin G L, Frade J R. Methane oxidation over perovskite-related ferrites: effects of oxygen nonstoichiometry[J]. Solid State Sci., 2005, 7(11): 1344-1352
[2]	He X X, Meng M, He J J, Zou Z Q, Li X G, Li Z Q, Jiang Z. A potential substitution of noble metal Pt by perovskite LaCoO3 in ZrTiO4 supported lean-burn NOx trap catalysts[J]. Catal. Commun., 2010, 12(3): 165-168
[3]	Wang P, Cai Y X, Lei L L, Li L. Effect of temperature on reduction of NOx and soot in diesel exhaust with perovskite-type catalysts[J]. Procedia Engineering, 2011, 16(1): 259-263
[4]	Zawadzki M, Trawczyński J. Synthesis, characterization and catalytic performance of LSCF perovskite or VOC combustion[J]. Catal. Today, 2011, 176(1): 449-452
[5]	Nishihata Y, Mizuki J, Tanaka H, Uenishi M, Kimura M. Self-regeneration of palladium-perovskite catalysts in modern automobiles[J]. J. Phys. Chem. Solids, 2005, 66(2/3/4): 274-282
[6]	Nagai T, Ito W. Stabilization of the perovskite structure in Co-based mixed conductors by tri-valent cation substitution[J]. Solid State Ion, 2014, 259(1): 21-28
[7]	Trepakov V, Makarova M, Stupakov O, Tereshina E A. Synthesis, structure and properties of heavily Mn-doped perovskite-type SrTiO3 nanoparticles[J]. Mater. Chem. Phys., 2014, 143(2): 570-577
[8]	Ghaffari M, Shannon M, Hui H, Tan O K, Irannejad A. Preparation, surface state and band structure studies of SrTi1-xFexO3-d(x=0-1) perovskite-type nano structure by X-ray and ultraviolet photoelectron spectroscopy[J]. Surf. Sci., 2012, 606(5/6): 670-677
[9]	Pon-On W, Meejoo S, Mehtar A, Tang I M. Influence of manganese substitution into the A-site of perovskite type Ca1-xMnxTiO3 ceramic[J] Ceram. Int., 2011, 37(7): 2075-2079
[10]	Cimino S, Lisi L, De Rossi S, Faticanti M, Porta P. Methane combustion and CO oxidation on LaAl1-xMnxO3 perovskite-type oxide solid solutions[J]. Appl. Catal. B: Environ., 2003, 43(4): 397-406
[11]	Sarshar Z, Kaliaguine S. Reduction kinetics of perovskite-based oxygen carriers for chemical looping combustion[J]. Ind. Eng. Chem. Res., 2013, 52(21): 6946-6955
[12]	Sarshar Z, Kleitzb F, Kaliaguine S. Novel oxygen carriers for chemical looping combustion: La1-xCexBO3 (B =Co, Mn) perovskites synthesized by reactive grinding and nanocasting[J]. Energy Environ. Sci., 2011, 4(10): 4258-4269
[13]	Rydén M, Lyngfelt A, Mattisson T, Chen D, Holmen A, Bjørgum E. Novel oxygen-carrier materials for chemical-looping combustion and chemical-looping reforming; LaxSr1-xFeyCo1-yO3-d perovskites and mixed-metal oxides of NiO, Fe2O3 and Mn3O4[J]. Int. J. Greenhouse Gas Control, 2008, 2(1): 21-36
[14]	Galinsky N L, Yan H, Shafiefarhood A, Li F X. Iron oxide with facilitated O2- transport for facile fuel oxidation and CO2 capture in a chemical looping scheme[J]. ACS Sustainable Chem. Eng., 2013, 1(3): 364-373
[15]	Shafiefarhood A, Galinsky N L, Huang Y, Chen Y G, Li F X. Fe2O3@LaxSr1-xFeO3 core-shell redox catalyst for methane partial oxidation[J]. Chem. Cat. Chem., 2014, 6(3): 790-799
[16]	Isogai S, Kosaka F, Takimoto I, Hatano H, Oshima Y, Otomo J. Acceleration of Fe2O3 reduction kinetics by wet methane with calcium titanate as support[J]. Chem. Lett., 2013, 42(11): 1438-1440
[17]	He F, Trainham J, Parsons G, Newman J, Li F. A hybrid solar-redox scheme for liquid fuel and hydrogen coproduction[J]. Energy Environ. Sci., 2014, DOI: 10.1039/C4EE00038B
[18]	Fan L S. Chemical Looping Systems for Fossil Energy Conversions [M]. Hoboken: John Wiley & Sons, 2010
[19]	Li F, Fan L S. Clean coal conversion processes — progress and challenges[J]. Energy & Environ. Sci., 2008, (1): 248
[20]	Li F, Sun Z, Luo S, Fan L S. Ionic diffusion in iron oxidation — effect of support and its implications to chemical looping applications[J]. Energy Environ. Sci., 2011(4): 876-880
[21]	Li F, Luo S, Sun Z, Fan L S. Role of metal oxide support in redox reactions of iron oxide for chemical looping applications: experiments and density functional theory calculations[J]. Energy Environ. Sci., 2011(4): 3661-3667
[22]	Fan L S, Li F, Ramkumar S. Utilization of chemical looping strategy in coal gasification processes[J]. Particuology, 2008, 6(3): 131-142
[23]	He F, Galinsky N, Li F. Chemical looping gasification of solid fuels using bimetallic oxygen carrier particles — feasibility assessment and process simulations[J]. Int. J. Hydrog. Energy, 2013, 38(19): 7839-7854
[24]	Chen Y, Galinsky N, Wang Z, Li F X. Investigation of perovskite supported composite oxides for chemical looping conversion of syngas// 2013 AIChE Annual Meeting[C]. San Francisco, CA, US, 2013
[25]	VanBerge P J, Everson R C. Cobalt as an alternative Fischer-Tropsch catalyst to iron for the production of middle distillates[J]. Natural Gas Conversion Ⅵ, 1997, 107:207-212
[26]	Sie S T. Process development and scale up(Ⅳ): Case history of the development of a Fischer-Tropsch synthesis process[J]. Rev. Chem. Eng., 1998, 14(2): 109-157
[27]	Nishihata, Y, Mizuki1 J, Akao T, et al. Self-regeneration of a Pd-perovskite catalyst for automotive emissions control[J]. Nature, 2002, 418: 164-167
[28]	Ruether J, Ramezan M, Grol E. Life-cycle analysis of greenhouse gas emissions for hydrogen fuel production in the United States from LNG and coal[EB/OL]. DOE/NETL-2006/1227. http://www.netl. doe.gov/ energy-analyses/pubs/H2_from_Coal_LNG_Final.pdf
[29]	Jaramillo P, Griffin W M, Matthews H S. Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas[J]. Energy Environ. Sci., 2008, 42(20): 7559-7565

钙钛矿型复合氧化物对甲烷的部分氧化及在混合太阳能氧化还原过程的应用

Redox conversion of methane with Fe₂O₃-CaTi_xM₁_-xO₃ composite oxides for hydrogen and liquid fuel co-production

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钙钛矿型复合氧化物对甲烷的部分氧化及在混合太阳能氧化还原过程的应用

Redox conversion of methane with Fe2O3-CaTixM1-xO3 composite oxides for hydrogen and liquid fuel co-production

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Redox conversion of methane with Fe₂O₃-CaTi_xM₁_-xO₃ composite oxides for hydrogen and liquid fuel co-production