CIESC Journal ›› 2019, Vol. 70 ›› Issue (S2): 44-49.DOI: 10.11949/0438-1157.20190544
• Thermodynamics • Previous Articles Next Articles
Manh Quang NGUYEN
Received:
2019-05-21
Revised:
2019-05-31
Online:
2019-09-06
Published:
2019-09-06
通讯作者:
何茂刚
基金资助:
CLC Number:
Manh Quang NGUYEN. Experimental measurement and theoretical calculation of solubility and diffusion coefficient of R1233zd(E) in [HMIM][PF6][J]. CIESC Journal, 2019, 70(S2): 44-49.
刘向阳,何茂刚. R1233zd(E)在[HMIM][PF6]中的溶解度和扩散系数的实验测量和理论计算[J]. 化工学报, 2019, 70(S2): 44-49.
T/K | p/ kPa | x | T/K | p/kPa | x |
---|---|---|---|---|---|
303.2 | 23.02 | 0.016 | 323.2 | 81.92 | 0.05 |
303.2 | 37.44 | 0.03 | 323.2 | 108.3 | 0.069 |
303.2 | 50.26 | 0.043 | 333.2 | 36.48 | 0.01 |
303.2 | 63.34 | 0.057 | 333.2 | 55.82 | 0.021 |
303.2 | 81.58 | 0.079 | 333.2 | 74.18 | 0.033 |
313.2 | 27.21 | 0.014 | 333.2 | 94.31 | 0.045 |
313.2 | 41.67 | 0.027 | 333.2 | 123.8 | 0.063 |
313.2 | 57.32 | 0.04 | 343.2 | 40.93 | 0.008 |
313.2 | 72.47 | 0.054 | 343.2 | 64.48 | 0.018 |
313.2 | 93.88 | 0.074 | 343.2 | 85.33 | 0.029 |
323.2 | 31.37 | 0.013 | 343.2 | 106.4 | 0.04 |
323.2 | 47.93 | 0.025 | 343.2 | 142.3 | 0.057 |
323.2 | 65.24 | 0.037 |
Table 1 Experimental results of solubility of R1233zd(E) in ionic liquid [HMIM][PF6]
T/K | p/ kPa | x | T/K | p/kPa | x |
---|---|---|---|---|---|
303.2 | 23.02 | 0.016 | 323.2 | 81.92 | 0.05 |
303.2 | 37.44 | 0.03 | 323.2 | 108.3 | 0.069 |
303.2 | 50.26 | 0.043 | 333.2 | 36.48 | 0.01 |
303.2 | 63.34 | 0.057 | 333.2 | 55.82 | 0.021 |
303.2 | 81.58 | 0.079 | 333.2 | 74.18 | 0.033 |
313.2 | 27.21 | 0.014 | 333.2 | 94.31 | 0.045 |
313.2 | 41.67 | 0.027 | 333.2 | 123.8 | 0.063 |
313.2 | 57.32 | 0.04 | 343.2 | 40.93 | 0.008 |
313.2 | 72.47 | 0.054 | 343.2 | 64.48 | 0.018 |
313.2 | 93.88 | 0.074 | 343.2 | 85.33 | 0.029 |
323.2 | 31.37 | 0.013 | 343.2 | 106.4 | 0.04 |
323.2 | 47.93 | 0.025 | 343.2 | 142.3 | 0.057 |
323.2 | 65.24 | 0.037 |
T/K | H/MPa | D×1010/(m2·s-1) |
---|---|---|
303.2 | 1.4604 | 0.9724 |
313.2 | 1.9248 | 1.4506 |
323.2 | 2.3614 | 2.0671 |
333.2 | 3.486 | 3.1289 |
343.2 | 4.8601 | 4.4513 |
Table 2 Experimental results of diffusion coefficient and Henry’s constant of R1233zd(E) in ionic liquid [HMIM][PF6]
T/K | H/MPa | D×1010/(m2·s-1) |
---|---|---|
303.2 | 1.4604 | 0.9724 |
313.2 | 1.9248 | 1.4506 |
323.2 | 2.3614 | 2.0671 |
333.2 | 3.486 | 3.1289 |
343.2 | 4.8601 | 4.4513 |
α | AARD/% | MD/% | ||||
---|---|---|---|---|---|---|
0.013 | -0.60982 | 869.04 | 626.12 | 3066.11 | 2.45 | 6.13 |
Table 3 Fitting parameters and errors of NRTL equation
α | AARD/% | MD/% | ||||
---|---|---|---|---|---|---|
0.013 | -0.60982 | 869.04 | 626.12 | 3066.11 | 2.45 | 6.13 |
A | -B | AARD/% | MD/% |
---|---|---|---|
612117.9 | -33758.8 | 1.91 | 4.12 |
Table 4 Fitting parameters and errors of Arrhenius equation
A | -B | AARD/% | MD/% |
---|---|---|---|
612117.9 | -33758.8 | 1.91 | 4.12 |
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