化工学报 ›› 2022, Vol. 73 ›› Issue (12): 5660-5671.DOI: 10.11949/0438-1157.20221141

• 材料化学工程与纳米技术 • 上一篇    下一篇

聚乙二醇高导热定形相变复合材料的制备及其性能研究

崔雯琦1,2(), 杨曙光1,3, 李红周1, 罗富彬1()   

  1. 1.福建师范大学环境与资源学院,福建 福州 350007
    2.福建师范大学环境与资源学院,聚合物资源绿色循环利用教育部 工程研究中心,福建 福州 350007
    3.福建师范大学环境与资源学院,福建省污染控制与资源循环利用重点实验室,福建 福州 350007
  • 收稿日期:2022-08-15 修回日期:2022-10-23 出版日期:2022-12-05 发布日期:2023-01-17
  • 通讯作者: 罗富彬
  • 作者简介:崔雯琦(1999—),女,硕士研究生, 1992926413@qq.com
  • 基金资助:
    泉港石化专项科技项目(2019YJY02);国家自然科学基金青年基金项目(51903049)

Preparation of highly thermally conductive and shape-stabilized polyethylene glycol-based phase change material

Wenqi CUI1,2(), Shuguang YANG1,3, Hongzhou LI1, Fubin LUO1()   

  1. 1.College of Environmental and Resources, Fujian Normal University, Fuzhou 350007, Fujian, China
    2.Engineering Research Center of Polymer Green Recycling of Ministry of Education, College of Environmental and Resources, Fujian Normal University, Fuzhou 350007, Fujian, China
    3.Fujian Key Laboratory of Pollution Control & Resource Reuse, College of Environmental and Resources, Fujian Normal University, Fuzhou 350007, Fujian, China
  • Received:2022-08-15 Revised:2022-10-23 Online:2022-12-05 Published:2023-01-17
  • Contact: Fubin LUO

摘要:

利用聚乙二醇为相变组分,以氮化硼为导热填料,通过两步法络合聚丙烯酸制备了具有相变稳定性的高导热相变复合材料。系统研究了片状氮化硼以及片状/球形混杂填充对复合材料导热以及相变性能的影响,探讨了相变复合材料的定形机理。结果表明,由于紧密的堆砌结构,片状氮化硼能够有效提升复合材料导热性能。填充60%(质量)的片状氮化硼时,热导率最高达到6.437 W/(m·K)。在混杂填充时,球形氮化硼与片状氮化硼的质量比为1∶3以及1∶6时,可以更加有效提升复合材料的导热性能。热储存实验显示,所制备的复合材料具有良好的热存储能力。此外,由于聚丙烯酸与聚乙二醇形成氢键的络合以及氮化硼的片状物理阻隔作用,复合材料在高温加热条件下具有优异的相变稳定性。

关键词: 复合材料, 相变, 聚合物, 热传导, 氮化硼

Abstract:

Shape-stabilized and highly thermally conductive phase change materials (PCMs) have been prepared based on polyethylene glycol (PEG) and boron nitride (BN). The PCMs are obtained by two-step blending assisted by the complexation of polyacrylic acid (PAA). The thermal conductivity and the stabilization mechanism of the PCMs have been investigated. The results show that the flake-like BN can significant improve the thermal conductivity of the composites. The thermal conductivity of the prepared PCMs can reach to 6.437 W/(m·K) when the mass fraction of BN is 60%. It is also confirmed that when one-third and one-sixth of flake-like BN is replaced by the spherical BN, the composites show an increased thermal conductivity, which suggests that the hybrid fillers has positive effect on the enhancement of thermal conductivity. The experimental results demonstrate that PAA can form hydrogen bond with PEG, which contributes to preventing the leakage of PEG from the matrix when enduring heating. In addition, abundant flake-like BN can act as a solid physical barriers to restrict the molten PEG being escaped from the matrix, resulting the excellent shape preserving property.

Key words: composites, phase change, polymers, heat conduction, boron nitride

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