芳基烷基磺酸盐链长对烷烃的油-水动态界面张力的影响

doi:10.11949/j.issn.0438-1157.20151773

摘要/Abstract

摘要：

采用旋转滴法测定系列自制芳基烷基磺酸盐（C_nNPAS, n=8，10，12，14，16）水溶液对烷烃的油-水动态界面张力，考察了表面活性剂烷基链长、表面活性剂浓度、弱碱浓度、烷烃碳数等因素对油-水动态界面张力的影响。结果表明，增大C_nNPAS的烷基链长和碱含量均会使界面张力达到稳定值的时间增长；增加C_nNPAS浓度和烷烃碳数均会使界面张力动态变化加快，达到平衡所需时间减少。C_nNPAS表面活性剂可在低浓度范围较明显地降低界面张力，而随着浓度的增加界面张力回升明显。

关键词: 芳基烷基磺酸盐表面活性剂, 动态界面张力, 烷烃, 水溶液, 数值分析

Abstract:

Using spinning drop method, the interfacial tensions between alkane and series of aryl alkyl sulfonate(C_nNPAS, n=8,10,12,14,16)aqueous solutions were measured. The effects of the carbon number of alkane, the molecular weight of surfactant, the concentration of the surfactant and Na₂CO₃ on the interfacial tension were studied in detail. The results showed that the required time to reach the equilibrium interfacial tension increased with increasing molecular weight of the surfactant and content of Na₂CO₃. On the contrary, the higher carbon number of alkane and concentration of the surfactant, the less required time. The interfacial tension could be reduced obviously at a range of relative low surfactant concentrations, and then went through a minimum and eventually increased with increasing concentration.

Key words: aryl alkyl sulfonate surfactants, dynamic interfacial tension, alkane, aqueous solution, numerical analysis

中图分类号:

O647.11

牛瑞霞, 王大强, 王敬玲, 王超, 廖凌之, 宋华. 芳基烷基磺酸盐链长对烷烃的油-水动态界面张力的影响[J]. 化工学报, 2016, 67(7): 2944-2949.

NIU Ruixia, WANG Daqiang, WANG Jingling, WANG Chao, LIAO Lingzhi, SONG Hua. Effects of carbon chain length on dynamic interfacial tension between alkane and aryl alkyl sulfonate aqueous solutions[J]. CIESC Journal, 2016, 67(7): 2944-2949.

参考文献 20

[1]	赵方剑, 王丽娟, 夏晞冉. 聚驱后油藏提高采收率技术研究进展及发展趋势[J]. 石油地质与工程, 2014, 28(2): 99-103. ZHAO F J, WANG L J, XIA X R. The research progress and development trend of improving oil recovery after polymer flooding technology[J]. Petroleum Geology and Engineering, 2014, 28(2): 99-103.
[2]	郭万奎, 杨振宇, 伍晓林, 等. 用于三次采油的新型弱碱表面活性剂[J]. 石油学报, 2006, 27(5): 75-78. GUO W K, YANG Z Y, WU X L, et al. New-type weak alkali surfactant applied to tertiary oil recovery[J]. Acta Petrolei Sinica, 2006, 27(5): 75-78.
[3]	郝宏达, 侯吉瑞, 赵凤兰, 等. ASP体系在大庆二类油层中的色谱分离现象及其对采收率的影响[J]. 油田化学, 2015, 32(1): 119-122. HAO H D, HOU J R, ZHAO F L, et al. Chromatographic separation of ASP system and its effect on recovery in Daqing second-class oil Layer[J]. Oilfield Chemistry, 2015, 32(1): 119-122.
[4]	岳晓云, 楼诸红, 韩冬, 等. 石油磺酸盐表面活性剂在三次采油中的应用[J]. 精细石油化工进展, 2005, 6(2): 48-52. YUE X Y, LOU Z H, HAN D, et al. Application of petroleum sulfonates in tertiary oil recovery[J]. Advances in Fine Petrochemicals, 2005, 6(2): 48-52.
[5]	王洋, 韩国彤, 葛际江, 等. 表面活性剂提高碳酸盐岩油藏采收率进展[J]. 油田化学, 2015, 32(2): 301-306. WANG Y, HAN G T, GE J J, et al. Research progress of enhanced oil recovery with surfactants in carbonate reservoirs[J]. Oilfield Chemistry, 2015, 32(2): 301-306.
[6]	陈丽文. AOS研制及其在三次采油中的应用[D]. 大庆: 大庆石油学院, 2007. CHEN L W. The development and application of AOS in the tertiary oil recovery[D]. Daqing: Daqing Petroleum Institute, 2007.
[7]	BERGER P D. Anionic surfactants based on alkene sulfonic acid: US6043391[P]. 2000.
[8]	BERGER P D, BERGER C H, HERRON S J. Chemistry of olefin acids. 1. Alkylation of aromatic sulfonic acid[C]//Proceedings of the 5th World Surfactants Congress. Federchimica, Milan, 2001, 1: 291-294.
[9]	BERGER P D, LEE C H. New anionic alkylaryl surfactants based on olefin sulfonic acids[J]. Journal of Surfactants and Detergents, 2001, 5(1): 39-43.
[10]	宋华, 廖凌之, 牛瑞霞, 等. 一种新型芳基烷基磺酸盐的制备与性能评价[J]. 化工进展, 2015, 34(6): 1742-1746. SONG H, LIAO L Z, NIU R X, et al. Synthesis and property evaluation of a new kind of alkyl sulfonate[J]. Chemical Industry and Engineering Progress, 2015, 34(6): 1742-1746.
[11]	AL-SABAGH A M, ZAKAA M M, EL-DIN M R. The interfacial tension and alkane carbon number (nmin) of alkyl benzene sulfonates in relation to enhanced oil recovery(Ⅰ): Effect of surfactant molecular weight/temperature and electrolyte on nmin [J]. Journal of Dispersion Science and Technology, 2009, 30(8): 1237-1246.
[12]	张越, 张高勇, 王佩维, 等. 重烷基苯磺酸盐的界面性质和驱油机理的研究[J]. 物理化学学报, 2005, 21(2): 161-165. ZHANG Y, ZHANG G Y, WANG P W, et al. The interface behavior and enhanced oil recovery mechanism of heavy alkylbenzene sulfonate[J]. Acta Phys.-Chim. Sin., 2005, 21(2): 161-165.
[13]	高树棠, 苗希仁. 低界面张力的产生和大庆原油等效烷烃碳数(EACN)的测定[J]. 油田化学, 1985, 2(2): 96-102. GAO S T, MIAO X R. Research institute of exploration and development Daqing petroleum administrative bureau[J]. Oilfield Chemistry, 1985, 2(2): 96-102.
[14]	赵荣华, 黄海耀, 董林芳, 等. 胜利原油活性组分对其与烷基苯磺酸盐溶液组成的体系油-水界面张力的影响[J]. 石油学报(石油加工), 2012, 28(5): 827-833. ZHAO R H, HUANG H Y, DONG L F, et al. Effect of Shengli crude oil active fractions on oil-water interfacial tension of the system of alkylbenzene sulfonate solution and the active fraction[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2012, 28(5): 827-833.
[15]	丁伟, 李安军, 于涛, 等. 烷基芳基磺酸盐结构对原油-表面活性剂-碱体系油-水界面张力的影响[J]. 石油学报(石油加工), 2010, 26(1): 36-40. DING W, LI A J, YU T, et al. Effects of structure of alkyl aryl sulfonates on oil-water interfacial tension of crude oil-alkali-surfactant system[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2010, 26(1): 36-40.
[16]	赵宇, 董雅红, 毕彩丰, 等. 系列烷基苯磺酸盐对烷烃的动态界面张力研究[J]. 化学学报, 2008, 66(7): 799-802. ZHAO Y, DONG Y H, BI C F, et al. Study on dynamic interfacial tension of a series of alkylbenzene sulfonates with alkane[J]. Acta Chimica Sinica, 2008, 66(7): 799-802.
[17]	ZHAO J H, DAI C L, DING Q F, et al. The structure effect on the surface and interfacial properties of zwitterionic sulfobetaine surfactants for enhanced oil recovery[J]. RSC Advances, 2015, 5(18): 13993-14001.
[18]	黄志宇, 张太亮, 鲁红升, 等. 表面及胶体化学[M]. 2版. 北京: 石油工业出版社, 2012: 108-109. HUANG Z Y, ZHANG T L, LU H S, et al. Superficial and Colloid Chemistry[M]. 2nd ed. Beijing: Petroleum Industry Press, 2012: 108-109.
[19]	赵振国. 应用胶体与界面化学[M]. 北京: 化学工业出版社, 2008: 38-39. ZHAO Z G. Applied Colloid and Interfacial Chemistry[M]. Beijing: Chemical Industry Press, 2008: 38-39.
[20]	张莹, 陈莉, 肖进新, 等. 高浓度无机盐对正负离子等摩尔混合表面活性剂表面活性的影响[J]. 化学学报, 2004, 62(16): 1491-1494. ZHANG Y, CHEN L, XIAO J X, et al. Effect of salt with high concentration on surface activities of equimolar mixtures of cationic-anionic surfactants[J]. Acta Chimica Sinica, 2004, 62(16): 1491-1494.