废旧磷酸铁锂材料的固相再生及电化学性能研究

doi:10.11949/j.issn.0438-1157.20180319

化工学报 ›› 2018, Vol. 69 ›› Issue (12): 5316-5325.DOI: 10.11949/j.issn.0438-1157.20180319

• 材料化学工程与纳米技术 • 上一篇下一篇

废旧磷酸铁锂材料的固相再生及电化学性能研究

陈永珍^1,2,3, 黎华玲^1,2,3, 宋文吉^1,2,3, 冯自平^1,2,3

1. 中国科学院广州能源研究所, 广东广州 510640;
2. 中国科学院可再生能源重点实验室, 广东广州 510640;
3. 广东省新能源和可再生能源研究开发与应用重点实验室, 广东广州 510640

收稿日期:2018-03-23 修回日期:2018-08-08 出版日期:2018-12-05 发布日期:2018-12-05
通讯作者: 宋文吉
基金资助:
广东省科技计划项目（2015B050501008）；广东省新能源和可再生能源研究开发与应用重点实验室项目（y807ji1001）。

Regeneration of spent LiFePO₄cathode materials using solid state method and electrochemical performance

CHEN Yongzhen^1,2,3, LI Hualing^1,2,3, SONG Wenji^1,2,3, FENG Ziping^1,2,3

1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
2. Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
3. Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, Guangdong, China

Received:2018-03-23 Revised:2018-08-08 Online:2018-12-05 Published:2018-12-05
Supported by:
supported by Guangdong Science and Technology Project(2015B050501008) and the Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development(y807ji1001).

摘要/Abstract

摘要：

热处理废旧电池正极片除去黏结剂后得到回收材料，在对回收材料元素定量分析的基础上，通过添加不同比例的Li、Fe、P源进行高温固相再生反应获得再生材料，研究杂质对再生材料的影响并优化再生反应原料比例。实验结果表明，再生反应过程中生成了Fe₂P杂质，该杂质衍射特征峰随着添加的Li、Fe、P源比例增加逐渐减弱；过多Li、Fe、P源添加时，导致再生材料结构致密性严重，Fe₂P杂质存在及材料结构过于致密，均降低了再生材料的容量性能。回收材料、化学计量比再生材料、过量元素源（1：1）再生材料首次放电容量分别为103.4、115.8和134.0 mA·h·g^-1，再生反应后分别提高了11.99%、29.59%。上述三种材料50次循环后放电容量分别为100.9、108.0和115.3 mA·h·g^-1。

关键词: 废旧电池, 磷酸铁锂, 元素补充, 回收, 再生, 电化学

Abstract:

The recycled cathode material was obtained after removing the binder of the scrap electrode by heat treatment. The regenerated materials were obtained by high temperature solid state method that adding different proportions of Li, Fe, and P element sources to the recycled material on the basis of quantitative analysis. In this paper, the influence of impurities on regenerated materials was investigated and the optimal proportion of regenerative reaction materials was obtained. The results showed that the Fe₂P impurity occurred during the regeneration process. The diffraction characteristic peak of the Fe₂P phase gradually declined with the increase of Li, Fe and P element sources. The presence of Fe₂P phase decreases the specific capacity of the sample due to the low content of LiFePO₄ active material. The morphology of regenerated materials tends to become densification as the proportion of Li, Fe and P element sources increases. The fine and close microstructure decreases the capacity and cycle performance of regenerated materials. The initial specific discharge capacities of the recycled material, stoichiometric regenerated material and excess element sources regenerated material were 103.4, 115.8 and 134.0 mA·h·g^-1, respectively. Compared with that of the recycled material, the initial specific discharge capacity of the two regenerated materials was improved by 11.99% and 29.59%, respectively. The discharge capacities of the above three materials after 50 cycles are 100.9, 108.0 and 115.3 mA·h·g^-1.

Key words: scrap Li-ion battery, lithium iron phosphate, element supplement, recovery, regeneration, electrochemistry

中图分类号:

TM912.9

陈永珍, 黎华玲, 宋文吉, 冯自平. 废旧磷酸铁锂材料的固相再生及电化学性能研究[J]. 化工学报, 2018, 69(12): 5316-5325.

CHEN Yongzhen, LI Hualing, SONG Wenji, FENG Ziping. Regeneration of spent LiFePO₄cathode materials using solid state method and electrochemical performance[J]. CIESC Journal, 2018, 69(12): 5316-5325.

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废旧磷酸铁锂材料的固相再生及电化学性能研究

Regeneration of spent LiFePO₄cathode materials using solid state method and electrochemical performance

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废旧磷酸铁锂材料的固相再生及电化学性能研究

Regeneration of spent LiFePO4cathode materials using solid state method and electrochemical performance

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Regeneration of spent LiFePO₄cathode materials using solid state method and electrochemical performance